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Intramolecular [2+2] cycloaddition of homoallylketenes to bicyclo[2.1.1]hexan-5-ones.
Hoshikawa, Takaya; Tanji, Kei; Matsuo, Jun-ichi; Ishibashi, Hiroyuki.
Chem Pharm Bull (Tokyo) ; 60(4): 548-53, 2012.
Article in English | MEDLINE | ID: mdl-22466740

ABSTRACT

Intramolecular [2+2] cycloaddition of γ,δ-unsaturated ketenes derived from hex-5-enoyl chloride derivatives gave bicyclo[2.1.1]hexan-5-ones with complete regioselectivity.


Subject(s)
Bridged Bicyclo Compounds/chemistry , Ethylenes/chemistry , Ketones/chemistry , Methyl n-Butyl Ketone/chemistry , Cyclization , Ethylenes/chemical synthesis , Ketones/chemical synthesis , Stereoisomerism
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