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J Agric Food Chem ; 65(48): 10571-10581, 2017 Dec 06.
Article in English | MEDLINE | ID: mdl-29113432

ABSTRACT

In this study, graphene oxide (GO) was investigated as a potential nanoreinforcing agent in starch/lignin (ST/L) biopolymer matrix. Bionanocomposite films based on ST/L blend matrix and GO were prepared by solution-casting technique of the corresponding film-forming solution. The structures, morphologies, and properties of bionanocomposite films were characterized by Fourier transform infrared (FTIR), thermal gravimetric analysis (TGA), ultraviolet-visible (UV-vis), SEM, and tensile tests. The experimental results showed that content of GO have a significant influence on the mechanical properties of the produced films. The results revealed that the interfacial interaction formed in the bionanocomposite films improved the compatibility between GO fillers and ST/L matrix. The addition of GO also reduced moisture uptake (Mu) and water vapor permeability of ST/L blend film. In addition, TGA showed that the thermal stability of bionanocomposite films was better than that of neat starch film. These findings confirmed the effectiveness of the proposed approach to produce biodegradable films with enhanced properties, which may be used in packaging applications.


Subject(s)
Graphite/chemistry , Lignin/chemistry , Nanocomposites/chemistry , Oxides/chemistry , Starch/chemistry , Mechanical Phenomena , Permeability , Spectroscopy, Fourier Transform Infrared , Thermogravimetry
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