Simplified LIBS-based intensity-ratio approach for concentration estimation (SLICE): an approach for elemental analysis using laser induced breakdown spectroscopy.

We propose what we believe to be a new approach for elemental analysis using laser induced breakdown spectroscopy (LIBS). This method offers enhanced convenience and simplicity for elemental analysis as it eliminates the necessity of Boltzmann/ Saha-Boltzmann plot. It is an intensity-ratio based approach that provides several notable advantages. One of the key benefits is its ability to perform comprehensive elemental analysis using only a few spectral lines; specifically, only n + 1 emission lines are sufficient for a sample containing n elemental species. This offers a great flexibility in the choice of emission lines which do not suffer from self-absorption. Further, high accuracy can be obtained as many repeated estimations from a single measurement are possible. We demonstrate the theory and working procedure of this technique by experimentally recording the data of two samples (binary and ternary copper alloys). A nanosecond Nd:YAG pulsed laser of ∼7 ns pulse duration and 532 nm incident wavelength is used. The results are in good agreement with CF-LIBS and Energy-dispersive X-ray spectroscopy (EDS).

Compositional analysis of copper and iron-based alloys using LIBS coupled with chemometric method.

The present manuscript deals with the utility of the calibration-free LIBS and calibration curve methods for the compositional study of different alloys using laser-induced breakdown spectroscopy (LIBS). In the process of alloying in the smelting industry, metal concentration in different alloys affects the physical and chemical properties of the final products. Therefore, LIBS can be used as an efficient quantitative analysis tool for online monitoring of the quality of the products. This is because LIBS can be performed online, in situ, without any pre-processing, and need no sample preparation for the compositional analysis of any type of materials present in any phase (solid, liquid, gas or even molten alloys in the industries). In the present study, four alloys (three copper and one iron-based alloy) consisting of Cu, Al, Zn, Ni, Fe, Cr and Mn as major and Sn and Si as minor elements were selected for the study using calibration-free laser-induced breakdown spectroscopy (CF-LIBS) and calibration curve method i.e. partial least square regression (PLSR). For the CF-LIBS method, the temporal delay has been optimized in order to satisfy the optically thin and local thermal equilibrium (LTE) condition of the plasma. For the PLSR method, different regions of the strongest emission lines of constituents have been selected for quantitative analysis. The study of time-resolved LIBS spectra and the variation of plasma parameters with respect to the delay time is also discussed. The utility of the combined technique of CF-LIBS with the PLSR method for rapid monitoring and quality assessment of desired material/products without any sample pretreatment, thus reducing the cost of the analysis, is presented in this paper.

Effect of mineral elements on the formation of gallbladder stones using spectroscopic techniques.

Long-standing gallbladder stones have been recognized as one of the highest risk factors for gallbladder cancer. However, the growth and progression of gallbladder stones are still not well-known, and their uncovering requires accurate information on the formation/nucleation and complex compositional information of gallstones. Multiple and single gallstones are analyzed using laser-induced breakdown spectroscopy (LIBS), photoacoustic spectroscopy (PAS), and Fourier transform infrared spectroscopy (FTIR). Spectral signatures as well as spatial variation in the spectral intensities of different elements are observed in the LIBS spectra of the gallstones. In the multiple-type gallstones, the concentration of inorganic content increases from core to periphery, whereas a single gallstone shows the opposite trend from the point of nucleation/core. It is suggested that the concentration of inorganic elements (Mg, Ca, K, and Na) plays an important role in the nucleation and growth of gallstones; thus, accordingly, multiple- and single-type gallstones are found in the gallbladder. The presence of different electronic bands of molecules, such as CH, C2, CN, and NH, is confirmed by LIBS and FTIR. PAS has identified molecules, such as cholesterol, calcium carbonate, and calcium phosphate, in different gallstone samples. These results show that PAS combined with LIBS is a promising candidate for the compositional analysis of gallstones. Furthermore, principal component analysis (PCA) is used to discriminate different layers present in the gallstones.

Time-Dependent Intensity Ratio-Based Approach for Estimating the Temperature of Laser Produced Plasma.

Reported here is a rapid and simplified approach for modeling the temporal evolution of the plasma temperature. The use of only two emission lines makes this technique simple, accurate, and fast. Usually, multiple emission lines are required for estimating plasma temperature using Boltzmann/Saha-Boltzmann plots. But, in several cases, either multiple emission lines are not available for every element and/or sufficient lines are not free from self-absorption effect. The proposed method greatly increases the possibility of plasma temperature estimation as it requires only two lines. A brass target was used to generate the plasma, using a conventional single-pulse nanosecond laser of ∼7 ns pulse duration at an excitation wavelength of 532 nm. The initial temperature of plasma and the radiation decay constant were estimated using a proposed intensity ratio model. The results were estimated using various combinations of emission lines, which show an excellent agreement with the values obtained using the previously reported method.