Potential for managing pool levels in a flood-control reservoir to increase nitrate-nitrogen load reductions.

Few strategies are available to reduce nitrate-nitrogen (NO3 -N) loads at larger landscape scales, but flood control reservoirs are known to reduce riverine loads. In this study, we evaluated the potential to increase nitrogen (N) loss at Lake Red Rock, a large reservoir located in central Iowa, by evaluating the inundation of sediments deposited at the reservoir inflow. Sediment samples were collected at 51 locations in the lower delta region and analyzed for particle size and nutrient content. Nitrogen loss rates in delta sediments were determined from laboratory assays, and satellite imagery was used to develop a rating curve to quantify land area inundated within the delta. The daily mass of NO3 -N reduced with delta inundation was estimated by applying the mean N 24-h loss rate (0.66 g N m2 day-1 ) by the area of inundation (m2 ). Results indicated that raising pool elevations to inundate more of the delta would result in greater N losses, ranging from 2 to 377 Mg per year. Potential N loss of 102 Mg achieved by increasing pool stage by 0.5 m would be equivalent to installing nearly 650 edge-of-field practices in the watershed. Although more work is needed to integrate with an existing environmental pool management plan, study results indicate that reservoir management could achieve N reductions at a novel landscape scale.

Dissolved inorganic and organic carbon export from tile-drained midwestern agricultural systems.

While carbon is a critically important natural element cycling through the soil profile of agricultural systems, few studies have examined the flux of dissolved organic carbon (OC) and inorganic carbon (IC) through artificially-drained cropped fields. In this study, we monitored eight tile outlets, nine groundwater wells and the receiving stream during a March to November period in 2018 to quantify subsurface IC and OC flux from tiles and groundwater to a perennial stream from a single cropped field in north-central Iowa. Results showed that carbon export from the field was dominated by IC losses through subsurface drainage tiles that were 20× higher than dissolved OC concentration in tiles, groundwater and in Hardin Creek. IC loads from tiles comprised approximately 96 % of the total carbon export. Detailed soil sampling within the field quantified TC stocks to a 1.2 m depth (246,514 kg/ha), and based on the maximum annual rate of IC loss from the field (553 kg/ha per year), we estimated that approximately 0.23 % of the TC content (0.32 % of the TOC content and 0.70 % of the TIC content) of the shallow soils was lost in a single year. Loss of dissolved carbon from the field is likely offset by reduced tillage and additions of lime. Study results suggest that attention should be given to improved monitoring of aqueous total carbon export from fields for accurate accounting of carbon sequestration performance.

Use of high-resolution ground conductivity measurements for denitrifying conservation practice placement.

Accurate field-scale maps of soil properties including features such as texture, soil organic matter (SOM) content, and hydraulic conductivity are essential for proper placement of conservation practices that utilize anoxic soil environments for denitrification. However, in many cases, soil maps inaccurately represent subsoil properties and can mislead managers about where to install new practices. Non-invasive methods of subsoil property analysis including electromagnetic induction techniques are a potentially efficient method for improving existing field-scale soil maps. In this study, we quantified the accuracy of existing soil maps in an agricultural field in north-central Iowa. Of 60 soil cores collected and reclassified, 19 were identified as taxadjunct at the soil series level primarily due to hydrologic indicators and soil particle size. We assessed the correlation among physical and chemical soil properties measured in-lab and geophysical responses measured in-field. We identified significant correlation of SOM and sand to electrical conductivity for individual core and mean soil series data. From this analysis, we developed a conservation practice suitability map and evaluated the potential for field-scale geophysical investigations to serve as a new tool for agricultural conservation planning and placement of site-specific denitrifying conservation practices. Study results suggest that incorporating a geophysical conductivity investigation into conservation planning may improve understanding of critical soil properties beyond those ascertained with limited soil borings.

Paired riparian water table monitoring to quantify hydraulic loading to a saturated buffer.

The use of saturated buffers for reducing NO3-N loads from tile-drained croplands is increasing in the US Midwest and there is a need to develop options for estimating reductions at riparian sites. In this study, we present a paired water table monitoring approach to estimate hydraulic and NO3-N loading into a saturated buffer in eastern Iowa. One well was located within the saturated buffer (treatment) and a second well was installed in the same section of the riparian buffer but without the saturated buffer (control). Over a season of monitoring, water table depths were remarkably consistent between the two wells but the water table beneath the saturated buffer was consistently 0.22 m higher than the non-saturated buffer control. The increase in water table height increased the amount of water discharged from a 162 m long buffer by 468.2 m3/year and, assuming concentration reduction of 15 mg/l, resulted in a N reduction of approximately 7 kg. Although more work is needed to document this paired monitoring approach elsewhere, the method may hold promise for inexpensively quantifying the performance of conservation practices at landowner-led sites.

Quantifying the effectiveness of a saturated buffer to reduce tile NO3-N concentrations in eastern Iowa.

