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Int J Biol Macromol ; 189: 477-482, 2021 Oct 31.
Article in English | MEDLINE | ID: mdl-34450145

ABSTRACT

We prepared the magnetic chitosan carbon quantum dot nanoparticles (Fe3O4@CQD NPs) via the hydrothermal treatment of chitosan biopolymer and then its magnetization with Fe3O4 nanoparticles. (4-Acetylphenyl)boronic acid compound was utilized for the modification of surface of Fe3O4@CQD nanoparticles via the covalent imine bond formation between NH2 groups of chitosan quantum dot with carbonyl functional of acetyl-substituted arylboronic acid. The synthesized Fe3O4@CQD@AP-B(OH)2 was characterized by FE-SEM, EDS, XRD, VSM and ICP-OES analysis and its fluorescence property was studied. This magnetic multifunctional nanoplatform sensor has shown high potential sensitivity for Cu2+ ions (in the range of 1.0-30.0 µM with limit of detection 0.3 µM) through interaction of cupric ions with the boronic-acid moiety.


Subject(s)
Boronic Acids/chemistry , Chitosan/chemistry , Copper/analysis , Magnetic Phenomena , Nanocomposites/chemistry , Quantum Dots/chemistry , Boronic Acids/chemical synthesis , Cations , Chitosan/chemical synthesis , Fluorescence , Ions , Nanocomposites/ultrastructure , Quantum Dots/ultrastructure , Spectroscopy, Fourier Transform Infrared , X-Ray Diffraction
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