Floating Liquid Droplets on the Surface of Cryogenic Liquids: Implications for Titan Rain.

Saturn's moon, Titan, has a hydrocarbon-based hydrologic cycle with methane and ethane rainfall. Because of Titan's low gravity, "floating liquid droplets" (coherent droplets of liquid hydrocarbons that float upon a liquid surface) may form on the surface of Titan's hydrocarbon lakes and seas during rainfall. Floating liquid droplets, however, have not been investigated in the laboratory under conditions appropriate for the surface of Titan (cryogenic, hydrocarbon, liquids). We conducted a set of experiments to simulate methane and ethane rainfall under Titan surface conditions (89-94 K, 1.5 bar nitrogen atmosphere) and find that floating ethane droplets form in a wide range of bulk liquid compositions, yet floating methane droplets only form in a narrow compositional range and impact velocity. We find droplet formation is independent of the liquid density and hypothesize that dissolved atmospheric nitrogen in the bulk liquid may repel liquid ethane droplets at the surface. We propose that liquid droplets will form in Titan's methane-rich lakes and seas during ethane rainfall with a droplet radius of ≤3 mm and an impact velocity of ≤0.7 m/s. The presence of these droplets on Titan's lakes may result in a liquid surface layer that is dominated in rainfall composition.

Non-isoplethic measurement on the solid-liquid-vapor equilibrium of binary mixtures at cryogenic temperatures.

We measured the solid-liquid-vapor (SLV) equilibrium of binary mixtures during experiments that alternated between cooling the mixture and injecting the more-volatile component into the sample chamber; thus, the composition of the mixture changed (non-isoplethic) throughout the experiment. Four binary mixtures were used in the experiments to represent mixtures with miscible solid phases (N2/CO) and barely miscible solid solutions (N2/C2H6), as well as mixtures with intermediate solid miscibility (N2/CH4 and CO/CH4). We measured new SLV pressure data for the binary mixtures, except for N2/CH4, which are also available in the literature for verification in this work. While these mixtures are of great interest in planetary science and cryogenics, the resulting pressure data are also needed for modeling purposes. We found the results for N2/CH4 to be consistent with the literature. The resulting new SLV curve for CO/CH4 shows similarities to N2/CH4. Both have two density inversion points (bracketing the temperature range where the solid floats). This result is important for places such as Pluto, Triton, and Titan, where these mixtures exist in vapor, liquid, and solid phases. Based on our experiments, the presence of a eutectic is unlikely for the N2/CH4 and CO/CH4 systems. An azeotrope with or without a peritectic is likely, but further investigations are needed to confirm. The N2/CO system does not have a density inversion point, as the ice always sinks in its liquid. For N2/C2H6, new SLV pressure data were measured near each triple point of the pure components.

The Formation of Bilobate Comet Shapes through Sublimative Torques.

Recent spacecraft and radar observations have found that ~70 percent of short-period comet nuclei, mostly Jupiter-family comets (JFCs), have bilobate shapes (two masses connected by a narrow neck). This is in stark contrast to the shapes of asteroids of similar sizes, of which ~14% are bilobate. This suggests that a process or mechanism unique to comets is producing these shapes. Here we show that the bilobate shapes of JFC nuclei are a natural byproduct of sublimative activity during their dynamical migration from their trans-Neptunian reservoir, through the Centaur population, and into the Jupiter family. We model the torques resulting from volatile sublimation during this dynamical migration and find that they tend to spin up these nuclei to disruption. Once disrupted, the rubble pile-like material properties of comet nuclei (tensile strengths of ~1-10 Pa and internal friction angles of ~35°) cause them to reform as bilobate objects. We find that JFCs likely experienced rotational disruption events prior to entering the Jupiter family, which could explain the prevalence of bilobate shapes. These results suggest that the bilobate shapes of observed comets developed recently in their history (within the past ~1-10 Myr), rather than during solar system formation or collisions during planet migration and residency in the trans-Neptunian population.

How Sublimation Delays the Onset of Dusty Debris Disk Formation Around White Dwarf Stars.

