ABSTRACT
As the industry develops and energy demand increases, wind turbines are increasingly being used to generate electricity, resulting in an increasing number of obsolete turbine blades that need to be properly recycled or used as a secondary raw material in other industries. The authors of this work propose an innovative technology not yet studied in the literature, where the wind turbine blades are mechanically shredded and micrometric fibers are formed from the obtained powder using plasma technologies. As shown by SEM and EDS studies, the powder is composed of irregularly shaped microgranules and the carbon content in the obtained fiber is lower by up to seven times compared with the original powder. Meanwhile, the chromatographic studies show that no hazardous to the environment gases are formed during the fiber production. It is worth mentioning that this fiber formation technology can be one of the additional methods for recycling wind turbine blades, and the obtained fiber can be used as a secondary raw material in the production of catalysts, construction materials, etc.
ABSTRACT
This study investigated biomass (wood pellets) gasification to syngas using direct current (DC) thermal arc plasma at atmospheric pressure. Water vapor was used as a main gasifying agent and a plasma-forming gas. The biomass gasification system was quantified in terms of the producer gas composition, the tar content, the H2/CO ratio, the carbon conversion efficiency, the energy conversion efficiency and the specific energy requirements. It was found that the gasification performance efficiency was highest at the water vapor-to-biomass ratio of 0.97. The producer gas was mostly composed of H2 (43.86 vol.%) and CO (30.93 vol.%), giving the H2/CO ratio of 1.42 and the LHV of 10.23 MJ/Nm3. However, high content of tars of 13.81 g/Nm3 was obtained in the syngas. The yield of H2 and CO was 48.31% and 58.13%, respectively, with the highest producer gas yield of 2.42 Nm3/kg biomass. The carbon conversion efficiency and the energy conversion efficiency were 100% and 48.83%, respectively, and the production of 1 kg of syngas required 1.78 kWh of electric energy input. Finally, the obtained results were compared with different plasma methods, including plasma-assisted application coupled with conventional gasification.
ABSTRACT
Soil pollution with petroleum-based fuels is a serious issue causing environmental problems. Recently, the use of plasma technologies for soil remediation has shown an interest and great potential. The remediation process can be performed in a fast timeframe without adding supplementary chemical reagents or without additional pre-treatment of the polluted soil. As a result, the use of plasma enables to obtain highly effective degradation of pollutants. Thus, in the present experimental research, diesel fuel removal from contaminated soil by utilizing thermal water vapor arc plasma was investigated. It was found that increased concentration of diesel fuel in the soil raised carbon and hydrogen concentrations in the soil. Moreover, soil surface morphology was modified by causing the formation of bigger agglomerates. It was also determined that after the plasma treatment process, soil grains became akin in size and structure to clean soil grains. A complete desorption of carbon, which came from diesel fuel to the soil, and a slight decomposition of organic carbon present in the soil were observed during the soil remediation process. Thermogravimetric analysis showed that regardless of the diesel fuel concentration in the soil, four stages of mass loss were observed: moisture loss, vaporization, and combustion of diesel fuel as well as reduction of volatiles and char in the soil. Producer gas analysis indicated that during soil remediation diesel fuel was mainly converted to synthesis gas, i.e., a mixture of H2, CO, and CO2. Moreover, the decomposition of diesel fuel and the formation of synthesis gas depended on the amount of pollutant in the soil. According to the obtained results, thermal water vapor arc plasma was able to completely remove diesel fuel from polluted soil in the form of synthesis gas with no significant influence on soil's properties.
