Imidazoline As a Volatile Corrosion Inhibitor for Mitigation of Top- and Bottom-of-the-Line CO2 Corrosion in Carbon Steel Pipelines.

A fatty acid imidazoline-based inhibitor was synthesized via a facile solvent-free synthesis method between tall oil fatty acid (TOFA) and diethylenetriamine (DETA) under atmospheric conditions with a short reaction time. The as-synthesized imidazoline (S-Imd) acted as an effective inhibitor for reducing or preventing corrosion of carbon steel pipelines at both bottom of the line (BOL) and top of the line (TOL) positions under simulated conditions of a gas pipeline in a CO2-saturated environment. The inhibition efficacy was examined by both weight loss and electrochemical measurements, such as the electrochemical impedance spectrum (EIS), potentiodynamic polarization (PDP), and linear polarization resistance (LPR). The results revealed that the S-Imd, 2-(8-heptadecenyl)-2-imidazoline-1-ethanamin, at 300 ppm exhibited a superior inhibition efficiency of up to 91.6 and 89.9% for BOL and TOL corrosion tests, respectively. The surface morphology of the carbon steel test specimens was also examined using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDAX), and contact angle analysis. It was found that the as-synthesized S-Imd acted as a mixed-type inhibitor that exhibited a decreased surface roughness and oxide layer on carbon steel surfaces. However, the water contact angle was found to increase, implying enhanced hydrophobicity of the surface. Adsorption of the imidazoline molecules on carbon steel surfaces followed the Langmuir adsorption isotherm. The present work provides very promising results in the synthesis and utilization of the studied imidazoline as a volatile corrosion inhibitor (VCI), especially for carbon steel pipelines in petroleum industries.

Bacterial cellulose-based magnetic nanocomposites: A review.

Bacterial cellulose (BC) is a natural polymer that has unique and interesting structural, physical and chemical properties. These characteristics make it very attractive as a starting point for several novel developments in innovative research. However, the pristine BC lacks certain properties, in particular, magnetic property, which can be imparted to BC by incorporation of several types of magnetic nanoparticles. Magnetic nanocomposites based on BC exhibit additional magnetic functionality on top of the excellent properties of pristine BC, which make them promising materials with potential uses in various medical and environmental applications, as well as in advanced electronic devices. This review has compiled information about all classes of BC magnetic nanocomposites fabricated by various synthesis approaches and an overview of applications as well as improved features of these materials. A summary of the key developments of BC magnetic nanocomposites and emphasis on novel advances in this field is presented.

Enhancing piezoelectric properties of bacterial cellulose films by incorporation of MnFe2O4 nanoparticles.

Low-cost and highly sensitive piezoelectric sensors were fabricated from bacterial cellulose (BC)/MnFe2O4 nanocomposite films via a co-precipitation method, followed by hot-pressing. MnFe2O4 nanoparticles were homogeneously distributed in the BC structure. The piezoelectric sensitivity measurements in the normal mode showed that the pristine BC film exhibited a sensitivity of ∼5 pC/N, whereas this value was increased to 23 pC/N for the composite film, which is comparable to the PVDF reference film. In the bending mode, the piezoelectric response increased to 25 pC/N and 57 pC/N for the BC film and the composite film, respectively. Moreover, the piezoelectric sensitivity was significantly enhanced using carbon tape electrodes attached directly to the films instead of sandwiched electrodes. This produced a sensitivity of greater than 50 pC/N for the MBC nanocomposite film in the normal mode measurement. Our work demonstrates the potential of using MBC composite films as inexpensive and highly sensitive flexible piezoelectric sensors.

Magnetically responsive and flexible bacterial cellulose membranes.

Magnetically responsive and flexible bacterial cellulose (BC) membranes were successfully fabricated using a simple diffusion of a ferrofluid solution. BC hydrogels were either water-substituted by alcohol (BC-N) or freeze dried (BC-F) prior to their immersion in the ferrofluid. The presence of both crystalline BC and Fe3O4 phases, and the homogeneous distribution of nanoparticles (NPs) in BC nanofibrils were observed. Higher concentrations of Fe3O4 NPs were found in the BC-N samples than for the BC-F samples. Higher magnetization in the BC-N samples was observed compared to the BC-F samples. Mechanical properties tests showed the higher strength and Young's modulus for the BC-F samples was possibly due to their more compacted nanostructure compared to BC-N. Using this simple process, the magnetic BC membranes show elastic properties upon deformation, returning to their original shape without damage. Also, they were highly sensitive to external magnetic forces giving them potential for many applications.