Conventional and microwave-assisted acid pretreatment of tea waste powder: analysis of functional groups using FTIR.

Tea waste powder (TWP) is one of the potential biomass waste to recover valuable chemicals and materials. The prime objective of this work is to investigate the role of acid pretreatment on TWP. Diluted acids (HCl, H3PO4, CH3COOH, and H2SO4) were used to soak the TWP to understand the role of acids on bond cleavage and chemicals formation. One gram of TWP was soaked in 100 mL of diluted acids for 24 h. The soaked samples were further subjected to a hot air oven (temperature: 80 °C, duration: 6 h), orbital shaking (shaking speed: 80-100 rpm, duration: 6 h), and microwave irradiation (microwave power: 100 W, duration: 10 min) to understand the synergistic effects of acids and mode of exposure. The pretreated solid samples and liquid samples were analyzed using FTIR to understand the presence of functional groups. The mass loss of TWP after treatment significantly varied with the type of acid and exposure mode used. In the orbital shaker, the mass loss was varied in the following order: H2SO4 (36%) > CH3COOH (32%) > H3PO4 (22%) > HCl (15%). In hot air oven, high mass loss was observed compared to orbital shaking [HCl (48%) > CH3COOH (37%) > H2SO4 (35%) > H3PO4 (33%)]. The mass loss in microwave irradiation is lower (19 to 25%) with all acids compared to orbital shaking. In the solid samples, O-H stretching, C-H stretching, C=O stretching, C=C stretching, -C-O-, and -C-OH- functional groups were noticed. Similarly, C=O and C=C peaks and C-O and -C-OH peaks were noticed in liquid samples. Interestingly, microwave irradiation showed promising results in 10 min of pretreatment, whereas orbital shaking and hot air oven pretreatments require 6 h to achieve the same result.

The effect of torrefaction temperature and catalyst loading in Microwave-Assisted in-situ catalytic Co-Pyrolysis of torrefied biomass and plastic wastes.

In the current study, the effect of torrefaction temperatures (125-175 °C) and catalyst quantity (5-15 g) on co-pyrolysis of torrefied sawdust (TSD) and polystyrene (PS) are investigated to obtain value-added products. The role of torrefaction in co-pyrolysis of TSD: PS was analyzed to understand the product yields, synergy, and energy consumption . As the torrefaction temperature increases, oil yield (48.3-59.6 wt%) and char yield (24.3-29 wt%) increase while gas yield (27.4-11.4 wt%) decreases. Catalytic co-pyrolysis showed a significant level of synergy when compared to non-catalytic co-pyrolysis. For the conversion (%), a positive synergy maximum (-2.6) exists at a torrefaction temperature of 175 °C and 15 g of KOH catalyst. To develop the model, polynomial regression-based machine learning was used to predict pyrolysisproduct yields and energy usage variables. The developed models showed significant prediction accuracy (R2 > 0.98), suggesting the experimental values and the predicted values matched well.

The role of solvent soaking and pretreatment temperature in microwave-assisted pyrolysis of waste tea powder: Analysis of products, synergy, pyrolysis index, and reaction mechanism.

This study focuses on microwave-assisted pyrolysis (MAP) of fresh waste tea powder and torrefied waste tea powder as feedstocks. Solvents including benzene, acetone, and ethanol were used for soaking feedstocks. The feedstock torrefaction temperature (at 150 °C) and solvents soaking enhanced the yields of char (44.2-59.8 wt%) and the oil (39.8-45.3 wt%) in MAP. Co-pyrolysis synergy induced an increase in the yield of gaseous products (4.7-20.1 wt%). The average heating rate varied in the range of 5-25 °C/min. The energy consumption in MAP of torrefied feedstock (1386 KJ) significantly decreased compared to fresh (3114 KJ). The pyrolysis index dramatically varied with the solvent soaking in the following order: ethanol (26.7) > benzene (25.6) > no solvent (10) > acetone (6). It shows that solvent soaking plays an important role in the pyrolysis process. The obtained bio-oil was composed of mono-aromatics, poly-aromatics, and oxygenated compounds.

Synthesis of sustainable chemicals from waste tea powder and Polystyrene via Microwave-Assisted in-situ catalytic Co-Pyrolysis: Analysis of pyrolysis using experimental and modeling approaches.

In the current study, catalytic co-pyrolysis was performed on waste tea powder (WTP) and polystyrene (PS) wastes to convert them into value-added products using KOH catalyst. The feed mixture influenced the heating rates (17-75 °C/min) and product formation. PS promoted the formation of oil and WTP enhanced the char formation. The maximum oil yield (80 wt%) was obtained at 15 g:5 g, and the maximum char yield (44 wt%) was achieved at 5 g:25 g (PS:WTP). The pyrolysis index (PI) increased with the increase in feedstock quantity. High PI was noticed at 25 g:5 g, and low PI was at 5 g:5 g (PS:WTP). Low energy consumption and low pyrolysis time enhanced the PI value. Significant interactions were noticed during co-pyrolysis. The obtained bio-oil was analyzed using GC-MS and a plausible reaction mechanism is presented. Catalyst and co-pyrolysis synergy promoted the formation of aliphatic and aromatic hydrocarbons by reducing the oxygenated products.

Understanding of synergy in non-isothermal microwave-assisted in-situ catalytic co-pyrolysis of rice husk and polystyrene waste mixtures.

Rice husk (RH) and polystyrene (PS) wastes were converted into value-added products using microwave-assisted catalytic co-pyrolysis. The graphite susceptor (10 g) along with KOH catalyst (5 g) was mixed with the feedstock to understand the products and energy consumption. RH promoted the char yield (20-34 wt%) and gaseous yields (16-25 wt%) whereas PS enhanced the oil yield (23-70 wt%). Co-pyrolysis synergy induced an increase in gaseous yields (14-53 wt%) due to excessive cracking. The specific microwave energy consumption dramatically decreased in co-pyrolysis (5-22 kJ/g) compared to pyrolysis (56-102 kJ/g). The pyrolysis index increased (17-445) with the increase in feedstock quantity (5-50 g). The obtained oil was composed of monoaromatics (74%) and polyaromatics (18%). The char was rich in carbon content (79.5 wt%) and the gases were composed of CO (24%), H2 (12%), and CH4 (22%).