ABSTRACT
Nanoscale friction behavior on hydrophilic surfaces (HS), influenced by a probe gliding on a confined water layer, has been investigated with friction force microscopy under various relative humidity (RH) conditions. The topographical and frictional responses of the mechanically exfoliated single-layer graphene (SLG) on native-oxide-covered silicon (SiO2/Si) and mica were both influenced by RH conditions. The ordinary phenomena at ambient conditions (i.e., higher friction on a HS than on a SLG due to different hydrophilicity), nondistinguishable height, friction of SLG with SiO2/Si at high RH (>98%), and the superlubricating behavior of friction on a HS were observed. Furthermore, the subdomain within SLG, consisting of an ice-like water layer intercalated between SLG and SiO2/Si, showed friction enhancement. These results suggest that the abundant water molecules at the interface of the probe and a HS can make a slippery surface that overcomes capillary and viscosity effects through the gliding motion of the probe.
ABSTRACT
The interfacial effect between a metal catalyst and its various supporting transition metal oxides on the catalytic activity of heterogeneous catalysis has been extensively explored; engineering interfacial sites of metal supported on metal oxide has been found to influence catalytic performance. Here, we investigate the interfacial effect of Pt nanowires (NWs) vertically and alternatingly stacked with titanium dioxide (TiO2) or cobalt monoxide (CoO) NWs, which exhibit a strong metal-support interaction under carbon monoxide (CO) oxidation. High-resolution nanotransfer printing based on nanoscale pattern replication and e-beam evaporation were utilized to obtain the Pt NWs cross-stacked on the CoO or TiO2 NW on the silicon dioxide (SiO2) substrate with varying numbers of nanowires. The morphology and interfacial area were precisely determined by means of atomic force microscopy and scanning electron microscopy. The cross-stacked Pt/TiO2 NW and Pt/CoO NW catalysts were estimated with CO oxidation under 40 Torr CO and 100 Torr O2 from 200 to 240 °C. Higher catalytic activity was found on the Pt/CoO NW catalyst than on Pt/TiO2 NWs and Pt NWs, which indicates the significance of nanoscale metal-oxide interfaces. As the number of nanowire layers increased, the catalytic activity became saturated. Our study demonstrates the interfacial role of nanoscale metal-oxide interfaces under CO oxidation, which has intriguing applications in the smart design of catalytic materials.
ABSTRACT
The strong metal-oxide interaction of platinum nanoparticles (PtNPs) deposited on two types of cobalt oxides, CoO and Co3O4, was investigated using CO oxidation. Two different sizes of PtNPs as well as arc-plasma-deposited (APD) PtNPs without a capping layer were used to reveal the effect of metal-oxide interfaces on catalytic activity. An enhanced catalytic activity was observed on the PtNPs on the Co3O4 substrate, which was ascribed to the reducible support and to the interfacial sites.
ABSTRACT
The use of hot carriers generated from the decay of localized surface plasmon resonance in noble metal nanoparticles is a promising concept for photocatalysis. Here, we report the enhancement of photocatalytic activity by the flow of hot electrons on TiO2 nanotube arrays decorated with 5-30 nm Au nanoparticles as photoanodes for photoelectrochemical water splitting. This enhanced photocatalytic activity is correlated to the size of the Au nanoparticles, where higher oxygen evolution was observed on the smaller nanoparticles. Conductive atomic force microscopy and ultraviolet photoelectron spectroscopy were used to characterize the Schottky barrier between Au and TiO2, which reveals a reduction in the Schottky barrier with the smaller Au nanoparticles and produces an enhanced transfer of photoinduced hot carriers. This study confirms that the higher photocatalytic activity was indeed driven by the hot electron flux generated from the decay of localized surface plasmon resonance.
