Unleashing the piezoelectric potential of PVDF: a study on phase transformation from gamma (γ) to beta (ß) phase through thermal contact poling.

Polyvinylidene fluoride (PVDF) is known for its piezoelectric properties. This material has different crystalline phases, alpha (α), beta (ß) and gamma (γ), where the ß-phase, in particular, is related to the piezoelectric behavior of PVDF. While the transformation from the α-phase to ß-phase in PVDF is well-documented and widely studied, the transformation from γ- to ß-phase has not yet been fully explored. However, when PVDF is produced by certain solution-based methods it can adopt its γ-form, which is not as piezoelectric as the ß-phase. Hence, this study aims to bridge this gap by investigating the transformation from γ- to ß-phase in PVDF nanocomposites films obtained from solution-based techniques. Our PVDF nanocomposite is made by solvent evaporation-assisted 3D printing of PVDF's nanocomposite with barium-titanate nanoparticles (BTO). To achieve the γ- to ß-phase transformation, we first highlight the importance of annealing in the successful poling of PVDF samples. We then perform an in-depth analysis of the α-, ß- and γ-crystallographic phases of PVDF-BTO using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and differential scanning calorimetry (DSC). We observed that after annealing but before poling, the PVDF-BTO nanocomposite contains 76% of ß + γ phases, the majority of which is the γ-phase. Poling of these samples resulted in the combination of the ß + γ phases reaching 93% with the appearance of 40% of absolute fraction of the ß-phase. We then demonstrated that the fraction of ß-phase in the nanocomposite - as indicated by the 1275 cm-1 peak in PVDF's FTIR spectra - is not uniform on the surface area of the film. Additionally, the value of the absolute ß-phase content also depends on the poling field's direction. Our work reveals that while considering PVDF's piezoelectric behavior, it is critical to be aware of these nuances and this article offers essential insights on how to address them. Overall, this study provides a step-by-step guideline to enhance the piezoelectricity of PVDF-based nanocomposites for sensing applications.

Resonant Gas Sensing in the Terahertz Spectral Range Using Two-Wire Phase-Shifted Waveguide Bragg Gratings.

The development of low-cost sensing devices with high compactness, flexibility, and robustness is of significance for practical applications of optical gas sensing. In this work, we propose a waveguide-based resonant gas sensor operating in the terahertz frequency band. It features micro-encapsulated two-wire plasmonic waveguides and a phase-shifted waveguide Bragg grating (WBG). The modular semi-sealed structure ensures the controllable and efficient interaction between terahertz radiation and gaseous analytes of small quantities. WBG built by superimposing periodical features on one wire shows high reflection and a low transmission coefficient within the grating stopband. Phase-shifted grating is developed by inserting a Fabry-Perot cavity in the form of a straight waveguide section inside the uniform gratings. Its spectral response is optimized for sensing by tailoring the cavity length and the number of grating periods. Gas sensor operating around 140 GHz, featuring a sensitivity of 144 GHz/RIU to the variation in the gas refractive index, with resolution of 7 × 10-5 RIU, is developed. In proof-of-concept experiments, gas sensing was demonstrated by monitoring the real-time spectral response of the phase-shifted grating to glycerol vapor flowing through its sealed cavity. We believe that the phase-shifted grating-based terahertz resonant gas sensor can open new opportunities in the monitoring of gaseous analytes.

Continuous fabrication of polarization maintaining fibers via an annealing improved infinity additive manufacturing technique for THz communications.

