ABSTRACT
The production of high-purity hydrogen from hydrogen storage materials with further direct use of generated hydrogen in fuel cells is still a relevant research field. For this purpose, nickel-molybdenum-plated copper catalysts (NiMo/Cu), comprising between 1 and 20 wt.% molybdenum, as catalytic materials for hydrogen generation, were prepared using a low-cost, straightforward electroless metal deposition method by using citrate plating baths containing Ni2+-Mo6+ ions as a metal source and morpholine borane as a reducing agent. The catalytic activity of the prepared NiMo/Cu catalysts toward alkaline sodium borohydride (NaBH4) hydrolysis increased with the increase in the content of molybdenum present in the catalysts. The hydrogen generation rate of 6.48 L min-1 gcat-1 was achieved by employing NiMo/Cu comprising 20 wt.% at a temperature of 343 K and a calculated activation energy of 60.49 kJ mol-1 with remarkable stability, retaining 94% of its initial catalytic activity for NaBH4 hydrolysis following the completion of the fifth cycle. The synergetic effect between nickel and molybdenum, in addition to the formation of solid-state solutions between metals, promoted the hydrogen generation reaction.
ABSTRACT
In this study, Mn-based multicomponent catalysts supported by two different carriers (lightweight expanded clay aggregate and the Ukrainian clinoptiolite) were prepared by electroless metal deposition method and tested for the selective catalytic reduction of NO with ammonia (NH3-SCR de-NO). Prior to the activity test, all the catalysts prepared were characterized by inductively coupled plasma optical emission spectroscopy, field emission scanning electron microscopy (FESEM), energy dispersive X-ray mapping, X-ray photoelectron spectroscopy, H2-TPR and NH3-TPD techniques. The particular interest of the present study was focused on the investigation of the carrier's role in the NO catalytic reduction and the promoting effect provided by the incorporation of the small amount of Pt (0.1 wt.%) in the Mn-based catalytic layer. The results revealed that the carrier's role in the NO catalytic conversion can be considered as a factor determining the effectiveness of the conversion process. Ukrainian clinoptiolite was proved to be a more attractive carrier for the preparation of the effective SCR de-NO catalysts due to its intrinsic sorption capacity, surface acidity and the redox potential. The high NO conversion efficiency provided by the Mn-based clinoptiolite-supported catalysts can be explained by the synergistic effect between the carrier and the active species deposited. It was shown that both the Mn97.6Cu2.4/clinoptiolite and the Mn97.5Co2.5/clinoptiolite catalysts can be successfully applied as the low-temperature (100-300°C) catalysts for NH3-SCR de-NO. When the NO removal efficiency varies in the range of 86-91%, the additional incorporation of Pt in the active layer in the amount of 0.1 wt.% can enhance the NO reduction by about 5% on average.
ABSTRACT
In this study, sodium borohydride oxidation has been investigated on the platinum nanoparticles modified copper/titanium catalysts (PtNPsCu/Ti), which were fabricated by employing the electroless copper plating and galvanic displacement technique. ICP-OES, XRD, FESEM, and EDX have been used to characterize PtNPsCu/Ti catalysts' composition, structure, and surface morphology. The oxidation of sodium borohydride was examined on the PtNPsCu/Ti catalysts using cyclic voltammetry and chrono-techniques.
ABSTRACT
Saccharose, forming sufficiently stable complexes with copper(II) ions in alkaline solutions, was found to be a suitable ligand for copper(II) chelating in alkaline (pH>12) electroless copper deposition solutions. Reduction of copper(II)-saccharose complexes by hydrated formaldehyde was investigated and the copper deposits formed were characterized. The thickness of the compact copper coatings obtained under optimal operating conditions in 1h reaches ca. 2 microm at ambient temperature. The plating solutions were stable and no signs of Cu(II) reduction in the bulk solution were observed. Results were compared with those systems operating with other copper(II) ligands.