Alteration of biomass toxicity in torrefaction - A XDS-CALUX bioassay study.

Torrefaction constitutes one of the promising technologies for the management of waste biomass and the production of high-carbon products for combustion, gasification, adsorption of pollutants or soil treatment. Unfortunately, waste biomass may be contaminated with toxic persistent organic pollutants, such as polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDF) and dioxin-like biphenyls (dl-PCB). Literature does not provide consistent measurements on how the low-temperature thermochemical processing, such as torrefaction, affects the toxicity of biomass. This contribution assesses how a torrefaction treatment, conducted at 200 °C, modifies the toxicity due to PCDD/PCDF/dl-PCB in biomass. We deploy the XDS-CALUX biotest on five types of waste biomass (sewage sludge, tree bark, cattle manure, spent coffee ground, common reed), before and after treatment. The content of total dioxin- & biphenyl fraction compounds in the raw biomass, investigated in this study, varies from 0.14 to 3.67 pg BEQ·g-1d.m., and in the torrefied biomass between 0.17 and 6.00 pg BEQ·g-1d.m.; BEQ stands for bioanalytical equivalent. This increase is statistically insignificant at p = 0.05, taking into account all types of examined biomass. This proves that low-temperature torrefaction cannot detoxify biomass, i.e., chars, produced from biomass characterized by elevated concentration of PCDD/PCDF/dl-PCB, will reflect the contamination of the feedstocks. With respect to heavy metals, we conclude that only the content of Cd in biomass, and, to a lesser extent, the abundance of Cu and Fe, modify the toxicity of this material during its thermochemical treatment at low temperature.

Bonitation assessment of intensively used football turf depending on the date and area of observation.

This article aimed to evaluate the visual and functional characteristics of intensively used football turf over 10 years, depending on the different areas of the game. The research was conducted on the football turf of the AZS Environmental Club in Wroclaw (N: 51° 7' 31'' E:17° 4' 14''). High variability of the evaluated parameters was observed regarding seasonality, year of observation, and the area of play. It has been shown that the goal area and penalty box areas have the lowest functional value, which are vital areas of the game from the point of view of gaining an advantage in the game. Also, these places are more susceptible to creating sites without plants (requiring additional overseeding) due to the potential of hollowing and goalkeeper interventions ending with the body landing on the ground. The middle area was characterized by the highest overall aspect, color, and turf density values. In the vast majority of cases, there was a downward trend in the turfs' functional value with the turf's age, which is an essential finding in the context of the use of intensively used, athletic natural grass surfaces.

The influence of the grass mixture composition on the quality and suitability for football pitches.

The selection of grass mixtures with appropriate visual and functional parameters for sowing football fields is a key element in shaping the sports infrastructure, ensuring the spectacularity of a match and comfort for players. The aim of the research was to investigate the properties of lawn grass mixtures and their suitability for football pitches. The experiment was conducted at the Toya Golf & Country Club (51° 20' E, 17° 07' N), Wroclaw, Poland, between 2007 and 2009. 12 grass mixtures were selected, mainly based on red fescue, Kentucky bluegrass, and perennial ryegrass. The assessment was carried out using a nine-point scale, according to the Plant Variety Office methodology for crops and turf grass. Six features of sports turf were studied: appearance, density, colour, leaf fineness, overwintering, and susceptibility to disease and they significantly varied, depending on the grass mixture and the year of research. Our study showed that mixtures based on the dominance of meadow grass were characterized by higher values of the general visual aspect, colour and slenderness of the leaf blade and these based on the dominance of perennial ryegrass and co-dominance of perennial ryegrass and meadow grass were the most useful in terms of wintering, resistance to diseases and sodding.