We report the design and fabrication of a polarization-maintaining fiber for applications in fiber-assisted THz communications. The fiber features a subwavelength square core suspended in the middle of a hexagonal over-cladding tube by four bridges. The fiber is designed to have low transmission losses, high birefringence, high flexibility, and near-zero dispersion at the carrier frequency of 128 GHz. An infinity 3D printing technique is used to continuously fabricate a 5 m-long polypropylene fiber of ∼6.8 mm diameter. The fiber transmission losses are furthermore reduced by as high as ∼4.4 dB/m via post-fabrication annealing. Cutback measurements using 3 m-long annealed fibers show ∼6.5-11 dB/m and ∼6.9-13.5 dB/m losses (by power) over a 110-150 GHz window for the two orthogonally polarized modes. Signal transmission with bit error rates of ∼10-11-10-5 is achieved at 128 GHz for 1-6 Gbps data rates using a 1.6 m-long fiber link. The average polarization crosstalk values of ∼14.5 dB and ∼12.7 dB are demonstrated for the two orthogonal polarizations in fiber lengths of 1.6-2 m, which confirms the polarization-maintaining property of the fiber at ∼1-2 meter lengths. Finally, THz imaging of the fiber near-field is performed and shows strong modal confinement of the two orthogonal modes in the suspended-core region well inside of the hexagonal over-cladding. We believe that this work shows a strong potential of the infinity 3D printing technique augmented with post-fabrication annealing to continuously produce high-performance fibers of complex geometries for demanding THz communications applications.

Photonics based frequency hopping spread spectrum system for secure terahertz communications.

Terahertz (THz) spectrum (100 GHz-10 THz) is considered the next frontier in the design of high-speed wireless communication systems. While the high-power THz sources have commercially become available, it increases the possibility of developing THz jammers to disrupt the THz communication link. Therefore, the development of novel anti-jamming solutions is the need of the hour. In this work, we present the photonics-based THz communication system and demonstrate the frequency hopping spread spectrum (FHSS) technique which acts against the single/multi-tone jamming attack in the frequency window of 110 GHz-170 GHz. By tuning the output wavelength of the distributed feedback lasers, the THz carrier frequencies are swept back and forth within the scanning window. The frequency tuning range was measured for different scanning rates of the laser which decreases rapidly with the increase in the scanning rate. Next, we demonstrate the THz FHSS technique in a real-time communication system by transmitting a 6 Gbps NRZ signal in both wireless and THz-fiber-based links within the link distance of 1.75 m. We experimentally found that the measured bit error rate in the THz FHSS system is the time average of the measured BER for individual carrier frequencies within the hopping frequency window. By combining with the forward error correction codes and by using the tunable filter in the receiver, we believe that the proposed technique will offer a novel and compact solution against the single/multi-tone jammer for high-bit rate THz communications.

Add drop multiplexers for terahertz communications using two-wire waveguide-based plasmonic circuits.

Terahertz (THz) band is considered to be the next frontier in wireless communications. The emerging THz multiplexing techniques are expected to dramatically increase the information capacity of THz communications far beyond a single channel limit. In this work, we explore the THz frequency-division multiplexing modality enabled by an add-drop multiplexer (ADM) design. Based on modular two-wire plasmonic waveguides fabricated using additive manufacturing and metallization techniques, we demonstrate four-port THz ADMs containing grating-loaded side couplers for operation at ~140 GHz carrier frequency. Particular attention is paid to the design of plasmonic waveguide Bragg gratings and directional couplers capable of splitting broadband THz light into spectral and spatial domains. Finally, we demonstrate multi/demultiplexing of THz signals with bit rates up to 6 Gbps using the developed ADMs. We believe that the proposed plasmonic circuits hold strong potential to provide robust integrated solutions for analog signal processing in the upcoming THz communications.

Infinity additive manufacturing of continuous microstructured fiber links for THz communications.

