Holocene melting of the West Antarctic Ice Sheet driven by tropical Pacific warming.

The primary Antarctic contribution to modern sea-level rise is glacial discharge from the Amundsen Sea sector of the West Antarctic Ice Sheet. The main processes responsible for ice mass loss include: (1) ocean-driven melting of ice shelves by upwelling of warm water onto the continental shelf; and (2) atmospheric-driven surface melting of glaciers along the Antarctic coast. Understanding the relative influence of these processes on glacial stability is imperative to predicting sea-level rise. Employing a beryllium isotope-based reconstruction of ice-shelf history, we demonstrate that glaciers flowing into the Amundsen Sea Embayment underwent melting and retreat between 9 and 6 thousand years ago. Despite warm ocean water influence, this melting event was mainly forced by atmospheric circulation changes over continental West Antarctica, linked via a Rossby wave train to tropical Pacific Ocean warming. This millennial-scale glacial history may be used to validate contemporary ice-sheet models and improve sea-level projections.

Initial measurement of beryllium-9 using high-resolution inductively coupled plasma mass spectrometry allows for more precise applications of the beryllium isotope system within the Earth Sciences.

RATIONALE: Precise and accurate determination of the ratio of the cosmogenic nuclide 10 Be to the stable isotope 9 Be (10 Be/9 Be) is needed across multiple fields of research within the Earth Sciences. Current techniques used to measure the 9 Be content of geological materials generally require a large amount of sample or solution aliquot and present a large range of analytical precisions. METHODS: A range of geological reference materials underwent whole-rock dissolution and "strong" (0.04 M NH2 OH.HCl in 25% acetic acid) and "weak" (0.02 M NH2 OH.HCl in 10% acetic acid) leaching to represent a range of potential applications within the geosciences. After treatment, the 9 Be and major element (Na, Ca, Mg, Fe, Mn, Al and Ti) content of sample solutions were determined by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) using a Thermo® ELEMENT XR instrument. RESULTS: The 9 Be concentration of whole-rock and leaching solutions displayed a wide range of values within each geological reference material, generally following a uniform relationship implying a potential kinetic control on NH2 OH leaching, as suggested by major element profiles. A precision of 0.1 to 1.4% is achieved independent of sample size or leaching strength. CONCLUSIONS: Initial results suggest that the use of HR-ICP-MS improves the precision of 9 Be analysis for a range of geological reference materials. A high precision is maintained despite reducing the sample size or strength of leaching solution. This has implications for the use of the Be isotope system within the Earth Sciences by reducing the propagated uncertainty of 10 Be/9 Be ratios or the mass of sample or 9 Be aliquot used.

Anthropogenic Osmium in Macroalgae from Tokyo Bay Reveals Widespread Contamination from Municipal Solid Waste.

Human activity is influencing the global osmium cycle, driving the Os isotopic composition (187Os/188Os) of the hydrosphere and associated sedimentary material to lower values. Here, we present the Re and Os abundance and isotope systematics of macroalgae, a proxy for seawater, from Tokyo Bay to elucidate the potential sources of anthropogenic Os to the Pacific Ocean. Macroalgae from the Uraga Channel, which connects Tokyo Bay to the Pacific Ocean, record relatively low Os abundances (∼10.1 pg/g) and an 187Os/188Os of ∼0.9, indicative of surface ocean seawater. Contrastingly, macroalgae within the bay closest to central Tokyo record the highest Os abundances (∼22.8 pg/g) and lowest 187Os/188Os values (∼0.47), suggesting contamination from human activity. To determine the source of anthropogenic Os, we have developed the first Os emission inventory, based on the East Asian Air Pollutant Emission Grid database (EAGrid2010). The close relationship (R2 = 0.67 and p-value = <0.05) between Os inventories and macroalgal data suggests that municipal solid waste incinerators (MSWIs) are the dominant source of Os to Tokyo Bay. Projections for Japan estimate that 26-18+38 ng Os/m2/yr is released from MSWI smokestacks, leading to a concentration in precipitation of 26-18+38 fg/g, identifying MSWIs as a major contributor of anthropogenic Os to the hydrological cycle.

Tracing the natural and anthropogenic influence on the trace elemental chemistry of estuarine macroalgae and the implications for human consumption.

Macroalgae (seaweed) has been shown to be an effective environmental indicator. We investigate the trace element chemistry of macroalgae samples from locations along the Firth of Forth and Forth Estuary in Scotland. The overall trend in elemental abundance (Os ≪ Re < Ag < U < Cd < Co < Ni < Pb < Cu < As < Zn ≪ I), and changes along the estuary (seawards: increase As, I, Cd, U, Re, Os; decrease Pb, Cu; mid-estuary peak Zn; based on certain species), are controlled by a number of factors, including: salinity, mixing and macroalgal species differences. Within the same macroalgal species, some elemental abundances (As, I, Pb, Cu, Cd and U) are affected by mixing between freshwater riverine and North Sea marine saltwater. Additional mixing of natural and anthropogenic inputs from the surrounding geology and industry are also observed, affecting Zn, Ni, Co, Re and Os. Macroalgae is also an increasingly popular food, with some species harvested in the Firth of Forth. Iodine (67-5061 ppm), lead (0.047-4.1 ppm) and cadmium (0.006-0.93 ppm) macroalgal abundances are at safe levels for human consumption (WHO limits). However, many samples exceed the American (3 ppm) and Australian (1 ppm) limits for inorganic arsenic in macroalgae, with values ranging 0-67 ppm. In most of the samples, soaking and cooking the macroalgae reduced the inorganic arsenic content to within the American and Australian limits. However, this has further implications if the macroalgae is used to cook soups (e.g., Dashi), as the leached elements become a significant component of the soup.

Monte Carlo sampling for error propagation in linear regression and applications in isochron geochronology.

Geochronology is essential for understanding Earth's history. The availability of precise and accurate isotopic data is increasing; hence it is crucial to develop transparent and accessible data reduction techniques and tools to transform raw mass spectrometry data into robust chronological data. Here we present a Monte Carlo sampling approach to fully propagate uncertainties from linear regressions for isochron dating. Our new approach makes no prior assumption about the causes of variability in the derived chronological results and propagates uncertainties from both experimental measurements (analytical uncertainties) and underlying assumptions (model uncertainties) into the final age determination. Using synthetic examples, we find that although the estimates of the slope and y-intercept (hence age and initial isotopic ratios) are comparable between the Monte Carlo method and the benchmark "Isoplot" algorithm, uncertainties from the later could be underestimated by up to 60%, which are likely due to an incomplete propagation of model uncertainties. An additional advantage of the new method is its ability to integrate with geological information to yield refined chronological constraints. The new method presented here is specifically designed to fully propagate errors in geochronological applications involves linear regressions such as Rb-Sr, Sm-Nd, Re-Os, Pt-Os, Lu-Hf, U-Pb (with discordant points), Pb-Pb and Ar-Ar.