Low-Temperature Upcycling of Polypropylene Waste into H2 Fuel via a Novel Tandem Hydrothermal Process.

Plastic waste is a promising and abundant resource for H2 production. However, upcycling plastic waste into H2 fuel via conventional thermochemical routes requires relatively considerable energy input and severe reaction conditions, particularly for polyolefin waste. Here, we report a tandem strategy for the selective upcycling of polypropylene (PP) waste into H2 fuel in a mild and clean manner. PP waste was first oxidized into small-molecule organic acids using pure O2 as oxidant at 190 °C, followed by the catalytic reforming of oxidation aqueous products over ZnO-modified Ru/NiAl2 O4 catalysts to produce H2 at 300 °C. A high H2 yield of 44.5 mol/kgPP and a H2 mole fraction of 60.5 % were obtained from this tandem process. The entire process operated with almost no solid residue remaining and equipment contamination, ensuring relative stability and cleanliness of the reaction system. This strategy provides a new route for low-temperature transforming PP and improving the sustainability of plastic waste disposal processes.

Low-temperature upcycling of PET waste into high-purity H2 fuel in a one-pot hydrothermal system with in situ CO2 capture.

The accumulation and improper disposal of a large amount of plastic waste have exacerbated the deterioration of the global ecosystem and environment. To simplify the complex management system and alleviate the environmental impact of plastic wastes, this study reports a novel one-pot hydrothermal conversion strategy for polyethylene terephthalate (PET), integrating three steps, namely depolymerization, subsequent in-situ aqueous phase reforming, and in-situ CO2 capture. Here, the PET waste was converted directly into the clean high-purity H2 fuel and the disodium terephthalate (Na2-TPA). A high yield of H2 at 23.7 mol/kgPET with ca. 99 % of H2 concentration was obtained at a temperature as low as 240 °C. The feasibility of this strategy in handling real-world PET plastic wastes was demonstrated through a series of tests on beverage bottles, food packaging, and polyester fabric waste. The Na2-TPA crystals produced from the proposed PET conversion system exhibited purity close to that of the standard sample, and thus had the potential to be directly used as an electrode material. Overall, this strategy provides an efficient way to transform PET waste into high-value products and improves the sustainability of the PET waste disposal process.

Catalytic Reforming of the Aqueous Phase Derived from Diluted Hydrogen Peroxide Oxidation of Waste Polyethylene for Hydrogen Production.

The thermal degradation and conversion of waste polyethylene (PE) using a two-step process including hydrothermal oxidation (HO) and aqueous phase reforming (APR) were investigated. The objective of this study was to achieve efficient disposal of waste PE and generate H2 in a mild and green way. The effects of various HO conditions on both HO and APR processes were studied. A high H2 O2 concentration caused overoxidation of PE resulting in more CO2 . Decreasing the H2 O2 concentration weakened the overoxidation. The process using diluted H2 O2 exhibited the highest selectivity for acetic acid among the produced carboxylic acids. When the HO temperature exceeded 200 °C, there was an increase in the CO2 yield during the HO process and a decrease in the H2 yield during the APR process. In addition, the effects of various monometallic and bimetallic catalysts on the reforming of the aqueous phase from the HO of PE were discussed. The highest H2 mole fraction (51.52 %) in gaseous products from the APR process was obtained with Ru/mesoporous carbon. Nevertheless, Ru-Ni exhibited a higher stability than the monometallic Ru catalyst.

Hydrothermal carbonization of food waste after oil extraction pre-treatment: Study on hydrochar fuel characteristics, combustion behavior, and removal behavior of sodium and potassium.

This study aims to convert oil extracted food waste (OEFW) into hydrochar as potential solid fuel via hydrothermal carbonization (HTC) process. The effect of HTC temperature and residence time on the physicochemical characteristic, combustion behavior, and the removal behavior of sodium and potassium were evaluated. The raw OEFW material was successfully converted into energy densified hydrochar with higher high heating value (HHV) (21.13-24.07 MJ/kg) and higher fuel ratio (0.112-0.146). In addition, carbon content in hydrochar increased to 46.92-51.82% after HTC at various operating conditions. Compared with OEFW, the hydrochar had more stable and longer combustion process with the higher ignition temperature and burnout temperature. Besides, the HTC process showed high removal rates of sodium and potassium. It was found that the HTC temperature resulted in a significant reduction of sodium and potassium in hydrochar as compared to the residence time. The highest removal rate of sodium (70.98%) and potassium (84.05%) was obtained. Overall, the results show that the HTC is a promising alternative for conventional technologies (e.g., incineration and landfill) for treatment and energy conversion of OEFW.

Gasification of effluent from food waste treatment process in sub- and supercritical water: H2-rich syngas production and pollutants management.

The effluent of food waste (FWE) is generated during food waste treatment process. It contains high organic matter content and is difficult to be efficiently treated. In this study, the sample was collected from a 200 t/d food waste treatment center in Hangzhou, China. Subcritical and supercritical water gasification were employed to decompose and convert FWE into energy. The effects of reaction temperature (300-500 °C), residence time (20-70 min) and activated carbon loading (0.5-3.5 wt%) on syngas production and the remaining pollutants in liquid residue were investigated. It was found that higher reaction temperature and longer residence time favored gasification and pollutant decomposition, resulting in higher H2 production and gasification efficiencies. It is noteworthy that the NH3-N was difficult to be converted and removed under current experimental conditions. The addition of activated carbon was found to increase the gasification efficiency. The highest total gas yield, H2 yield, carbon conversion efficiency, gasification efficiency, total organic carbon removal efficiency and chemical oxygen demand removal efficiency were obtained from gasification at 500 °C for 70 min with 3.5 wt% activated carbon.

Production of H2-rich syngas from gasification of unsorted food waste in supercritical water.

In China, waste sorting practice is not strictly followed, plastics, especially food packaging, are commonly mixed in food waste. Supercritical water gasification (SCWG) of unsorted food waste was conducted in this study, using model unsorted food waste by mixture of pure food waste and plastic. Different operating parameters including reaction temperature, residence time, and feedstock concentration were investigated. Moreover, the effect of three representative food additives namely NaCl, NaHCO3 and Na2CO3 were tested in this work. Finally, comparative analysis about SCWG of unsorted food waste, pure food waste, and plastic was studied. It was found that higher reaction temperature, longer residence time and lower feedstock concentration were advantageous for SCWG of unsorted food waste. Within the range of operating parameters in this study, when the feedstock concentration was 5 wt%, the highest H2 yield (7.69 mol/kg), H2 selectivity (82.11%), total gas yield (17.05 mol/kg), and efficiencies of SCWG (cold gas efficiency, gasification efficiency, carbon gasification efficiency, and hydrogen gasification efficiency) were obtained at 480 °C for 75 min. Also, the addition of food additives with Na+ promoted the SCWG of unsorted food waste. The Na2CO3 showed the best catalytic performance on enhancement of H2 and syngas production. This research demonstrated the positive effect of waste sorting on the SCWG of food waste, and provided novel results and information that help to overcome the problems in the process of food waste treatment and accelerate the industrial application of SCWG technology in the future.