In this work, a novel infinity 3D printing technique is explored to fabricate continuous few-meter-long low-loss near-zero dispersion suspended-core polypropylene fibers for application in terahertz (THz) communications. Particular attention is paid to process parameter optimization for 3D printing with low-loss polypropylene plastic. Three microstructured THz fibers were 3D printed using the standard and infinity 3D printers, and an in-depth theoretical and experimental comparison between the fibers was carried out. Transmission losses (by power) of 4.79 dB/m, 17.34 dB/m, and 11.13 dB/m are experimentally demonstrated for the three fibers operating at 128 GHz. Signal transmission with bit error rate (BER) far below the forward error correction limit (10-3) for the corresponding three fiber types of lengths of 2 m, 0.75 m, and 1.6 m are observed, and an error-free transmission is realized at the bit rates up to 5.2 Gbps. THz imaging of the fiber near-field is used to visualize modal distributions and study optimal fiber excitation conditions. The ability to shield the fundamental mode from the environment, mechanical robustness, and ease of handling of thus developed effectively single-mode high optical performance fibers make them excellent candidates for upcoming fiber-assisted THz communications. Additionally, novel fused deposition modeling (FDM)-based infinity printing technique allows continuous fabrication of unlimited in length fibers of complex transverse geometries using advanced thermoplastic composites, which, in our opinion, is poised to become a key fabrication technique for advanced terahertz fiber manufacturing.

Cellular effects of terahertz waves.

SIGNIFICANCE: An increasing interest in the area of biological effects at exposure of tissues and cells to the terahertz (THz) radiation is driven by a rapid progress in THz biophotonics, observed during the past decades. Despite the attractiveness of THz technology for medical diagnosis and therapy, there is still quite limited knowledge about safe limits of THz exposure. Different modes of THz exposure of tissues and cells, including continuous-wave versus pulsed radiation, various powers, and number and duration of exposure cycles, ought to be systematically studied. AIM: We provide an overview of recent research results in the area of biological effects at exposure of tissues and cells to THz waves. APPROACH: We start with a brief overview of general features of the THz-wave-tissue interactions, as well as modern THz emitters, with an emphasis on those that are reliable for studying the biological effects of THz waves. Then, we consider three levels of biological system organization, at which the exposure effects are considered: (i) solutions of biological molecules; (ii) cultures of cells, individual cells, and cell structures; and (iii) entire organs or organisms; special attention is devoted to the cellular level. We distinguish thermal and nonthermal mechanisms of THz-wave-cell interactions and discuss a problem of adequate estimation of the THz biological effects' specificity. The problem of experimental data reproducibility, caused by rareness of the THz experimental setups and an absence of unitary protocols, is also considered. RESULTS: The summarized data demonstrate the current stage of the research activity and knowledge about the THz exposure on living objects. CONCLUSIONS: This review helps the biomedical optics community to summarize up-to-date knowledge in the area of cell exposure to THz radiation, and paves the ways for the development of THz safety standards and THz therapeutic applications.

Special Section Guest Editorial: Advances in Terahertz Biomedical Science and Applications.

The editorial introduces a special section of the Journal of Biomedical Optics on Advances in Terahertz Biomedical Science and Applications. This special section includes one review and ten research papers addressing the complex challenges of terahertz biophotonics and related areas of biomedical optics.

Improving thermo-optic properties of smart windows via coupling to radiative coolers.

In this work we first solve the radiative heat transfer problem in one dimension to perform a comparative analysis of the time-averaged performance of the partially transparent radiative windows and radiative coolers. In doing so, we clearly distinguish the design goals for the partially transparent windows and radiative coolers and provide optimal choice for the material parameters to realize these goals. Thus, radiative coolers are normally non-transparent in the visible, and the main goal is to design a cooler with the temperature of its dark side as low as possible relative to that of the atmosphere. For the radiative windows, however, their surfaces are necessarily partially transparent in the visible. In the cooling mode, the main question is rather about the maximal visible light transmission through the window at which the temperature on the window somber side does not exceed that of the atmosphere. We then demonstrate that transmission of the visible light through smart windows can be significantly increased (by as much as a factor of 2) without additional heating of the windows. This is accomplished via coupling the windows to the radiative coolers using transparent cooling liquid that flows inside of the window and radiative cooler structures. We also demonstrate that efficient heat exchange between radiative coolers and smart windows can be realized using small coolant velocities (sub-1 mm/s for ${\sim}{1}\;{\rm m}$∼1m large windows) or even using a purely passive gravitationally driven coolant flows between a hot smart window and a cold radiative cooler mounted on top of the window with only a minimal temperature differential (sub-1K) between the two. We believe that our simple models complemented with an in-depth comparative analysis of the standalone and coupled smart windows and radiative coolers can be of interest to a broad scientific community pursuing research in these disciplines.

