Soil sedimentation and quality within the roadside ditches of an agricultural watershed.

Roadside ditches are an integral component to the >6.3 million km of roadsides in the U.S. and act as drainageways for millions of hectares of watershed runoff. Our study of six roadside ditches in Lime Creek watershed characterized soil nutrients and heavy metal patterns as well as quantified the physical and hydrological properties of ditch soils. At all ditch sites, we identified significant sedimentation of silt-sized particles, total nitrogen, and soil carbon in shallow roadside ditch soils. A post-settlement surface soil horizon significantly higher in silt content was observed compared to the underlying subsoil and parent material. Although accumulation of several heavy metals was measured in ditch soils, significant variability was not observed within the ditch environment. Most of the heavy metal concentrations were found to be either similar to or lower than state-wide averages. Higher levels of calcium near the roads were likely due to annual use of road deicers. Overall, we estimated that 42 Mg/ha of total carbon and 5 Mg/ha of total nitrogen are being stored in agricultural ditch soils, which is similar to that of surrounding agricultural land in terms of total carbon storage, but much higher than estimates of total nitrogen storage. Our study of six roadside ditches in an eastern Iowa watershed documented the soil chemistry, morphology, and sediment accumulation that occurred since ditch construction. Further research is needed to develop a better understanding of how the soil and water conditions in the ditches related to the watershed areas that feed them.

Subsurface nutrient processing capacity in agricultural roadside ditches.

Roadside ditches located throughout urban and rural landscapes are integral components of watershed-scale hydrologic processes but their capacity to reduce nutrients in the subsurface environment has not been investigated. In this study, vegetation, soil and groundwater conditions were characterized in six roadside ditches in the 66 km2 Lime Creek watershed in eastern Iowa. Shallow water table wells were installed at 17 locations in six transects and sampled monthly in 2017 to evaluate spatial and temporal patterns. Vegetation characteristics were surprisingly diverse but was not found to be a significant factor in water quality patterns. Groundwater NO3-N concentrations were <1 mg/L in wells at two transects and were observed to decrease from upgradient to downgradient positions at four locations (average 60% reduction). Water table levels were very shallow (<0.3 m) at nearly all sites, and the loamy and organic rich ditch soils appeared sufficiently anaerobic for subsurface processing of NO3-N via denitrification to occur. Groundwater dissolved reactive phosphorus concentrations did not vary systematically among the sites whereas two of the roadside ditches had Cl concentrations indicative of road salt encroachment. With estimated NO3-N reductions equivalent to typical wetland N reductions we recommend consideration of roadside ditches to serve as "linear wetlands" for watershed-scale treatment of nonpoint source pollution.

Effectiveness of a newly reconstructed floodplain oxbow to reduce NO3-N loads from a spring flood.

Enhancing NO3-N processing in floodplains offers opportunities to achieve water quality improvements in agricultural watersheds but few studies have quantified the effectiveness of newly reconstructed oxbows to reduce loads delivered from floods. In this study, we evaluated NO3-N retention during a spring storm water runoff event in a newly reconstructed oxbow (<1 year old) located along Morgan Creek in eastern Iowa. A 30-h flood connected the oxbow to the creek for approximately nine hours and delivered 14.7 kg of NO3-N into the oxbow. Using a NO3-N sensor, oxbow NO3-N concentrations were observed to increase from 0.7 to 5.3 mg/l after the flood event, but decreased to background conditions over the next 21 days. We estimated NO3-N retention to be 0.30 g N m-2 d-1 and the NO3-N retention efficiency to be 74.2% for the single flood event. The NO3-N mass reduction in the oxbow intersected with predicted mass reduction from a first-order denitrification decay model after 21 days which suggests that denitrification was largely responsible for the observed NO3-N decrease. However, the effectiveness of the oxbow for reducing watershed-scale N loads appears to be limited, since the oxbow is located in a low-nutrient floodplain and would only retain NO3-N loads when delivered to the oxbow via flooding. Study results suggest that oxbows provides valuable ecosystem services during non-flooding periods and are activated for NO3-N load reduction during floods.

Optimizing Sampling Strategies for Riverine Nitrate Using High-Frequency Data in Agricultural Watersheds.

Understanding linked hydrologic and biogeochemical processes such as nitrate loading to agricultural streams requires that the sampling bias and precision of monitoring strategies be known. An existing spatially distributed, high-frequency nitrate monitoring network covering ∼40% of Iowa provided direct observations of in situ nitrate concentrations at a temporal resolution of 15 min. Systematic subsampling of nitrate records allowed for quantification of uncertainties (bias and precision) associated with estimates of various nitrate parameters, including: mean nitrate concentration, proportion of samples exceeding the nitrate drinking water standard (DWS), peak (>90th quantile) nitrate concentration, and nitrate flux. We subsampled continuous records for 47 site-year combinations mimicking common, but labor-intensive, water-sampling regimes (e.g., time-interval, stage-triggered, and dynamic-discharge storm sampling). Our results suggest that time-interval sampling most efficiently characterized all nitrate parameters, except at coarse frequencies for nitrate flux. Stage-triggered storm sampling most precisely captured nitrate flux when less than 0.19% of possible 15 min observations for a site-year were used. The time-interval strategy had the greatest return on sampling investment by most precisely and accurately quantifying nitrate parameters per sampling effort. These uncertainty estimates can aid in designing sampling strategies focused on nitrate monitoring in the tile-drained Midwest or similar agricultural regions.

Antecedent moisture controls on stream nitrate flux in an agricultural watershed.

Evaluating nitrate-N fluxes from agricultural landscapes is inherently complex due to the wide range of intrinsic and dynamic controlling variables. In this study, we investigate the influence of contrasting antecedent moisture conditions on nitrate-N flux magnitude and dynamics in a single agricultural watershed on intra-annual and rainfall-event temporal scales. High temporal resolution discharge and nitrate concentration data were collected to evaluate nitrate-N flux magnitude associated with wet (2009) and dry (2012) conditions. Analysis of individual rainfall events revealed a marked and consistent difference in nitrate-N flux response attributed to wet/dry cycles. Large-magnitude dilutions (up to 10 mg N L) persisted during the wet antecedent conditions (2009), consistent with a dominant baseflow contribution and excess groundwater release in relation to precipitation volume (discharge > > precipitation). Smaller-magnitude concentrations (<7 mg N L) were observed during the drought conditions of 2012, consistent with a quickflow-dominated response to rain events and infiltration/storage of precipitation resulting in discharge < precipitation. Nitrate-N loads and yields from the watershed were much higher (up to an order of magnitude) in the wet year vs. the dry year. Our results suggest that the response of nitrate-N loading to rain events is highly dependent on intra-annual antecedent moisture conditions and subsurface hydrologic connectivity, which together dictate the dominant hydrologic pathways for stream recharge. Additionally, the results of our study indicate that continued pronounced wet/dry cycles may become more dominant as the short-term driver of future nitrate-N exports.