Phytofabricated ZnO-NPs mediated by Hibiscus tiliaceus leaf extract and its potential as a diosgenin delivery vehicle.

Zinc oxide nanoparticles (ZnO-NPs) have provided promising potential in the biomedical field, including the ability to overcome various health problems. Diosgenin is used to treat multiple health disorders but has very low solubility in water. Using ZnO-NPs as a diosgenin delivery vehicle was expected to increase the solubility of diosgenin, which would affect its bioavailability. This study demonstrates phytofabrication and characterization of ZnO-NPs, loading of diosgenin onto the ZnO-NPs, characterization of the product (ZnO-NPs/diosgenin), and evaluations of diosgenin release. Phytofabrication of the ZnO-NPs was carried out with zinc precursors and Hibiscus tiliaceus leaf extract (HLE) obtained with various extraction solvents. To explore the potential of using the ZnO-NPs as a diosgenin delivery vehicle, diosgenin release from the ZnO-NPs/diosgenin was studied. Based on the X-ray fluorescence (XRF) and X-ray diffraction (XRD) results, ZnO-NPs with high purity have been successfully fabricated. Nano-sized particles were detected using scanning electron microscopy (SEM) and confirmed by transmission electron microscopy (TEM), revealing the smallest particle size of 45.924 ± 27.910 nm obtained from the methanol extract with the zinc acetate precursor. The ZnO-NPs had hexagonal wurtzite and rod-like structures. Diosgenin was successfully added to the ZnO-NPs with loadings of 79.972% for ZnO-HLMEA-D500 (ZnO-NPs/diosgenin produced by doping with a 500 µg mL-1 of diosgenin solution) and 39.775% for ZnO-HLMEA-D1000 (ZnO-NPs/diosgenin produced by doping with a 1000 µg mL-1 of diosgenin solution). The solubilities of diosgenin from ZnO-HLMEA-D500 and ZnO-HLMEA-D1000 were higher than that of free diosgenin, confirming that ZnO-NPs have potential as delivery vehicles for diosgenin and conceivably other water-insoluble drugs.

Modification of Sugar Cane Bagasse with CTAB and ZnO for Methyl Orange and Methylene Blue Removal.

Sugar cane bagasse (SB) was modified with cetyltrimethylammonium bromide (CTAB), followed by impregnation with zinc oxide (ZnO) to create a synergistic adsorption and photocatalytic system for methyl orange (MO) and methylene blue (MB) removal. The presence of CTAB and ZnO was confirmed by X-ray diffraction, Fourier transform infrared, and energy dispersive X-ray (for Zn and O). Modification of SB with CTAB (CSB) generated more positive sites on the surface of SB, which enhanced MO removal compared with that of pristine SB. ZnO impregnation induces a decrease in MO removal due to the ZnO presence on the CSB surface, which might reduce the positive sites on the CSB. In addition, the positive sites on CSB can interact with Zn2+ and O2- to form ZnO and lead to a decrease in MO removal. In contrast, the presence of ZnO facilitated good removal of MB compared to CSB, indicating that the photocatalytic process plays a greater role in removing MB. However, the addition of H2O2 can improve MO and MB removal under irradiation due to the formation of external •OH. The photocatalytic performance of MO and MB was also observed to be favored under acidic and alkaline conditions, respectively.

Adsorption and biodegradation of the azo dye methyl orange using Ralstonia pickettii immobilized in polyvinyl alcohol (PVA)-alginate-hectorite beads (BHec-RP).

Biological methods are widely used to treat dye waste, particularly methyl orange (MO) dye. The importance of MO degradation stems from its classification as a toxic dye. Within the scope of this research, successful bio-decolorization of MO was achieved through the use of Ralstonia pickettii bacteria immobilized in a PVA-alginate-hectorite matrix (BHec-RP). The optimum conditions for the degradation were observed at a composition of PVA (10%), hectorite (1%), static incubation, 40 °C, and pH 7. Subsequently, the adsorption kinetics of BHec-RP (dead cells) as well as the degradation kinetics of BHec-RP (live cells) and MO using free R. pickettii cells were evaluated. The decolorization of MO using BHec-RP (dead cells) is an adsorption process following pseudo-first-order kinetics (0.6918 mg g-1 beads) and occurs in a monolayer or physical process. Meanwhile, the adoption of BHec-RP (live cells) and free R. pickettii cells shows a degradation process under pseudo-first-order kinetics, with the highest rates at an initial MO concentration of 50 mg L-1 being 0.025 mg L-1 h-1 and 0.015 mg L-1 h-1, respectively. These results show that the immobilization system is superior compared to free R. pickettii cells. Furthermore, the degradation process shows the inclusion of several enzymes, such as azoreductase, NADH-DCIP reductase, and laccase, presumed to be included in the fragmentation of molecules. This results in five fragments based on LC-QTOF/MS analysis, with m/z values of 267.12; 189.09; 179.07; 169.09; and 165.05.