Improving thermo-optic properties of smart windows via coupling to radiative coolers: publisher's note.

This publisher's note amends several equations and one formula in Appl. Opt.59, D210 (2020).APOPAI0003-693510.1364/AO.382050.

Surface Wave Enhanced Sensing in the Terahertz Spectral Range: Modalities, Materials, and Perspectives.

The terahertz spectral range (frequencies of 0.1-10 THz) has recently emerged as the next frontier in non-destructive imaging and sensing. Here, we review amplitude-based and phase-based sensing modalities in the context of the surface wave enhanced sensing in the terahertz frequency band. A variety of surface waves are considered including surface plasmon polaritons on metals, semiconductors, and zero gap materials, surface phonon polaritons on polaritonic materials, Zenneck waves on high-k dielectrics, as well as spoof surface plasmons and spoof Zenneck waves on structured interfaces. Special attention is paid to the trade-off between surface wave localization and sensor sensitivity. Furthermore, a detailed theoretical analysis of the surface wave optical properties as well as the sensitivity of sensors based on such waves is supplemented with many examples related to naturally occurring and artificial materials. We believe our review can be of interest to scientists pursuing research in novel high-performance sensor designs operating at frequencies beyond the visible/IR band.

Additive manufacturing of resonant fluidic sensors based on photonic bandgap waveguides for terahertz applications.

A hollow-core Bragg waveguide-based resonant fluidic sensor operating in the terahertz frequency band is studied. A fused deposition modeling 3D printing technique with a Polylactic Acid filament is employed to fabricate the sensor where the liquid analyte is flowing in the microfluidic channel integrated into the waveguide cladding. The fluidic channel supports a resonant defect state which is probed spectrally using the core-guided mode of the Bragg waveguide. Continuous-wave terahertz spectroscopy is used to characterize the fluidic sensor. The measured signal amplitude shows a dip in the transmission spectrum, while the measured phase shows a sharp change in the vicinity of the anticrossing frequency whose spectral position depends strongly on the real part of the analyte refractive index. The sensor spectral response is further optimized by tailoring the waveguide length and position of the defect layer. Consistent with the results of numerical modeling, the measured sensor sensitivity is ~110 GHz/RIU, while the sensor resolution ~0.0045 RIU is limited by the parasitic standing waves in the spectrometer cavity. We believe that the proposed fluidic sensor opens new opportunities in applied chemical and biological sensing as it offers a non-contact measurement technique for monitoring refractive index changes in flowing liquids.

Analog signal processing in the terahertz communication links using waveguide Bragg gratings: example of dispersion compensation.

We study the possibility of analog signal processing for the upcoming terahertz (THz) high-bitrate communications using as an example the problem of dispersion compensation in the THz communication links. In particular, two Waveguide Bragg Grating devices (WBGs) operating in the transmission mode are detailed. WBGs are designed by introducing periodic corrugation onto the inner surface of the metalized tubes. The resultant devices operate in a single mode regime either in the vicinity of the modal cutoff or in the vicinity of a bandgap edge, featuring large negative group velocity dispersions (GVD). We fabricate the proposed WBGs using 3D stereolithography, and metallize them using wet chemistry. Optical properties of the fabricated WBGs are investigated both theoretically and experimentally. The results confirm single mode guidance, relatively high coupling efficiency, as well as large negative group velocity dispersions in the range of several -100's ps/(THz · cm) in the vicinity of 0.14THz. This makes the short sections of proposed WBGs suitable for compensating positive dispersion incurred in the THz wireless links or fiber-assisted THz interconnects for signals of several-GHz bandwidth. Finally, we comment on the challenges associated with the analog signal processing in the THz spectral range.

Piezoelectric Microstructured Fibers via Drawing of Multimaterial Preforms.

