Large Temporal Variations of Functional Properties of Outdoor Equestrian Arena Surfaces and a New Concept of Evaluating Reactivity With Light Weight Deflectometer Settlement Curves.

Sports physiological properties of ten sand or sand-mineral outdoor arenas, five with vertical drainage systems and five with an ebb and flow like system were assessed over a period of 8 weeks. For each arena, the riding zone was spatially delineated, nine locations at medium to intensely used zones were selected by simple random sampling and used along the whole measurement period. A total of 72 values for the dynamic deflection modulus (Evd), attenuation (s/v), settlement (s) and moisture content (Vol %) were analyzed for each arena. A novel technique to analyze the settlement curves of the light weight deflectometer (LWD) to describe reactivity of the footing surface was introduced. Statistical testing was done by linear mixed models. Three of the five arenas with a vertical watering system were judged to be hard (Evd > 20 MN/m2), whereas all five arenas with an ebb and flow like watering systems were medium hard (Evd = 10-20 MN/m2) over the entire 8 weeks. Significant (P < .01) temporal differences in Evd, s/v and moisture were demonstrated for both watering systems; however, the spatial and temporal variations were much lower with the ebb-flow system. Temporal consistency in the parameters over the test weeks appeared to be a criterion for stability of the arena surface. The analysis of the settlement curves of the LWD showed that the slope symmetry has a large potential to describe the restoration of the energy of an equestrian surface than only the settlement, which requires further validation.

Towards Net Zero Greenhouse Gas Emissions in the Energy and Chemical Sectors in Switzerland and Beyond - A Review.

In today's societies, climate-damaging and finite fossil resources such as oil and natural gas serve a dual purpose as energy source and as carbon source for chemicals and plastics. To respond to the finite availability and to meet international climate goals, a change to a renewable energy and raw material basis is inevitable and represents a highly complex task. In this review, we assess possible technology paths for Switzerland to reach these goals. First, we provide an overview of Switzerland's current energy demand and discuss possible renewable technologies as well as proposed scenarios to defossilize the current energy system. In here, electric vehicles and heat pumps are key technologies, whereas mainly photovoltaics replace nuclear power to deliver clean electricity. The production of chemicals also consumes fossil resources and for Switzerland, the oil demand for imported domestically used chemicals and plastics corresponds to around 20% of the current energetic oil demand. Thus, we additionally summarize technologies and visions for a sustainable chemical sector based on the renewable carbon sources biomass, CO2 and recycled plastic. As biomass is the most versatile renewable energy and carbon source, although with a limited availability, aspects and proposed strategies for an optimal use are discussed.

Techno-economic assessment of bioethanol production from lignocellulose by consortium-based consolidated bioprocessing at industrial scale.

Lignocellulose-based biofuels are of major importance to mitigate the impact of international traffic and transport on climate change while sustaining agricultural land for food supply. Highly integrated systems like consolidated bioprocessing (CBP), where enzyme production, enzymatic hydrolysis and fermentation of the released sugars are carried out in one reactor, offer the highest potential to save costs and to make lignocellulose-based biofuels economically competitive. The work described here showed that CBP based on a microbial consortium operated at full-scale (2000 t/d) saves up to 27.5 % of the total ethanol production costs compared to conventional ethanol production from lignocellulose in individual process steps. The cost savings are mainly achieved through lower CAPEX due to less apparatus requirements because of the integrated process, as well as through lower OPEX since no glucose is needed for enzyme production. A comparison with literature estimations of cost savings of CBP based on genetically modified microorganisms results in approximately the same range. As a result of a detailed sensitivity analysis, scale and yield were identified as the main cost-pushers from a process point of view, whereas the price level of the plant location has the highest impact on the investment conditions. In the EU, CBP yields enough margin for profitable production and the possibility to decentralize biomass valorization, whereas in the world's largest ethanol market, the U.S, profitable production of lignocellulosic ethanol can only be achieved by CBP combined with other cost saving techniques, such as utilization of cost-free waste feedstocks, since ethanol has undergone a considerable price slump.

A cellulolytic fungal biofilm enhances the consolidated bioconversion of cellulose to short chain fatty acids by the rumen microbiome.

The ability of the multispecies biofilm membrane reactors (MBM reactors) to provide distinguished niches for aerobic and anaerobic microbes at the same time was used for the investigation of the consolidated bioprocessing of cellulose to short chain fatty acids (SCFAs). A consortium based consolidated bioprocess (CBP) was designed. The rumen microbiome was used as the converting microbial consortium, co-cultivated with selected individual aerobic fungi which formed a biofilm on the tubular membrane flushed with oxygen. The beneficial effect of the fungal biofilm on the process yields and productivities was attributed to the enhanced cellulolytic activities compared with those achieved by the rumen microbiome alone. At 30 °C, the MBM system with Trichoderma reesei biofilm reached a concentration 39% higher (7.3 g/L SCFAs), than the rumen microbiome alone (5.1 g/L) using 15 g/L crystalline cellulose as the substrate. Fermentation temperature was crucial especially for the composition of the short chain fatty acids produced. The temperature increase resulted in shorter fatty acids produced. While a mixture of acetic, propionic, butyric, and caproic acids was produced at 30 °C with Trichoderma reesei biofilm, butyric and caproic acids were not detected during the fermentations at 37.5 °C carried out with Coprinopsis cinerea as the biofilm forming fungus. Apart from the presence of the fungal biofilm, no parameter studied had a significant impact on the total yield of organic acids produced, which reached 0.47 g of total SCFAs per g of cellulose (at 30 °C and at pH 6, with rumen inoculum to total volume ratio equal to 0.372).