An overlooked mechanism underlying the attenuated temperature response of soil heterotrophic respiration.

Biogeochemical reactions occurring in soil pore space underpin gaseous emissions measured at macroscopic scales but are difficult to quantify due to their complexity and heterogeneity. We develop a volumetric-average method to calculate aerobic respiration rates analytically from soil with microscopic soil structure represented explicitly. Soil water content in the model is the result of the volumetric-average of the microscopic processes, and it is nonlinearly coupled with temperature and other factors. Since many biogeochemical reactions are driven by oxygen (O2) which must overcome various resistances before reaching reactive microsites from the atmosphere, the volumetric-average results in negative feedback between temperature and soil respiration, with the magnitude of the feedback increasing with soil water content and substrate quality. Comparisons with various experiments show the model reproduces the variation of carbon dioxide emission from soils under different water content and temperature gradients, indicating that it captures the key microscopic processes underpinning soil respiration. We show that alongside thermal microbial adaptation, substrate heterogeneity and microbial turnover and carbon use efficiency, O2 dissolution and diffusion in water associated with soil pore space is another key explanation for the attenuated temperature response of soil respiration and should be considered in developing soil organic carbon models.

Quantifying the Surface Strain Field Induced by Active Sources with Distributed Acoustic Sensing: Theory and Practice.

Quantitative dynamic strain measurements of the ground would be useful for engineering scale problems such as monitoring for natural hazards, soil-structure interaction studies, and non-invasive site investigation using full waveform inversion (FWI). Distributed acoustic sensing (DAS), a promising technology for these purposes, needs to be better understood in terms of its directional sensitivity, spatial position, and amplitude for application to engineering-scale problems. This study investigates whether the physical measurements made using DAS are consistent with the theoretical transfer function, reception patterns, and experimental measurements of ground strain made by geophones. Results show that DAS and geophone measurements are consistent in both phase and amplitude for broadband (10 s of Hz), high amplitude (10 s of microstrain), and complex wavefields originating from different positions around the array when: (1) the DAS channels and geophone locations are properly aligned, (2) the DAS cable provides good deformation coupling to the internal optical fiber, (3) the cable is coupled to the ground through direct burial and compaction, and (4) laser frequency drift is mitigated in the DAS measurements. The transfer function of DAS arrays is presented considering the gauge length, pulse shape, and cable design. The theoretical relationship between DAS-measured and pointwise strain for vertical and horizontal active sources is introduced using 3D elastic finite-difference simulations. The implications of using DAS strain measurements are discussed including directionality and magnitude differences between the actual and DAS-measured strain fields. Estimating measurement quality based on the wavelength-to-gauge length ratio for field data is demonstrated. A method for spatially aligning the DAS channels with the geophone locations at tolerances less than the spatial resolution of a DAS system is proposed.

Impacts of underground climate change on urban geothermal potential: Lessons learnt from a case study in London.

While urban underground is being increasingly used for various purposes, two concerns should be addressed with respect to the urban underground climate change: i) how much energy has been stored in urban subsurface due to the heat rejection from underground heated spaces (such as tunnels and basements) and ii) how much of the thermal demand of a city or district can be supplied by harvesting this accumulative thermal energy in the ground. However, our understanding of the temperature rise in the ground and of the geothermal potential of urban subsurface is still limited. This paper quantifies the geothermal potential for a 12 km2 densely populated borough in central London by considering the spatio-temporal temperature variation in the ground owing to continuous rejection of heat into the ground, coupled with the effect of geothermal extraction capacity. A large-scale transient semi-3D geothermal subsurface model of the site is developed, and the thermal interaction between underground heated spaces, geothermal energy extraction systems and the ground and groundwater are simulated. The concurrent heat rejection and extraction processes in the subsurface are computed so that the most influencing parameters of the subsurface on its geothermal potential are identified. Results show that up to 50% of the borough's total heat demand can be supplied via geothermal installations leading to around 33% reduction in CO2 emission. The geothermal extraction efficiency in sand and gravel primarily depends on the ground conditions such as the thickness of the permeable layer and the groundwater flow regime. In impermeable ground such as clay, however, the underground built environment such as heated spaces have shown to have a significant impact on improving the geothermal extraction efficiency.

The role of bacterial urease activity on the uniformity of carbonate precipitation profiles of bio-treated coarse sand specimens.

