ABSTRACT
Background: This study assessed the effect of different concentrations of 4-methacryloyloxyethy trimellitate anhydride (4-META) added to silane on microtensile bond strength (µTBS) of light-cure and dual-cure resin cement to hybrid and zirconia-reinforced lithium silicate ceramics. Materials and Methods: This in vitro, experimental study was conducted on 32 Celtra Duo and 32 VITA Enamic ceramics bonded to Allcem Veneer light-cure and Allcem dual-cure resin cements using silane impregnated with 4-META in 0%, 2.5%, 5%, and 10 wt% concentrations in 16 groups (n = 4). The µTBS of specimens was measured by a universal testing machine and analyzed by the Kruskal-Wallis and Mann-Whitney tests, and the mode of failure was determined under a stereomicroscope and analyzed by the Chi-square test (alpha = 0.05). Results: The lowest mean µTBS was recorded in the Enamic ceramic group with 4-META (0%) bonded to dual-cure cement (14.26 MPa), and the highest mean µTBS was recorded in Enamic ceramic with 4-META (10%) bonded to light-cure cement (18.59 MPa) (P < 0.001). The µTBS of Celtra Duo was significantly higher than that of Enamic in bonding to light-cure cement using 4-META (2.5%) (P = 0.003). All failures (100%) were adhesive in most groups. The frequency of adhesive failure was the lowest (90%) in Celtra Duo bonded to dual-cure cement with 4-META (5%). Conclusion: According to the results of this pilot study, the addition of 4-META (10%) to silane caused a significant improvement in µTBS to light-cure cement. The addition of 4-META in all concentrations significantly improved the µTBS to Enamic ceramic in the use of dual-cure cement; however, it had no significant effect on µTBS of Celtra Duo. Nonetheless, the results should be interpreted with caution due to the relatively small sample size.
ABSTRACT
BACKGROUND: Silane promotes bonding between ceramic and resin cement. Silane function could be improved by heat treatment and adding 4-Methacryloxyethyl trimellitate anhydride (4-META). The aim of this study was to assess the effect of heat treatment and adding 4-META to silanes on the microtensile bond strength of IPS e.max CAD ceramic and resin cement. MATERIALS AND METHODS: In this in vitro study, 32 IPS e.max CAD blocks (6 mm × 6 mm × 4 mm) were randomly divided into 8 groups of 4. The ceramic surfaces were etched by 10% hydrofluoric (HF) for 20 s, and Clearfil Ceramic Primer Plus, Clearfil Porcelain Bond Activator (CPA) +4-META, CPA + Clearfil SE Bond (CPA + SE), and Bis-Silane with and without Oven drying at 100°C for 5 min were applied on the ceramic surfaces as silanes, and then, the ceramics were bonded to composite disks by dual-cured resin cements. Ultimately, a total of 120 sticks ( 1 mm × 1 mm × 8 mm) were subjected to microtensile bond strength test (15 sticks from each group) and the failure types were assessed by stereomicroscope at 40x. Data were analyzed by two-sided analysis of variance test and Student's t-test the P values were considered to be < 0.05. RESULTS: The Bis Silane group (two bottles) showed maximum bond strength (P = 0.009). Heat treatment significantly reduced the bond strength in Bis Silane (P = 0.0001); but, in other groups, it did not show significant effect on the bond strength. Adding 4-META to CPA did not significantly affect the microtensile bond strength of IPS e.max CAD ceramic to resin cement, and there was no difference in mode of failure between groups. CONCLUSION: The effect of silane type was significant on the microtensile bond strength of the ceramic to resin cement. The effect of 4-META on the bond strength was not significant. The interaction between silane type and heat treatment on the bond strength of ceramic to resin cement was also significant.
