Phononic Cavity Optomechanics of Atomically Thin Crystal in Plasmonic Nanocavity.

In the picture of molecular cavity optomechanics, surface-enhanced Raman scattering (SERS) can be understood as molecular oscillators parametrically coupled to plasmonic nanocavities supporting an extremely localized optical field. This enables SERS from conventional fingerprint detection toward quantum nanotechnologies associated with, e.g., frequency upconversion and optomechanically induced transparency. Here, we study a phononic cavity optomechanical system consisting of a monolayer MoS2 placed inside a plasmonic nanogap, where the coherent phonon-plasmon interaction involves the collective oscillation from tens of thousands of unit cells of the MoS2 crystal. We observe the selective nonlinear SERS enhancement of the system as determined by the laser-plasmon detuning, suggesting the dynamic backaction modification of the phonon populations. Anomalous superlinear power dependence of a second-order Raman-inactive phonon mode with respect to the first-order phonons is also observed, indicating the distinctive properties of the phononic nanodevice compared with the molecular system. Our results promote the development of robust phononic optomechanical nanocavities to further explore the related quantum correlation and nonlinear effects including parametric instabilities.

Cost-Effective Calculation of Collective Electronic Excitations in Graphite Intercalated Compounds.

Graphite/graphene intercalation compounds with good and improving electrical transport properties, optical properties, magnetic properties and even superconductivity are widely used in battery, capacitors and so on. Computational simulation helps with predicting important properties and exploring unknown functions, while it is restricted by limited computing resources and insufficient precision. Here, we present a cost-effective study on graphite/graphene intercalation compounds properties with sufficient precision. The calculation of electronic collective excitations in AA-stacking graphite based on the tight-binding model within the random phase approximation framework agrees quite well with previous experimental and calculation work, such as effects of doping level, interlayer distance, and interlayer hopping on 2D π plasmon and 3D intraband plasmon modes. This cost-effective simulation method can be extended to other intercalation compounds with unlimited intercalation species.