1.
Synthesis (Stuttg)
; 2009(17): 2905, 2009 Sep 01.
Article
in English
| MEDLINE
| ID: mdl-20151022
ABSTRACT
Details in developing a stereodivergent approach to the lepadin family and establishing an entry to both C2,8a-syn and C2,8a-anti relative stereochemical manifolds through a common intermediate are described here. This works paves a foundation for constructing all members of the lepadin family, which consists of three subsets based on an array of interesting relative configurations. These efforts underline the prominence of aza-[3 + 3] annulation as a unified strategy in alkaloid synthesis.