Spectroscopic Evidence of Localized Small Polarons in Low-Dimensional Ionic Liquid Lead-Free Hybrid Perovskites.

Rational design is an important approach to consider in the development of low-dimensional hybrid organic-inorganic perovskites (HOIPs). In this study, 1-butyl-1-methyl pyrrolidinium (BMP), 1-(3-aminopropyl)imidazole (API), and 1-butyl-3-methyl imidazolium (BMI) serve as prototypical ionic liquid components in bismuth-based HOIPs. Element-sensitive X-ray absorption spectroscopy measurements of BMPBiBr4 and APIBiBr5 reveal distinct resonant excitation profiles across the N K-edges, where contrasting peak shifts are observed. These 1D-HOIPs exhibit a large Stokes shift due to the small polaron contribution, as probed by photoluminescence spectroscopy at room temperature. Interestingly, the incorporation of a small fraction of tin (Sn) into the APIBiBr5 (Sn/Bi mole ratio of 1:3) structure demonstrates a strong spectral weight transfer accompanied by a fast decay lifetime (2.6 ns). These phenomena are the direct result of Sn-substitution in APIBiBr5, decreasing the small polaron effect. By changing the active ionic liquid, the electronic interactions and optical responses can be moderately tuned by alteration of their intermolecular interaction between the semiconducting inorganic layers and organic moieties.

Recent advances of modification effect in Co3O4-based catalyst towards highly efficient photocatalysis.

Tricobalt tetroxide (Co3O4) has been developed as a promising photocatalyst material for various applications. Several reports have been published on the self-modification of Co3O4 to achieve optimal photocatalytic performance. The pristine Co3O4 alone is inadequate for photocatalysis due to the rapid recombination process of photogenerated (PG) charge carriers. The modification of Co3O4 can be extended through the introduction of doping elements, incorporation of supporting materials, surface functionalization, metal loading, and combination with other photocatalysts. The addition of doping elements and support materials may enhance the photocatalysis process, although these modifications have a slight effect on decreasing the recombination process of PG charge carriers. On the other hand, combining Co3O4 with other semiconductors results in a different PG charge carrier mechanism, leading to a decrease in the recombination process and an increase in photocatalytic activity. Therefore, this work discusses recent modifications of Co3O4 and their effects on its photocatalytic performance. Additionally, the modification effects, such as enhanced surface area, generation of oxygen vacancies, tuning the band gap, and formation of heterojunctions, are reviewed to demonstrate the feasibility of separating PG charge carriers. Finally, the formation and mechanism of these modification effects are also reviewed based on theoretical and experimental approaches to validate their formation and the transfer process of charge carriers.

Hydrothermal effect of gunningite use Pluronic F127-Gelatin as template and the ibuprofen adsorption performance.

The gunningite has been successfully synthesized using Pluronic F127 and gelatin as template via hydrothermal at 100-200 °C for 12-48 h. By scanning electron microscopy, nitrogen adsorption-desorption, and X-ray diffraction, changes in structure, pore size, and morphology due to ibuprofen adsorption were investigated in gunningite. Various hydrothermal (temperature and time) parameters had an influence on the percentage elimination (%) of ibuprofens. Gunningite's specific surface area intensifies from 14.60 to 24.03 m2/g as the longer hydrothermal time. In batch adsorption studies, the resulting sample was conducted to isotherm and kinetic analysis to evaluate the distribution of ibuprofen between the liquid and solid phases. Pseudo-first-order kinetics with an adsorption capacity range of 27-34.5 mg g-1 were the best fit for the observed data. Consequently, gunningite may be considered a viable adsorbent for the large-scale treatment of water contaminated with ibuprofen and related anti-inflammatory medicines.

Synthesis and characterization of silica gel from Lapindo volcanic mud with ethanol as a cosolvent for desiccant applications.

Lapindo mud (LM) is a volcanic mud from a natural disaster that occurred 16 years ago in Sidoarjo District, East Java, Indonesia. The high amount of silica in the local materials of LM has been extracted for silica gel synthesis via hydrometallurgy methods, followed by sol-gel methods. The presence of ethanol in the synthesis process generated a unique textural property at different ratios between ethanol and sodium silicate (e/ss). Sol-gel mediated silica gel synthesis exhibited mesoporous properties with an amorphous structure, which is a characteristic of the silica gel. The silica gel exhibits silica nanoparticles over the average diameter of 2.08 nm with a spherical morphology and is connected to form an agglomeration structure. Increasing the e/ss ratio enhanced the amount of the hydroxyl group and the specific surface area ranged from 57 to 103 m2 g-1. The moisture adsorption performance of each silica gel showed that the silica gel with an e/ss ratio of 5 : 5 exhibited the highest adsorption capacity measured by conventional gravimetric methods and thermogravimetric analysis of 10.56% and 11.20% gwater gsilica -1, respectively. These results indicated that the silica gel with an e/ss ratio has a high number of hydroxyl groups and more surface-active sites, which is beneficial for the adsorption process. The adsorption capacity of the synthesized silica gel is also higher than that of the commercial silica gel, indicating an excellent performance for desiccant applications.