Although numerous white dwarf stars host dusty debris disks, the temperature distribution of these stars differs significantly from the white dwarf population as a whole. Dusty debris disks exist exclusively around white dwarfs cooler than 27,000 K. This is all the more enigmatic given that the formation processes of dusty debris disks should favor younger, hotter white dwarfs, which likely host more dynamically unstable planetary systems. Here we apply a sophisticated material sublimation model to white dwarf systems to show that these statistics are actually a natural result of the interplay of thermal and tidal forces, and show how they define the circumstellar regions where dusty debris disks can form. We demonstrate that these processes tend to prevent stability against both sublimative destruction and reaccretion into planetesimals for rocky materials until white dwarfs cool to below ~25,000-32,000 K, in agreement with the observed limit of ~27,000 K. For pure water ice, this critical temperature is less than 2,700 K (requiring a cooling age older the universe); this precludes pure water ice-rich debris disks forming through the accepted two-step mechanism. The critical temperature is size-dependent; more massive white dwarfs could potentially host dusty debris disks at warmer temperatures.. Our model suggests that the location of the disks within the PG 0010+280, GD 56, GD 362, and PG 1541+651 systems are consistent with a forsterite-dominated olivine composition. We also find that very cool white dwarfs may simultaneously host multiple, independently formed dusty debris disks, consistent with observations of the LSPM J0207+3331 system.

Stratification Dynamics of Titan's Lakes via Methane Evaporation.

Saturn's moon Titan is the only extraterrestrial body known to host stable lakes and a hydrological cycle. Titan's lakes predominantly contain liquid methane, ethane, and nitrogen, with methane evaporation driving its hydrological cycle. Molecular interactions between these three species lead to non-ideal behavior that causes Titan's lakes to behave differently than Earth's lakes. Here, we numerically investigate how methane evaporation and non-ideal interactions affect the physical properties, structure, dynamics, and evolution of shallow lakes on Titan. We find that, under certain temperature regimes, methane-rich mixtures are denser than relatively ethane-rich mixtures. This allows methane evaporation to stratify Titan's lakes into ethane-rich upper layers and methane-rich lower layers, separated by a strong compositional gradient. At temperatures above 86K, lakes remain well-mixed and unstratified. Between 84 and 86K, lakes can stratify episodically. Below 84K, lakes permanently stratify, and develop very methane-depleted epilimnia. Despite small seasonal and diurnal deviations (<5K) from typical surface temperatures, Titan's rain-filled ephemeral lakes and "phantom lakes" may nevertheless experience significantly larger temperature fluctuations, resulting in polymictic or even meromictic stratification, which may trigger ethane ice precipitation.

Reorientation and faulting of Pluto due to volatile loading within Sputnik Planitia.

Pluto is an astoundingly diverse, geologically dynamic world. The dominant feature is Sputnik Planitia-a tear-drop-shaped topographic depression approximately 1,000 kilometres in diameter possibly representing an ancient impact basin. The interior of Sputnik Planitia is characterized by a smooth, craterless plain three to four kilometres beneath the surrounding rugged uplands, and represents the surface of a massive unit of actively convecting volatile ices (N2, CH4 and CO) several kilometres thick. This large feature is very near the Pluto-Charon tidal axis. Here we report that the location of Sputnik Planitia is the natural consequence of the sequestration of volatile ices within the basin and the resulting reorientation (true polar wander) of Pluto. Loading of volatile ices within a basin the size of Sputnik Planitia can substantially alter Pluto's inertia tensor, resulting in a reorientation of the dwarf planet of around 60 degrees with respect to the rotational and tidal axes. The combination of this reorientation, loading and global expansion due to the freezing of a possible subsurface ocean generates stresses within the planet's lithosphere, resulting in a global network of extensional faults that closely replicate the observed fault networks on Pluto. Sputnik Planitia probably formed northwest of its present location, and was loaded with volatiles over million-year timescales as a result of volatile transport cycles on Pluto. Pluto's past, present and future orientation is controlled by feedbacks between volatile sublimation and condensation, changing insolation conditions and Pluto's interior structure.