Assessing the progress in depolluting the Mediterranean Sea.

The depollution of the Mediterranean Sea by 2020 is the overarching goal of Horizon 2020 Initiative (H2020). The first phase (2007-2013) tackled the main land-based pollution sources; municipal waste, urban wastewater and industrial emissions. As part of the H2020 roadmap implementation, the ENPI-SEIS project focused on the first H2020 review mechanism that included a) establishing a process for regular environmental reporting in the European Neighbourhood Policy South countries, and b) generating the knowledge necessary to assess the progress in depolluting the Mediterranean Sea. This paper reviews the process in line with the "Shared Environmental Information System" principles and its three pillars (content, cooperation, infrastructure). The main outcomes of the thematic assessment, based on a set of regional H2020 indicators, are also presented. This assessment highlights the major drivers and their implications on marine protection. It also identifies areas that require further attention in the next phase of H2020 (2014-2020).

Modelling the geochemical fate and transport of wastewater-derived phosphorus in contrasting groundwater systems.

A 1D reactive transport model (RTM) is used to obtain a mechanistic understanding of the fate of phosphorus (P) in the saturated zone of two contrasting aquifer systems. We use the field data from two oxic, electron donor-poor, wastewater-impacted, sandy Canadian aquifers, (Cambridge and Muskoka sites) as an example of a calcareous and non-calcareous groundwater system, respectively, to validate our reaction network. After approximately 10 years of wastewater infiltration, P is effectively attenuated within the first 10 m down-gradient of the source mainly through fast sorption onto calcite and Fe oxides. Slow, kinetic sorption contributes further to P removal, while precipitation of phosphate minerals (strengite, hydroxyapatite) is quantitatively unimportant in the saturated zone. Nitrogen (N) dynamics are also considered, but nitrate behaves essentially as a conservative tracer in both systems. The model-predicted advancement of the P plume upon continued wastewater discharge at the calcareous site is in line with field observations. Model results suggest that, upon removal of the wastewater source, the P plume at both sites will persist for at least 20 years, owing to desorption of P from aquifer solids and the slow rate of P mineral precipitation. Sensitivity analyses for the non-calcareous scenario (Muskoka) illustrate the importance of the sorption capacity of the aquifer solids for P in modulating groundwater N:P ratios in oxic groundwater. The model simulations predict the breakthrough of groundwater with high P concentrations and low N:P ratios after 17 years at 20 m from the source for an aquifer with low sorption capacity (<0.02% w/w Fe(OH)(3)). In this type of system, denitrification plays a minor role in lowering the N:P ratios because it is limited by the availability of labile dissolved organic matter.