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1.
Chem Commun (Camb) ; 51(52): 10459-62, 2015 Jul 04.
Article in English | MEDLINE | ID: mdl-26028215

ABSTRACT

Photocatalytic mineralization of o-toluidine in aqueous media under UV/solar irradiation was achieved by bare and bismuth doped zinc oxide nanoparticles. By adopting different analytical approaches a reaction mechanism is proposed, explaining the differences in photodetoxification performances.


Subject(s)
Bismuth/chemistry , Toluidines/chemistry , Zinc Oxide/chemistry , Catalysis , Molecular Structure , Nanoparticles/chemistry , Photochemical Processes , Sunlight , Ultraviolet Rays
2.
Chem Commun (Camb) ; 47(9): 2640-2, 2011 Mar 07.
Article in English | MEDLINE | ID: mdl-21234470

ABSTRACT

Photocatalytic ozonation by Al-supported TiO(2) films is successfully applied to the mineralization of 4-cumylphenol, a recalcitrant endocrine disrupting compound. A possible reaction mechanism implying the intermediate formation of bisphenols is proposed on the grounds of HPLC-MS and FTIR analyses.


Subject(s)
Endocrine Disruptors/chemistry , Ozone/chemistry , Phenols/chemistry , Titanium/chemistry , Water Pollutants, Chemical/chemistry , Catalysis , Chromatography, High Pressure Liquid , Mass Spectrometry , Spectroscopy, Fourier Transform Infrared , Surface Properties
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