ABSTRACT
The PdGa intermetallic compound is a highly selective and stable heterogeneous hydrogenation catalyst for the semi-hydrogenation of acetylene. We have studied single crystals of PdGa grown by the Czochralski technique. The (69)Ga electric-field-gradient (EFG) tensor was determined by means of NMR spectroscopy, giving experimental confirmation of both the recently refined structural model of PdGa and the theoretically predicted Pd-Ga covalent bonding scheme. The hydrogenation experiment has detected no hydrogen uptake in the PdGa, thus preventing in situ hydride formation that leads to a reduction of the catalytic selectivity. We have also determined bulk physical properties (the magnetic susceptibility, the electrical resistivity, the thermoelectric power, the Hall coefficient, the thermal conductivity and the specific heat) of single-crystalline PdGa. The results show that PdGa is a diamagnet with metallic electrical resistivity and moderately high thermal conductivity. The thermoelectric power is negative with complicated temperature dependence, whereas the Hall coefficient is positive and temperature-dependent, indicating complexity of the Fermi surface. Partial fulfillment of the NMR Korringa relation reveals that the charge carriers are weakly correlated. Specific heat measurements show that the density of electronic states (DOS) at the Fermi energy of PdGa is reduced to 15% of the DOS of the elemental Pd metal.
ABSTRACT
The thermal conductivity kappa in the basal plane of single-crystalline hexagonal NbSe2 has been measured as a function of magnetic field H, oriented both along and perpendicular to the c axis, at several temperatures below T(c). With the magnetic field in the basal plane and oriented parallel to the heat flux we observed, in fields well below H(c2), an unexpected hysteretic behavior of kappa(H) with all the generic features of a first order phase transition. The transition is not manifest in the kappa(H) curves, if H is still in the basal plane but oriented perpendicularly to the heat-flux direction. The origin of the transition is not yet understood.
