Actively tunable plasmon-induced transparency in terahertz based on Dirac semimetal metamaterials.

We numerically investigate a tunable plasmon-induced transparency based on bulk Dirac semimetal (BDS) metamaterial in the terahertz band. In the unit cell, the prominent transparent peak appears to be due to the interference between the cut wires (CWs) and split-ring resonators (SRRs). An active modulation via near-field coupling is obtained by varying the Fermi level of the BDS. Introducing photoactive silicon, it will be found that once the intensity of the pump light is adjusted, a tunable transparent peak will appear. Furthermore, by shifting the coupling distance between CWs and SRRs, the depth of the transparent peak will change accordingly. Finally, we place the structure in environments with different refractive indices, which will exhibit excellent sensitivity and facilitate the application of biochemical sensors. This simple and easy-to-fabricate metamaterial structure will have excellent potential applications in modulation, filters, and detection.

Metal and ligand effects on the stability and electronic properties of crystalline two-dimensional metal-benzenehexathiolate coordination compounds.

The cohesive energy, phonon spectrum and quantum molecular-dynamic simulation have been used successively to determine whether the crystalline two-dimensional (2D) metal-benzenehexathiolate (M-BHT) coordination compounds are stable or not. The electronic structures of stable M-BHTs and the corresponding inorganic semiconducting materials have been compared. From the point of view of satisfying stoichiometric ratios and saturation of chemical bonds, we designed possible planar molecular structures and demonstrated that there may be two different 2D M-BHTs, i.e. group II-[Formula: see text] and group IV-[Formula: see text]. However, the cohesive energy calculation indicates that the group IV-[Formula: see text] coordination compound cannot be obtained by thermodynamic equilibrium growth. In contrast, [Formula: see text] and [Formula: see text] from the group II-[Formula: see text] have not only thermodynamic stability, but also dynamic stability due to their phonon spectrum with no imaginary frequency. Moreover, they are still the two most stable ones when the bridge atom S of ligand BHT is replaced by the other chalcogens of O, Se and Te. Further studies indicated that [Formula: see text] and [Formula: see text] both have room temperature dynamic stability and exhibit semiconducting. The exceptional stability and relatively narrow band gap make them advantageous over their inorganic counterparts. Our findings open opportunities to search for new 2D planar conducting coordination compound for organic electronic applications.

Flexible n-Type High-Performance Thermoelectric Thin Films of Poly(nickel-ethylenetetrathiolate) Prepared by an Electrochemical Method.

Flexible thin films of poly(nickel-ethylenetetrathiolate) prepared by an electrochemical method display promising n-type thermoelectric properties with the highest ZT value up to 0.3 at room temperature. Coexistence of high electrical conductivity and high Seebeck coefficient in this coordination polymer is attributed to its degenerate narrow-bandgap semiconductor behavior.