Protocols for microbially induced carbonate precipitation (MICP) have been extensively studied in the literature to optimise the process with regard to the amount of injected chemicals, the ratio of urea to calcium chloride, the method of injection and injection intervals, and the population of the bacteria, usually using fine- to medium-grained poorly graded sands. This study assesses the effect of varying urease activities, which have not been studied systematically, and population densities of the bacteria on the uniformity of cementation in very coarse sands (considered poor candidates for treatment). A procedure for producing bacteria with the desired urease activities was developed and qPCR tests were conducted to measure the counts of the RNA of the Ure-C genes. Sand biocementaton experiments followed, showing that slower rates of MICP reactions promote more effective and uniform cementation. Lowering urease activity, in particular, results in progressively more uniformly cemented samples and it is proven to be effective enough when its value is less than 10 mmol/L/h. The work presented highlights the importance of urease activity in controlling the quality and quantity of calcium carbonate cements.

Characterisation of CaCO3 phases during strain-specific ureolytic precipitation.

Numerous microbial species can selectively precipitate mineral carbonates with enhanced mechanical properties, however, understanding exactly how they achieve this control represents a major challenge in the field of biomineralisation. We have studied microbial induced calcium carbonate (CaCO3) precipitation (MICP) in three ureolytic bacterial strains from the Sporosarcina family, including S. newyorkensis, a newly isolated microbe from the deep sea. We find that the interplay between structural water and strain-specific amino acid groups is fundamental to the stabilisation of vaterite and that, under the same conditions, different isolates yield distinctly different polymorphs. The latter is found to be associated with different urease activities and, consequently, precipitation kinetics, which change depending on pressure-temperature conditions. Further, CaCO3 polymorph selection also depends on the coupled effect of chemical treatment and initial bacterial concentrations. Our findings provide new insights into strain-specific CaCO3 polymorphic selection and stabilisation, and open up promising avenues for designing bio-reinforced geo-materials that capitalise on the different particle bond mechanical properties offered by different polymorphs.

Large-scale urban underground hydro-thermal modelling - A case study of the Royal Borough of Kensington and Chelsea, London.

The shallow subsurface of dense cities is increasingly exploited for various purposes due to the significant rise in urban populations. Past research has shown that underground activities have a significant impact on local subsurface temperatures. However, the resulting spatial variability of ground temperature elevations on a city-scale is not well understood due to the lack of sufficient information and modelling complexity at such large scales. Resilient and sustainable planning of underground developments and geothermal exploitation in the short and long-term necessitate more detailed, more reliable knowledge of subsurface thermal status. This paper investigates the impact of some common underground heat sources such as train tunnels and residential basements on subsurface temperature elevation on a large scale and highlights the influence of local geology, hydrogeology, density, and type and arrangement of the heat sources on ground thermal disturbance. To tackle the size issues and computational expenses of such a large-scale problem, a semi-3D hydro-thermal numerical approach is presented to capture the combined influence of underground built environment characteristics coupled with ground properties on ground temperature elevation within the Royals Borough of Kensington and Chelsea (RBKC), London. Numerical results show that the extent of ground thermal disturbance is mostly affected by geological and hydrogeological characteristics in permeable ground (River Terrace Deposits). Density and spatial distribution of heat sources, however, are critical parameters in ground temperature evaluation in highly impermeable ground such as London Clay Formation. The locality of temperature rise and potential ground energy within immediate impermeable ground surrounding heat sources versus significantly large extent of ground thermal disturbance in permeable ground, highlights the significant dependency of ground thermal state and geothermal potential at the studied site to the ground and underground built environment characteristics and necessitates a better understanding of shallow subsurface thermal state for a sustainable and resilient urban underground development.

Frequency uncertainty improvement in a STFT-BOTDR using highly nonlinear optical fibers.

The sensitivity of a sensor to strain or the temperature variations due to distributed Brillouin scattering are partially related to the type of fibers used and the Brillouin scattering induced effective index. In this paper, a highly nonlinear fiber that can generate a higher Brillouin scattering signal is compared to a standard single mode fiber in a short-time-Fourier-transform Brillouin optical time domain reflectometer (STFT-BOTDR). The results show that much higher signal to noise ratios of the Brillouin scattering spectrum and smaller frequency uncertainties in the sensing measurement can be achieved in the highly nonlinear fiber for comparable launched powers. With a measurement speed of 4 Hz, the frequency uncertainty can be 0.43 MHz, corresponding to 10 µÎµ in strain or 0.43°C in temperature uncertainty for the highly nonlinear fiber. In contrast, for the standard single mode fiber case, the value would increase to about 1.02 MHz (25 µÎµ or 1.02°C), demonstrating the advantage of the highly nonlinear fiber for distributed strain/temperature sensing.

