Novel chitosan based smart cathode electrocatalysts for high power generation in plant based-sediment microbial fuel cells.

Smart electrocatalysts are synthesized from chitosan polymer and magnetic particles to enhance power by plant based sediment microbial fuel cell (P-SMFC). Cross-linked procedure is performed gelatinous microspheres as supporting metals (Cu, Pd, Mn, Pt, and Ni) and magnetic particles which create a porous structure on smart catalysts for increase ORR activity. A high and quick OCV rising is achieved with addition of Mag-Pd-Ch in reactor, and OCV value immediately increase from 0.408 V to 0.819 V within 10 minutes. The highest power density is also obtained as 1298 mW m-2 for reactor with Mag-Pd-Ch, which was 15 times higher than control. Significant metal leaching is observed using plant growth for smart catalyst containing Cu. Consequently, high power production, good stabilization, easy separation from water environment due to magnetic property, and relatively low cost make use of Mag-Pd-Ch both economic and environment friendly tools to enhance power generation in P-SMFC.

Boron (B) removal and bioelectricity captured from irrigation water using engineered duckweed-microbial fuel cell: effect of plant species and vegetation structure.

Boron (B) in the irrigation water can be hazardous to human beings and other aquatic or terrestrial organisms when B concentration exceeds a certain level. More importantly, B removal from irrigation water is relatively difficult using conventional processes. In the present experiment, an innovative treatment model based on monoculture and polyculture duckweed wastewater treatment modules was tested for B-rich irrigation water purification and bioelectricity harvesting. Different modules were designed using Lemna gibba L., Lemna minor L., and their combination in order to determine the most optimal duckweed species and vegetation structure for B removal process and bioelectricity generation in a module. In this respect, the module with a monoculture of Lemna gibba achieved the highest net B removal efficiency (71%) when it was exposed to 4 mg/L B (initial concentration). However, B removal efficiencies from all modules decreased when the initial B concentrations reached up to 4 mg/L in the irrigation water. The highest bioelectricity production was measured as 1.04 V with 17783 mWatt/m2 power density at a current density of 44.06 mA/m2 for module with Lemna gibba in monoculture through sacrificial magnesium anode. Specifically, both monocultures and polyculture removed considerable amounts of organic matter from irrigation water. However, biomass production and total chlorophyll (a + b) concentrations of duckweeds significantly decreased when they were exposed to 32 mg/L B in the irrigation water samples. Consequently, our modules present a holistic perspective to the prevention B toxicity problems in agricultural zones, and are a sustainable strategy for farmers or agricultural experts to produce bioelectricity by a cost-effective and eco-technological method.

Cost-effectiveness of boron (B) removal from irrigation water: an economic water treatment model (EWTM) for farmers to prevent boron toxicity.

Protection of water sources which are used for irrigation has raised great interest in the last years among the environmental strategists due to potential water scarcity worldwide. Excessive boron (B) in irrigation water poses crucial environmental problems in the agricultural zones and it leads to toxicity symptoms in crops, as well as human beings. In the present research, economic water treatment models consist of dried common wetland plants (Lemna gibba, Phragmites australis, and Typha latifolia) and Lemna gibba accumulation was tested and assessed to create a simple, cost-effective, and eco-friendly method for B removal from irrigation water. Significant amount of B was removed from irrigation water samples by EWTMs and B concentrations decreased below < 1 mg L-1 when the components were exposed to 4 and 8 mg L-1 initial B concentrations. Moreover, the results from batch adsorption study demonstrated that dried L. gibba had a higher B loading capacity compare to other dried plants, and B sorption capacity of dried L. gibba was found as 2.23 mg/g. The optimum pH value for sorption modules was found as neutral pH (pH = 7) in the batch adsorption experiment. Boron sorption from irrigation water samples fitted the Langmuir model, mostly B removed from irrigation water during the first 2 h of contact time. Techno-economic analysis indicated that EWTM is a promising method that appears to be both economically and ecologically feasible, and it can also provide a sustainable and practical strategy for farmers to prevent B toxicity in their agricultural zones.

Effect of vegetation type on treatment performance and bioelectric production of constructed wetland modules combined with microbial fuel cell (CW-MFC) treating synthetic wastewater.

