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Synthetic study of pyrrocidines: first entry to the decahydrofluorene core of pyrrocidines.
Tanaka, Ryo; Ohishi, Kentaro; Takanashi, Noriyuki; Nagano, Tomohiko; Suizu, Hiroshi; Suzuki, Takahiro; Kobayashi, Susumu.
Org Lett ; 14(18): 4886-9, 2012 Sep 21.
Article in English | MEDLINE | ID: mdl-22937974

ABSTRACT

The first synthesis of decahydrofluorene core 4 of pyrrocidines was accomplished. The cis,trans-fused tricyclic ring system was stereoselectively constructed via Diels-Alder reaction using two Danishefsky dienes.


Subject(s)
Alkadienes/chemistry , Bridged-Ring Compounds/chemical synthesis , Fluorenes/chemistry , Pyrrolidinones/chemical synthesis , Bridged-Ring Compounds/chemistry , Cycloaddition Reaction , Molecular Structure , Pyrrolidinones/chemistry , Stereoisomerism
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