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1.
Carbohydr Polym ; 297: 120039, 2022 Dec 01.
Article in English | MEDLINE | ID: mdl-36184147

ABSTRACT

Recently, in response to the challenges related to energy development and environmental issues, extensive efforts are being made towards the development of supercapacitors based on green and sustainable resources. Aerogel electrodes offer high energy/power autonomy, fast charge-discharge rates, and long charge/discharge cycles over composite film electrodes due to their unique structure, ultra-lightness, high porosity, and large specific surface area. Nanocellulose (NC), a sustainable nanomaterial, has gained popularity as a supercapacitor electrode material owing to its remarkable properties such as biodegradability, tunable surface chemistry, ability to develop 3D aerogel structures, etc. This comprehensive review summarizes the research progress on developing NC-based aerogels for supercapacitor applications. First, the fundamentals of NC extraction from cellulose sources and aerogel processing routes are discussed. An attempt is made to correlate the electrochemical performance of NC-based electrodes with their aerogel structures. Finally, challenges and future prospects for the advancement of NC-based aerogels are addressed.


Subject(s)
Cellulose , Nanostructures , Cellulose/chemistry , Electrodes , Gels/chemistry , Porosity
2.
ACS Nano ; 15(3): 3849-3874, 2021 Mar 23.
Article in English | MEDLINE | ID: mdl-33710860

ABSTRACT

Naturally derived nanocellulose (NC) is a renewable, biodegradable nanomaterial with high strength, low density, high surface area, and tunable surface chemistry, which allows its interaction with other polymers and nanomaterials in a controlled manner. In recent years, NC aerogel has gathered a lot of attention due to environmental concerns. This review presents recent developments of NC-based aerogels and their controlled interactions with other polymers and nanomaterials for thermal applications that include electronic devices, the apparel industry, superinsulating materials, and flame-retardant smart building materials. After going through the distinctive properties of NC aerogels, they are orderly categorized and discussed as thermally insulated, thermally conductive, and flame-retardant materials.

3.
Carbohydr Polym ; 255: 117479, 2021 Mar 01.
Article in English | MEDLINE | ID: mdl-33436241

ABSTRACT

The research in eco-friendly and sustainable materials for packaging applications with enhanced barrier, thermo-mechanical, rheological and anti-bacterial properties has accelerated in the last decade. Last decade has witnessed immense interest in employing nanocellulose (NC) as a sustainable and biodegradable alternative to the current synthetic packaging barrier films. This review article gathers the research information on NC as a choice for food packaging material. It reviews on the employment of NC and its various forms including its chemico-physical treatments into bio/polymers and its impact on the performance of nanocomposites for food packaging application. The review reveals the fact that the research trends towards NC based materials are quite promising for Active Packaging (AP) applications, including the Controlled Release Packaging (CRP) and Responsive Packaging (RP). Finally, it summarizes with the challenges of sustainable packaging, gray areas that need an improvement/focus in order to commercially exploit this wonderful material for packaging application.


Subject(s)
Anti-Bacterial Agents/chemistry , Cellulose/chemistry , Delayed-Action Preparations/chemistry , Food Packaging/methods , Nanocomposites/chemistry , Acrylic Resins/chemistry , Anti-Bacterial Agents/pharmacology , Biodegradation, Environmental , Cellulose/ultrastructure , Chitosan/chemistry , Delayed-Action Preparations/pharmacology , Dopamine/chemistry , Humans , Membranes, Artificial , Polyesters/chemistry , Steam/analysis , Tannins/chemistry
4.
Int J Biol Macromol ; 166: 587-600, 2021 Jan 01.
Article in English | MEDLINE | ID: mdl-33130267

ABSTRACT

Cellulose is abundant in the nature and nanocellulose (NC) in particular is regarded as a credible green substrate to be used in bio nanocomposites for various applications. NC exhibits excellent mechanical reinforcement properties comparable to conventionally used materials due to its high specific surface area and tunable surface chemistry. Additionally, low toxicity, biodegradability and biocompatibility of NC deem it a promising material for use in different biomedical applications. In this review, we highlight the biomedical applications of NC based hydrogels and aerogels/nanocomposites and advancements of their employment in the areas of wound dressing, drug delivery, tissue engineering, scaffolds and biomedical implants. This review also explores the recent use of NC in making biosensors for the detection of cholesterol, various enzymes and diseases, heavy metal ions in human sweat and urine, and for general health monitoring.


Subject(s)
Biosensing Techniques/methods , Cellulose/chemistry , Nanostructures/chemistry , Animals , Drug Delivery Systems , Humans , Porosity , Wound Healing
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