Assessment of polycyclic aromatic hydrocarbons in three environmental components from a tropical estuary in Northeast Brazil.

The evaluation of occurrence, risk quotient (RQ), bioaccumulation factor (BAF), and sources of PAH was conducted in Sergipe-Poxim estuarine system. PAH distribution that ranged from 7.1 to 30.9 ng L-1 (surface water, SW), 5.4 to 19.5 ng g-1 (sediment, S), and 4.3 to 18.1 ng g-1 (oyster, O), characterized the environment with low contamination; 2-3 (SW), 5-6 (S), and 4 (O) PAH rings accounted for 54.5%, 68.7%, and 87.7%, respectively, along with naphthalene (SW), dibenzo(a,h)anthracene (S), and pyrene (O) as the prevailing compounds. PCA suggested the predominance of particular groups related to SW (LMW-PAH), S (HMW-PAH), and O (pyrene and fluoranthene). Furthermore, one sample of O presented a high PAH bioavailability as shown through the BAF, with emphasis on pyrene (BAF = 26.8). The RQ showed a low to moderate range in SW and S; hence, in-depth information about the possible toxic effect in organisms of this region is required.

Concentration, distribution and source apportionment of polycyclic aromatic hydrocarbons (PAH) in Poxim River sediments, Brazil.

The individual concentrations, total amount and sources of 16 priority polycyclic aromatic hydrocarbons (PAH) in sediments collected along of the Poxim River, Aracaju, Brazil, were for the first time determined. The ΣPAH ranged between 2.2±1.5ngg-1 and 28.4±6.9ngg-1, with a mean value of 14.4±9.3ngg-1. The Pearson correlation test and Principal component analysis (PCA) were used to assess the correlation between the PAH, organic matter and grain size; and to differentiate the sampling stations. Diagnostic ratios presented predominance of pyrogenic sources. Therefore, the PAH quantified showed the influence of anthropogenic activities near of the Poxim River.