Agricultural drainage tiles are primary contributors to NO3-N export from Iowa croplands. Saturated buffers are a relatively new conservation practice that diverts tile water into a distribution tile installed in a riparian buffer parallel to a stream with the intent of enhancing NO3-N processing within the buffer. In this study, tile NO3-N concentration reductions were characterized through two different saturated buffers at a working farm site in eastern Iowa. Study objectives were to (1) evaluate the hydrogeology and water quality patterns in the saturated buffer and (2) quantify the reduction in tile NO3-N concentration from the saturated buffer installation. Results showed that the two saturated buffers are reducing NO3-N concentrations in tile drainage water from input concentrations of approximately 15 mg/l to levels < 1.5 mg/l at the streamside well locations. The reduction occurs rapidly in the fine-textured and organic-rich alluvial soils with most of the reduction occurring within 1.5 m of the distribution line. Denitrification is hypothesized as being primarily responsible for the concentration reductions based on soil and water chemistry conditions, completion of a geophysical survey (quantifying low potential for N loss to deeper aquifers), and comparisons to other similar Iowa sites. The study provides more assurance to new adopters that this practice can be installed in many areas throughout the Midwestern Cornbelt region.

Soil sedimentation and quality within the roadside ditches of an agricultural watershed.

Roadside ditches are an integral component to the >6.3 million km of roadsides in the U.S. and act as drainageways for millions of hectares of watershed runoff. Our study of six roadside ditches in Lime Creek watershed characterized soil nutrients and heavy metal patterns as well as quantified the physical and hydrological properties of ditch soils. At all ditch sites, we identified significant sedimentation of silt-sized particles, total nitrogen, and soil carbon in shallow roadside ditch soils. A post-settlement surface soil horizon significantly higher in silt content was observed compared to the underlying subsoil and parent material. Although accumulation of several heavy metals was measured in ditch soils, significant variability was not observed within the ditch environment. Most of the heavy metal concentrations were found to be either similar to or lower than state-wide averages. Higher levels of calcium near the roads were likely due to annual use of road deicers. Overall, we estimated that 42 Mg/ha of total carbon and 5 Mg/ha of total nitrogen are being stored in agricultural ditch soils, which is similar to that of surrounding agricultural land in terms of total carbon storage, but much higher than estimates of total nitrogen storage. Our study of six roadside ditches in an eastern Iowa watershed documented the soil chemistry, morphology, and sediment accumulation that occurred since ditch construction. Further research is needed to develop a better understanding of how the soil and water conditions in the ditches related to the watershed areas that feed them.

Distribution and mass of groundwater orthophosphorus in an agricultural watershed.

Orthophosphorus (OP) is the form of dissolved inorganic P that is commonly measured in groundwater studies, but the spatial distribution of groundwater OP across a watershed has rarely been assessed. In this study, we characterized spatial patterns of groundwater OP concentrations and loading rates within the 5218ha Walnut Creek watershed (Iowa) over a two-year period. Using a network of 24 shallow (<6m) monitoring wells established across watershed, OP concentrations ranged from <0.01 to 0.58mg/l in all samples (n=147) and averaged 0.084±0.107mg/l. Groundwater OP concentrations were higher in floodplains and OP mass loading rates were approximately three times higher than in uplands. We estimated that approximately 1231kg of OP is present in floodplain groundwater and 2869kg is present in upland groundwater within the shallow groundwater zone (0-5m depth). Assuming no new inputs of OP to shallow groundwater, we estimated it would take approximately eight years to flush out existing OP mass present in the system. Results suggest that conservation practices focused on reducing OP loading rates in floodplain areas may have a disproportionately large water quality benefit compared to upland areas.

Subsurface nutrient processing capacity in agricultural roadside ditches.

Roadside ditches located throughout urban and rural landscapes are integral components of watershed-scale hydrologic processes but their capacity to reduce nutrients in the subsurface environment has not been investigated. In this study, vegetation, soil and groundwater conditions were characterized in six roadside ditches in the 66 km2 Lime Creek watershed in eastern Iowa. Shallow water table wells were installed at 17 locations in six transects and sampled monthly in 2017 to evaluate spatial and temporal patterns. Vegetation characteristics were surprisingly diverse but was not found to be a significant factor in water quality patterns. Groundwater NO3-N concentrations were <1 mg/L in wells at two transects and were observed to decrease from upgradient to downgradient positions at four locations (average 60% reduction). Water table levels were very shallow (<0.3 m) at nearly all sites, and the loamy and organic rich ditch soils appeared sufficiently anaerobic for subsurface processing of NO3-N via denitrification to occur. Groundwater dissolved reactive phosphorus concentrations did not vary systematically among the sites whereas two of the roadside ditches had Cl concentrations indicative of road salt encroachment. With estimated NO3-N reductions equivalent to typical wetland N reductions we recommend consideration of roadside ditches to serve as "linear wetlands" for watershed-scale treatment of nonpoint source pollution.