We demonstrate planar laminated piezoelectric generators and piezoelectric microstructured fibers based on BaTiO3-polyvinylidene and carbon-loaded-polyethylene materials combinations. The laminated piezoelectric generators were assembled by sandwiching the electrospun BaTiO3-polyvinylidene mat between two carbon-loaded-polyethylene films. The piezoelectric microstructured fiber was fabricated via drawing of the multilayer fiber preform, and features a swissroll geometry that have ~10 alternating piezoelectric and conductive layers. Both piezoelectric generators have excellent mechanical durability, and could retain their piezoelectric performance after 3 day's cyclic bend-release tests. Compared to the laminated generators, the piezoelectric fibers are advantageous as they could be directly woven into large-area commercial fabrics. Potential applications of the proposed piezoelectric fibers include micro-power-generation and remote sensing in wearable, automotive and aerospace industries.

3D printed hollow core terahertz Bragg waveguides with defect layers for surface sensing applications.

We study a 3D-printed hollow core terahertz (THz) Bragg waveguide for resonant surface sensing applications. We demonstrate theoretically and confirm experimentally that by introducing a defect in the first layer of the Bragg reflector, thereby causing anticrossing between the dispersion relations of the core-guided mode and the defect mode, we can create a sharp transmission dip in the waveguide transmission spectrum. By tracking changes in the spectral position of the narrow transmission dip, one can build a sensor, which is highly sensitive to the optical properties of the defect layer. To calibrate our sensor, we use PMMA layers of various thicknesses deposited onto the waveguide core surface. The measured sensitivity to changes in the defect layer thickness is found to be 0.1 GHz/µm. Then, we explore THz resonant surface sensing using α-lactose monohydrate powder as an analyte. We employ a rotating THz Bragg fiber and a semi-automatic powder feeder to explore the limit of the analyte thickness detection using a surface modality. We demonstrate experimentally that powder layer thickness variations as small as 3µm can be reliably detected with our sensor. Finally, we present a comparative study of the time-domain spectroscopy versus continuous wave THz systems supplemented with THz imaging for resonant surface sensing applications.

Piezoelectric Micro- and Nanostructured Fibers Fabricated from Thermoplastic Nanocomposites Using a Fiber Drawing Technique: Comparative Study and Potential Applications.

We report an all-polymer flexible piezoelectric fiber that uses both judiciously chosen geometry and advanced materials in order to enhance fiber piezoelectric response. The microstructured/nanostructured fiber features a soft hollow polycarbonate core surrounded by a spiral multilayer cladding consisting of alternating layers of piezoelectric nanocomposites (polyvinylidene enhanced with BaTiO3, PZT, or CNT) and conductive polymer (carbon-filled polyethylene). The conductive polymer layers serve as two electrodes, and they also form two spatially offset electric connectors on the fiber surface designed for the ease of connectorization. Kilometer-long piezoelectric fibers of sub-millimeter diameters are thermally drawn from a macroscopic preform. The fibers exhibit high output voltage of up to 6 V under moderate bending, and they show excellent mechanical and electrical durability in a cyclic bend-release test. The micron/nanosize multilayer structure enhances in-fiber poling efficiency due to the small distance between the conducting electrodes sandwiching the piezoelectric composite layers. Additionally, the spiral structure greatly increases the active area of the piezoelectric composite, thus promoting higher voltage generation and resulting in 10-100 higher power generation efficiency over the existing piezoelectric cables. Finally, we weave the fabricated piezoelectric fibers into technical textiles and demonstrate their potential applications in power generation when used as a sound detector, smart car seat upholstery, or wearable materials.

Effect of Aging and PCBM Content on Bulk Heterojunction Organic Solar Cells Studied by Intensity Modulated Photocurrent Spectroscopy.

