Synthesis of BaZrS3 and BaHfS3 Chalcogenide Perovskite Films Using Single-Phase Molecular Precursors at Moderate Temperatures.

Chalcogenide perovskites have garnered interest for applications in semiconductor devices due to their excellent predicted optoelectronic properties and stability. However, high synthesis temperatures have historically made these materials incompatible with the creation of photovoltaic devices. Here, we demonstrate the solution processed synthesis of luminescent BaZrS3 and BaHfS3 chalcogenide perovskite films using single-phase molecular precursors at sulfurization temperatures of 575 °C and sulfurization times as short as one hour. These molecular precursor inks were synthesized using known carbon disulfide insertion chemistry to create Group 4 metal dithiocarbamates, and this chemistry was extended to create species, such as barium dithiocarboxylates, that have never been reported before. These findings, with added future research, have the potential to yield fully solution processed thin films of chalcogenide perovskites for various optoelectronic applications.

Solution Deposition for Chalcogenide Perovskites: A Low-Temperature Route to BaMS3 Materials (M = Ti, Zr, Hf).

Chalcogenide perovskites, including BaZrS3, have been suggested as highly stable alternatives to halide perovskites. However, the synthesis of chalcogenide perovskites has proven to be a significant challenge, often relying on excessively high temperatures and methods that are incompatible with device integration. In this study, we developed a solution-based approach to the deposition of BaZrS3. This method utilizes a combination of a soluble barium thiolate and nanoparticulate zirconium hydride. Following solution-based deposition of the precursors and subsequent sulfurization, BaZrS3 can be obtained at temperatures as low as 500 °C. Furthermore, this method was extended to other chalcogenide perovskite (BaHfS3) and perovskite-related (BaTiS3) materials.

The Relationship Between Physical Characteristics and Maximal Strength in Men Practicing the Back Squat, the Bench Press and the Deadlift.

This study was designed to quantify the relationships between physical characteristics and maximal strength in the back squat, the bench press and the deadlift on powerlifters and football players. Eighteen male junior drug-tested classic powerlifters and seventeen NCAA Division II American football players' anthropometric measurements were taken to compare them with maximal strength results from either a powerlifting meet or testing from their supervised strength and conditioning program. Pearson's bivariate correlations analysis revealed (statistical significance was set at p<0.05) that individuals with a greater (Wilks points) back squat, generally presented a higher Bodyweight (BW) (r=0.37), Body Mass Index (BMI) (r=0.45), Bodyfat Percentage (BF%) (r=0.36), Hip (r=0.41), Waist (r=0.35) and Torso (r=0.41) Circumference (C), Hip C/Height (r=0.46), Waist C/Height (r=0.39) and Torso C/Height (r=0.45) ratios. The individuals with a greater bench press generally presented a higher BMI (r=0.37), Lean Body Weight (LBW) (r=0.36), Hip C (r=0.39) and Hip C/Height ratio (r=0.39). On the other hand, individuals with a greater deadlift were generally older (r=0.34), shorter (r=-0.41), had shorter thighs (r=-0.52) and trunks (r=-0.36), smaller Thigh Length (L)/Height ratio (r=-0.44), Waist C/Hip C (r=-0.41) and Thigh L/Lower Leg L (r=-0.53) ratios, but a higher Lower Leg L/Height ratio (r=-046). The results of this study should be utilized by strength and conditioning coaches to deepen their comprehension of their athletes' physical characteristics in order to help them develop strength through their advantages. Further research should focus on evaluating how physical characteristics affect performance in different squat, bench, and deadlift stances.

Pedicle screw design and cement augmentation in osteoporotic vertebrae: effects of fenestrations and cement viscosity on fixation and extraction.

STUDY DESIGN: Experimental, human cadaveric study. OBJECTIVE: To assess the fixation effects of injecting cement augmentation before screw insertion or after insertion of fenestrated screws; the effect of modulating cement viscosity; and the effects of these techniques on screw removal. SUMMARY OF BACKGROUND DATA: It seems clear that cement augmentation can enhance pedicle screw fixation in osteoporotic bone. What remains to be demonstrated is the aspects of optimal technique such that fixation is enhanced with the greatest safety profile. METHODS: Part I: Human osteoporotic vertebrae were instrumented with solid (nonaugmented) screws, solid screws with polymethylmethacrylate (PMMA), partially cannulated fenestrated (Pfen) screws, or fully cannulated fenestrated (Ffen) screws through which PMMA was injected. Screw fixation was tested in pullout. Part II: Ffen screws were augmented with standard low-viscosity PMMA versus high-viscosity PMMA. Part III: Sample cohorts were extracted from vertebrae to assess required torque and characterize difficulty of extraction. RESULTS: Part I: Pfen screws demonstrated the greatest fixation with mean failure force of 690 ± 182 N. All methods of cement augmentation demonstrated significant increases in screw fixation. Part II: Ffen screws did not demonstrate a significant difference in pullout strength when high-viscosity PMMA was used as compared with low-viscosity PMMA. Part III: Mean extraction torque values for solid augmented screws, Ffen screws, and Pfen screws were 1.167, 1.764, and 1.794 Nm, respectively, but these differences did not reach significance. None of the osteoporotic vertebrae sustained catastrophic failure during augmented screw extraction. CONCLUSION: Polymethylmethacrylate cement augmentation clearly enhances pedicle screw fixation in osteoporotic vertebrae when tested in pure pullout. The technique used for cement injection and choice of specialty screws can have a significant impact on the magnitude of this effect. Fenestrated screws have the capacity to confine cement placement in the vertebral body and may provide enhanced safety from cement extrusion into the spinal canal. It is feasible to inject high-viscosity PMMA through this fenestration geometry, and higher-viscosity cement may enhance the fixation effect.