ABSTRACT
In the title molecular salt, C4H7N2 (+)·C6H2N3O7 (-), the phenolic proton of the starting picric acid has been transferred to the imidazole N atom. The nitro groups are twisted away from the benzene ring plane, making dihedral angles of 12.8â (2), 9.2â (4) and 29.3â (2)°. In the crystal, the component ions are linked into chains along [010] via N-Hâ¯O and bifurcated N-Hâ¯(O,O) hydrogen bonds. These chains are further linked by weak C-Hâ¯O hydrogen bonds into a three-dimensional network. The complex three-dimensional network can be topologically simplified into a 4-connected uninodal net with the point symbol {4.8(5)}.
ABSTRACT
The asymmetric unit of the title organic salt [systematic name: 1H-pyrazol-2-ium 2,4,6-tri-nitro-phenolate-1H-pyrazole (1/1)], H(C3H4N2)2 (+)·C6H2N3O7 (-), consists of one picrate anion and one hydrogen-bonded dimer of a pyrazolium monocation. The H atom involved in the dimer N-Hâ¯N hydrogen bond is disordered over both symmetry-unique pyrazole mol-ecules with occupancies of 0.52â (5) and 0.48â (5). In the crystal, the component ions are linked into chains along [100] by two different bifurcated N-Hâ¯(O,O) hydrogen bonds. In addition, weak C-Hâ¯O hydrogen bonds link inversion-related chains, forming columns along [100].