Integrity Testing of Pile Cover Using Distributed Fibre Optic Sensing.

The integrity of cast-in-place foundation piles is a major concern in geotechnical engineering. In this study, distributed fibre optic sensing (DFOS) cables, embedded in a pile during concreting, are used to measure the changes in concrete curing temperature profile to infer concrete cover thickness through modelling of heat transfer processes within the concrete and adjacent ground. A field trial was conducted at a high-rise building construction site in London during the construction of a 51 m long test pile. DFOS cables were attached to the reinforcement cage of the pile at four different axial directions to obtain distributed temperature change data along the pile. The monitoring data shows a clear development of concrete hydration temperature with time and the pattern of the change varies due to small changes in concrete cover. A one-dimensional axisymmetric heat transfer finite element (FE) model is used to estimate the pile geometry with depth by back analysing the DFOS data. The results show that the estimated pile diameter varies with depth in the range between 1.40 and 1.56 m for this instrumented pile. This average pile diameter profile compares well to that obtained with the standard Thermal Integrity Profiling (TIP) method. A parametric study is conducted to examine the sensitivity of concrete and soil thermal properties on estimating the pile geometry.

Infrastructure sensing.

Design, construction, maintenance and upgrading of civil engineering infrastructure requires fresh thinking to minimize use of materials, energy and labour. This can only be achieved by understanding the performance of the infrastructure, both during its construction and throughout its design life, through innovative monitoring. Advances in sensor systems offer intriguing possibilities to radically alter methods of condition assessment and monitoring of infrastructure. In this paper, it is hypothesized that the future of infrastructure relies on smarter information; the rich information obtained from embedded sensors within infrastructure will act as a catalyst for new design, construction, operation and maintenance processes for integrated infrastructure systems linked directly with user behaviour patterns. Some examples of emerging sensor technologies for infrastructure sensing are given. They include distributed fibre-optics sensors, computer vision, wireless sensor networks, low-power micro-electromechanical systems, energy harvesting and citizens as sensors.

Double peak-induced distance error in short-time-Fourier-transform-Brillouin optical time domain reflectometers event detection and the recovery method.

The measured distance error caused by double peaks in the BOTDRs (Brillouin optical time domain reflectometers) system is a kind of Brillouin scattering spectrum (BSS) deformation, discussed and simulated for the first time in the paper, to the best of the authors' knowledge. Double peak, as a kind of Brillouin spectrum deformation, is important in the enhancement of spatial resolution, measurement accuracy, and crack detection. Due to the variances of the peak powers of the BSS along the fiber, the measured starting point of a step-shape frequency transition region is shifted and results in distance errors. Zero-padded short-time-Fourier-transform (STFT) can restore the transition-induced double peaks in the asymmetric and deformed BSS, thus offering more accurate and quicker measurements than the conventional Lorentz-fitting method. The recovering method based on the double-peak detection and corresponding BSS deformation can be applied to calculate the real starting point, which can improve the distance accuracy of the STFT-based BOTDR system.

Transient dynamics of a 2D granular pile.

We investigate by means of Contact Dynamics simulations the transient dynamics of a 2D granular pile set into motion by applying shear velocity during a short time interval to all particles. The spreading dynamics is directly controlled by the input energy whereas in recent studies of column collapse the dynamics scales with the initial potential energy of the column. As in column collapse, we observe a power-law dependence of the runout distance with respect to the input energy with nontrivial exponents. This suggests that the power-law behavior is a generic feature of granular dynamics, and the values of the exponents reflect the distribution of kinetic energy inside the material. We observe two regimes with different values of the exponents: the low-energy regime reflects the destabilization of the pile by the impact with a runout time independent of the input energy whereas the high-energy regime is governed by the input energy. We show that the evolution of the pile in the high-energy regime can be described by a characteristic decay time and the available energy after the pile is destabilized.

Initiation of immersed granular avalanches.