An operation of microcosm-constructed wetland modules combined with microbial fuel cell device (CW-MFC) was assessed for wastewater treatment and bioelectric generation. One of the crucial aims of the present experiment is also to determine effect of vegetation on wastewater treatment process and bioelectric production in wetland matrix with microbial fuel cell. Accordingly, CW-MFC modules with vegetation had higher treatment efficiency compared to unplanted wetland module, and average COD, NH4+, and TP removal efficiency in vegetated wetland modules were ranged from 85 to 88%, 95 to 97%, and 95 to 97%, respectively. However, the highest NO3- removal (63%) was achieved by unplanted control module during the experiment period. The maximum average output voltage, power density, and Coulombic efficiency were obtained in wetland module vegetated with Typha angustifolia for 1.01 ± 0.14 V, 7.47 ± 13.7 mWatt/m2, and 8.28 ± 10.4%, respectively. The results suggest that the presence of Typha angustifolia vegetation in the CW-MFC matrix provides the benefits for treatment efficiency and bioelectric production; thus, it increases microbial activities which are responsible for biodegradation of organic compounds and catalyzed to electron flow from anode to cathode. Consequently, we suggest that engineers can use vegetated wetland matrix with Typha angustifolia in CW-MFC module in order to maximize treatment efficiency and bioelectric production.

Evaluation of an innovative approach based on prototype engineered wetland to control and manage boron (B) mine effluent pollution.

A major environmental problem associated with boron (B) mining in many parts of the world is B pollution, which can become a point source of B mine effluent pollution to aquatic habitats. In this study, a cost-effective, environment-friendly, and sustainable prototype engineered wetland was evaluated and tested to prevent B mine effluent from spilling into adjoining waterways in the largest B reserve in the world. According to the results, average B concentrations in mine effluent significantly decreased from 17.5 to 5.7 mg l(-1) after passing through the prototype with a hydraulic retention time of 14 days. The results of the present experiment, in which different doses of B had been introduced into the prototype, also demonstrated that Typha latifolia (selected as donor species in the prototype) showed a good resistance to alterations against B mine effluent loading rates. Moreover, we found that soil enzymes activities gradually decreased with increasing B dosages during the experiment. Boron mass balance model further showed that 60 % of total B was stored in the filtration media, and only 7 % of B was removed by plant uptake. Consequently, we suggested that application of the prototype in the vicinity of mining site may potentially become an innovative model and integral part of the overall landscape plan of B mine reserve areas worldwide. Graphical Abstract ᅟ.

Constructed wetlands as green tools for management of boron mine wastewater.

Constructed wetlands are of increasing interest worldwide given that they represent an eco-technological solution to many environmental problems such as wastewater treatment. Turkey possesses approximately 70% of the world's total boron (B) reserves, and B contamination occurs in both natural and cultivated sites throughout Turkey, particularly in the north-west of the country. This study analyzes B removal and plant uptake of B in pilot plots of subsurface horizontal-flow constructed wetlands. Constructed wetlands were vegetated with Typha latifolia (referred to as CW1) and Phragmites australis (referred to as CW2) to treat wastewater from a borax reserve in Turkey--the largest of its type in the world and were assessed under field conditions. The B concentrations of water inflows to the systems were determined to be 10.2, 28.2, 84.6, 232.3, 716.4, and 2019.1 mg l(-1). The T. latifolia in the CW1 treatment group absorbed a total of 1300 mg kg(-1) B, whereas P. australis absorbed 839 mg kg(-1). As a result, CW1 had an average removal efficiency of 40.7%, while that of CW2 was 27.2%. Our results suggest that constructed wetlands are an effective, economic and eco-friendly solution to treating B mine wastewater and controlling the adverse environmental effects of B mining.

Analysis of airborne pollen grains in Bilecik, Turkey.

In this study, pollen grains in the atmosphere of Bilecik were studied for a continuous period of 2 years (2005 and 2006) by using Durham sampler. During this period, pollen grains belonging to 46 taxa were recorded, 26 of which belonged to arboreal plants and 20 to non-arboreal. Of total 14,269 pollen grains determined in Bilecik atmosphere, 6,675 were recorded in 2005 and 7,594 were in 2006. From these, 75.74% were arboreal, 21.80% were non-arboreal and 2.47% unidentifiable. Pinus sp., Poaceae, Cupressaceae, Platanus sp., Quercus sp., Salix sp., Ailanthus sp., Fagus sp., Urticaceae, Chenopodiaceae/Amaranthaceae were the main pollen producers in the atmosphere of Bilecik, respectively. Pollen concentrations reached their highest levels in May. Atmospheric pollen concentrations in February, March, September, October and November were less than those in other months.