Synergistic effect of modified pore and heterojunction of MOF-derived α-Fe2O3/ZnO for superior photocatalytic degradation of methylene blue.

Mesoporous heterojunction MOF-derived α-Fe2O3/ZnO composites were prepared by a simple calcination of α-Fe2O3/ZIF-8 as a sacrificial template. The optical properties confirm that coupling of both the modified pore and the n-n heterojunction effectively reduces the possibility of photoinduced charge carrier recombination under irradiation. The mesoporous Fe(25)ZnO with 25% loading of α-Fe2O3 exhibited the best performance in MB degradation, up to ∼100% after 150 minutes irradiation, higher than that of pristine ZnO and α-Fe2O3. Furthermore, after three cycles reusability, mesoporous Fe(25)ZnO still showed an excellent stability performance of up to 95.42% for degradation of MB. The proposed photocatalytic mechanism of mesoporous Fe(25)ZnO for the degradation of MB corresponds to the n-n heterojunction system. This study provides a valuable reference for preparing mesoporous MOF-derived metal oxides with an n-n heterojunction system to enhance MB photodegradation.

Hectorite-CTAB-alginate composite beads for water treatment: kinetic, isothermal and thermodynamic studies.

Encapsulation of hectorite-modified CTAB with Ca-alginate formed reusable adsorbent beads for wastewater treatment. The thermogravimetric analysis (TGA) investigation indicated excellent thermal stability results for BHec-40 compared to Hec-40. Although the mesoporous surface area of BHec-40 decreased to 79.74 m2 g-1 compared to 224.21 m2 g-1 for Hec-40, the hectorite-CTAB-alginate beads showed high adsorption capacity and stability for methyl orange (MO) adsorption with more than 60% removal after five adsorption-desorption cycles. The influence of pH (3-11), temperature (30, 40, and 50 °C), initial concentration (50-400 mg L-1), and contact time were studied to obtain the kinetics and thermodynamics of adsorption. The outcomes revealed a maximum monolayer adsorption capacity of 117.71 mg g-1 for BHec-40. The kinetics of adsorption demonstrated the suitability of using the pseudo-first-order kinetic model, while the equilibrium adsorption data follows the Langmuir isotherm. Thermodynamic analysis indicates physisorption of MO onto BHec-40. BHec-40 improves the reusability as an adsorbent for the removal of anionic dyes from aqueous media.

Natural resources for dye-sensitized solar cells.

While the development of dye-sensitized solar cells (DSSCs) has been ongoing for more than 30 years, the currently obtained efficiency is unsatisfactory. However, the study of DSSC development has produced a fundamental understanding of cell performance and inspired other devices, such as perovskite cell solar cells. DSSCs consist of a dye-sensitized photoanode, a counter electrode, and a redox couple in the electrolyte system. Each of the components has an important role and cofunctions with each other to obtain a high power conversion efficiency. Various modifications to each DSSC component have been applied to improve their performance. Additionally, to generate improvements, the effort to reduce production costs has been crucial. The utilization of natural sources for DSSC components is a possible solution to this issue. The utilization of natural resources also aims to increase the value of the natural resource itself. In this review, the applications of various natural sources for DSSC components are described, as well as the modification efforts that have been made to enhance their performance. The discussion covers the utilization of natural dye for sensitizer dyes in liquid DSSC applications: (1) utilization of biopolymers for quasi-solid DSSC electrolytes, (2) green synthesis methods for photoanode semiconductors, and (3) development of natural carbon counter electrodes. The detailed factors that influence improvements in cell performance are also addressed.

Utilization of red mud waste into mesoporous ZSM-5 for methylene blue adsorption-desorption studies.

Red mud as industrial waste from bauxite was utilized as a precursor for the synthesis of mesoporous ZSM-5. A high concentration of iron oxide in red mud was successfully removed using alkali fusion treatment. Mesoporous ZSM-5 was synthesized using cetyltrimethylammonium bromide (CTABr) as a template via dual-hydrothermal method, and the effect of crystallization time was investigated towards the formation of mesopores. Characterization using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N2 adsorption-desorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) indicated the formation of cubic crystallite ZSM-5 with high surface area and mesopore volume within 6 h of crystallization. Increasing the crystallization time revealed the evolution of highly crystalline ZSM-5; however, the surface area and mesoporosity were significantly reduced. The effect of mesoporosity was investigated on the adsorption of methylene blue (MB). Kinetic and thermodynamic analysis of MB adsorption on mesoporous ZSM-5 was carried out at a variation of adsorption parameters such as the concentration of MB solution, the temperatures of solution, and the amount of adsorbent. Finally, methanol, 1-butanol, acetone, hydrochloric acid (HCl), and acetonitrile were used as desorbing agents to investigate the reusability and stability of mesoporous ZSM-5 as an adsorbent for MB removal.