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1.
Mar Pollut Bull ; 195: 115461, 2023 Oct.
Article in English | MEDLINE | ID: mdl-37659384

ABSTRACT

Microplastics (MPs) have become prevalent in various environmental compartments, including air, water, and soil, attracting attention as significant pollutant parameters. This study investigated the prevalence of MP pollution in surface sediments along Istanbul's Marmara Sea, encompassing the megacity and the Bosphorus. A comprehensive sampling approach was employed, covering 43 stations across four seasons and depths ranging from 5 to 70 m. The objective was to assess the impact of terrestrial, social, and industrial activities on MPs. The average concentrations varied per season, with fall, winter, spring, and summer values recorded as 2000 ± 4100, 1600 ± 3900, 4300 ± 12,000, and 9500 ± 20,300 particles/kg-DW. The study identified river stations in the Golden Horn and sea discharge locations as hotspots for high concentrations. Notably, the dominant shape shifted from fibers in fall, winter, and spring to fragments during summer, coinciding with mucilage occurrences. The study identified 11 different polymers, with polyethylene (44 %) and polypropylene (31 %) being the most common.

2.
Environ Sci Pollut Res Int ; 30(11): 29663-29680, 2023 Mar.
Article in English | MEDLINE | ID: mdl-36417059

ABSTRACT

An underground municipal solid waste (MSW) container should be washed periodically to prevent/reduce odor and leachate production. In this study, the treatment process of wastewater derived from the washing process of an MSW container was investigated using the electrochemical (EC) treatment process with different anode materials (Fe, TiO2, and graphite). Response surface methodology (RSM) was used to evaluate the effect of process parameters such as initial pH, applied current, and reaction time on chemical oxygen demand (COD), Tannin/Lignin, and color removals. According to the results obtained from the RSM models, all process parameters were significant. The optimum process parameters in terms of COD removal were derived from the models for each anode material. Under the optimized conditions, the COD removals were determined to be 93.25%, 75.95%, and 98.46% for Fe-Fe, TiO2-Fe, and graphite-Fe electrode pairs, respectively. The color and Tannin/Lignin removals were determined as 98.12% and 77.78% for the Fe-Fe, 92.76% and 98.45% for the TiO2-Fe and 94.50% and 79.56% for the graphite-Fe electrode pair, respectively. The specific energy consumption (SEC) values were found as 46.95, 300.02, and 32.95 kWh/m3 for each electrode combination given above, respectively. In terms of both removal efficiencies and SEC, the most effective anode material was determined as graphite, followed by iron.


Subject(s)
Graphite , Water Pollutants, Chemical , Wastewater , Waste Disposal, Fluid/methods , Solid Waste , Lignin , Electrodes , Biological Oxygen Demand Analysis , Industrial Waste/analysis
3.
J Water Process Eng ; 38: 101631, 2020 Dec.
Article in English | MEDLINE | ID: mdl-38620672

ABSTRACT

In this study, conventional membrane bioreactor (MBR) and moving bed-membrane bioreactor (MB-MBR) processes were compared in synthetic textile wastewater treatment. For this purpose, the bioreactors were operated as a conventional MBR, an MB-MBR with a biocarrier filling ratio of 20 % and an MB-MBR with a biocarrier filling ratio of 10 %, respectively. In the conventional MBR operation, 93.1 % chemical oxygen demand (COD) and 87.1 % color (Reactive Red 390) removal efficiencies were obtained. In both MB-MBR operations, almost equal COD and color removal efficiencies were found as 98.5 % and 89.5 %, respectively. Moreover, offline physical and chemical membrane cleaning processes were applied every other day and every 15 days throughout the conventional MBR operation, respectively, while no physical or chemical membrane cleaning was required during both MB-MBR operations. Furthermore, lower polysaccharide concentrations of extracellular polymeric substances (EPS) and floc sizes of sludge and higher zeta potential of sludge were determined in MB-MBR. Considering the obtained results, it may be stated that the MB-MBR process is an attractive treatment technology for reducing membrane fouling propensity for treatment of textile wastewater.

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