Crystalline germanium high-Q microresonators for mid-IR.

High-quality-factor optical microresonators have become an appealing object for numerous applications. However, the mid-infrared band experiences a lack of applicable materials for nonlinear photonics. Crystalline germanium demonstrates attractive material properties such as high nonlinear refractive index, large transparency window including the mid-IR band, particularly long wave multiphonon absorption limit. Nevertheless, the reported optical losses in germanium microresonators might not allow the potential of the Ge-based devices to be revealed. In this study, we report the fabrication of germanium microresonators with radii of 1.35 and 1.5 mm, exhibiting exceptional quality factors (Q-factors) exceeding 20 million, approaching the absorption-limited values at a wavelength of 2.68 µm. These Q-factors are a hundred times higher than previously reported, to the best of our knowledge. We measured the two-photon absorption coefficient combined with free-carrier absorption leveraging the high-Q of the resonators (obtained ßTPA = (0.71 ± 0.12) · 10-8 m/W at 2.68 µm). This research underscores the potential of whispering gallery mode microresonators as valuable tools for measuring absorption coefficients at different wavelengths, providing a comprehensive analysis of various loss mechanisms. Furthermore, the exceptional Q-factors observed in germanium microresonators open intriguing opportunities for the advancement of germanium-based photonics within the mid-infrared spectral band.

Ultrahigh-Q WGM microspheres from ZBLAN for the mid-IR band.

The advantages of high-quality-factor (high-Q) whispering gallery mode (WGM) microresonators can be applied to develop novel photonic devices for the mid-infrared (mid-IR) range. ZBLAN (glass based on heavy metal fluorides) is one of the most promising materials to be used for this purpose due to low optical losses in the mid-IR. We developed an original, to the best of our knowledge, fabrication method based on melting of commercially available ZBLAN-based optical fiber to produce high-Q ZBLAN microspheres with the diameters of 250 to 350 µm. We effectively excited whispering gallery modes in these microspheres and demonstrated high quality factor both at 1.55 µm and 2.64 µm. Intrinsic quality factor at telecom wavelength was shown to be (5.4 ± 0.4) × 108 which is defined by the material losses in ZBLAN. In the mid-IR at 2.64 µm we demonstrated record quality factor in ZBLAN exceeding 108 which is comparable to the highest values of the Q-factor among all materials in the mid-IR.