A series of encapsulated and nonencapsulated bulk heterojunction photovoltaic devices containing poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61 butyric acid methyl ester (PCBM) with different P3HT:PCBM ratios were investigated using traditional steady-state as well as non-steady-state intensity modulated photocurrent spectroscopy (IMPS) techniques. The steady state J-V measurements showed that PCBM content did not have a significant effect on the efficiency for freshly prepared devices, whereas aged nonencapsulated devices exhibited a strong dependence on PCBM content. IMPS measurements showed a significant contribution of interfacial nongeminate recombination in nonencapsulated devices, which increased with decreasing PCBM content in the photoactive layer and cell aging. It was related to the formation of interfacial states at the P3HT/PCBM interface due to atmospheric contamination, which act as recombination centers. Device encapsulation was found to be effective in preventing the occurrence of interfacial recombination. Our results suggest that IMPS can be used as a diagnostic tool to predict the performance of bulk heterojunction organic solar cells. If a solar cell shows the presence of interfacial states as indicated by semicircle arcs in quadrant I of the IMPS complex plane plots, it is most likely that its performance will deteriorate with time due to enhanced interfacial recombination, even without further exposure to atmospheric contaminations. We conclude that interfacial nongeminate recombination is an important degradation mechanism in organic solar cells, especially in the case of exposure to atmospheric contaminants.

Squeezed hollow-core photonic Bragg fiber for surface sensing applications.

We propose to use squeezed hollow-core photonic bandgap Bragg fibers for surface sensing applications. We demonstrate theoretically and confirm experimentally that squeezing a section of the Bragg fiber core increases overlap between the optical fields of the core guided modes and the modes bound to the sensing layer, thus, significantly enhancing their interaction via anticrossing phenomenon, which, in turn, enhances surface sensitivity of the fiber sensor. As a practical demonstration, we apply our fiber sensor to in situ monitoring of the dissolution dynamics of a sub-micron-thick polyvinyl butyral (PVB) film coated on the surface of the liquid-filled Bragg fiber core. Strong spectral shift is observed during the dissolution of the PVB film, and a surface spectral sensitivity of ~0.07nm/nm is achieved experimentally with aqueous analytes. The proposed fiber sensor offers a new sensing modality and opens new sensing applications for photonic bandgap fibers, such as real-time detection of binding and affinity, study of kinetics, etc. for a range of chemical and biological samples.

Nanotechnology in Textiles.

Increasing customer demand for durable and functional apparel manufactured in a sustainable manner has created an opportunity for nanomaterials to be integrated into textile substrates. Nanomoieties can induce stain repellence, wrinkle-freeness, static elimination, and electrical conductivity to fibers without compromising their comfort and flexibility. Nanomaterials also offer a wider application potential to create connected garments that can sense and respond to external stimuli via electrical, color, or physiological signals. This review discusses electronic and photonic nanotechnologies that are integrated with textiles and shows their applications in displays, sensing, and drug release within the context of performance, durability, and connectivity. Risk factors including nanotoxicity, nanomaterial release during washing, and environmental impact of nanotextiles based on life cycle assessments have been evaluated. This review also provides an analysis of nanotechnology consolidation in the textiles market to evaluate global trends and patent coverage, supplemented by case studies of commercial products. Perceived limitations of nanotechnology in the textile industry and future directions are identified.

Simultaneous monitoring the real and imaginary parts of the analyte refractive index using liquid-core photonic bandgap Bragg fibers.

We demonstrate simultaneous monitoring of the real and imaginary parts of the liquid analyte refractive index by using a hollow-core Bragg fiber. We apply this two-channel fiber sensor to monitor concentrations of various commercial cooling oils. The sensor operates using spectral monitoring of the fiber bandgap center wavelength, as well as monitoring of the fiber transmission amplitude at mid-bandgap position. The sensitivity of the fiber sensor to changes in the real part of the core refractive index is found to be 1460nm/Refractive index unit (RIU). By using spectral modality and effective medium theory, we determine the concentrations of the two commercial fluids from the measured refractive indices with an accuracy of ~0.57% for both low- and high-loss oils. Moreover, using an amplitude-based detection modality allows determination of the oil concentration with accuracy of ~1.64% for low-loss oils and ~2.81% for the high-loss oils.