By means of coupled molecular dynamics-computational fluid dynamics simulations, we analyze the initiation of avalanches in a granular bed of spherical particles immersed in a viscous fluid and inclined above its angle of repose. In quantitative agreement with experiments, we find that the bed is unstable for a packing fraction below 0.59 but is stabilized above this packing fraction by negative excess pore pressure induced by the effect of dilatancy. From detailed numerical data, we explore the time evolution of shear strain, packing fraction, excess pore pressures, and granular microstructure in this creeplike pressure redistribution regime, and we show that they scale excellently with a characteristic time extracted from a model based on the balance of granular stresses in the presence of a negative excess pressure and its interplay with dilatancy. The cumulative shear strain at failure is found to be ≃ 0.2, in close agreement with the experiments, irrespective of the initial packing fraction and inclination angle. Remarkably, the avalanche is triggered when dilatancy vanishes instantly as a result of fluctuations while the average dilatancy is still positive (expanding bed) with a packing fraction that declines with the initial packing fraction. Another nontrivial feature of this creeplike regime is that, in contrast to dry granular materials, the internal friction angle of the bed at failure is independent of dilatancy but depends on the inclination angle, leading therefore to a nonlinear dependence of the excess pore pressure on the inclination angle. We show that this behavior may be described in terms of the contact network anisotropy, which increases with a nearly constant connectivity and levels off at a value (critical state) that increases with the inclination angle. These features suggest that the behavior of immersed granular materials is controlled not only directly by hydrodynamic forces acting on the particles but also by the influence of the fluid on the granular microstructure.

Soil engineering in vivo: harnessing natural biogeochemical systems for sustainable, multi-functional engineering solutions.

Carbon sequestration, infrastructure rehabilitation, brownfields clean-up, hazardous waste disposal, water resources protection and global warming-these twenty-first century challenges can neither be solved by the high-energy consumptive practices that hallmark industry today, nor by minor tweaking or optimization of these processes. A more radical, holistic approach is required to develop the sustainable solutions society needs. Most of the above challenges occur within, are supported on, are enabled by or grown from soil. Soil, contrary to conventional civil engineering thought, is a living system host to multiple simultaneous processes. It is proposed herein that 'soil engineering in vivo', wherein the natural capacity of soil as a living ecosystem is used to provide multiple solutions simultaneously, may provide new, innovative, sustainable solutions to some of these great challenges of the twenty-first century. This requires a multi-disciplinary perspective that embraces the science of biology, chemistry and physics and applies this knowledge to provide multi-functional civil and environmental engineering designs for the soil environment. For example, can native soil bacterial species moderate the carbonate cycle in soils to simultaneously solidify liquefiable soil, immobilize reactive heavy metals and sequester carbon-effectively providing civil engineering functionality while clarifying the ground water and removing carbon from the atmosphere? Exploration of these ideas has begun in earnest in recent years. This paper explores the potential, challenges and opportunities of this new field, and highlights one biogeochemical function of soil that has shown promise and is developing rapidly as a new technology. The example is used to propose a generalized approach in which the potential of this new field can be fully realized.

The significance of heterogeneity on mass flux from DNAPL source zones: an experimental investigation.

Understanding the process of mass transfer from source zones of aquifers contaminated with organic chemicals in the form of dense non-aqueous phase liquids (DNAPL) is of importance in site management and remediation. A series of intermediate-scale tank experiments was conducted to examine the influence of aquifer heterogeneity on DNAPL mass transfer contributing to dissolved mass emission from source zone into groundwater under natural flow before and after remediation. A Tetrachloroethylene (PCE) spill was performed into six source zone models of increasing heterogeneity, and both the spatial distribution of the dissolution behavior and the net effluent mass flux were examined. Experimentally created initial PCE entrapment architecture resulting from the PCE migration was largely influenced by the coarser sand lenses and the PCE occupied between 30 and 60% of the model aquifer depth. The presence of DNAPL had no apparent effect on the bulk hydraulic conductivity of the porous media. Up to 71% of PCE mass in each of the tested source zone was removed during a series of surfactant flushes, with associated induced PCE mobilization responsible for increasing vertical DNAPL distributions. Effluent mass flux due to water dissolution was also found to increase progressively due to the increase in NAPL-water contact area even though the PCE mass was reduced. Doubling of local groundwater flow velocities showed negligible rate-limited effects at the scale of these experiments. Thus, mass transfer behavior was directly controlled by the morphology of DNAPL within each source zone. Effluent mass flux values were normalized by the up-gradient DNAPL distributions. For the suite of aquifer heterogeneities and all remedial stages, normalized flux values fell within a narrow band with mean of 0.39 and showed insensitivity to average source zone saturations.