1.
J Phys Condens Matter
; 34(43)2022 Sep 02.
Article
in English
| MEDLINE
| ID: mdl-35977536
ABSTRACT
Intercalation has become a powerful approach to tune the intrinsic properties and introduce novel phenomena in layered materials. Intercalating van der Waals (vdW) magnetic materials is a promising route to engineer the low-dimensional magnetism. Recently, metal thiophosphates,MPX3, has been widely studied because their magnetic orders are highly tunable and persist down to the two-dimensional limit. In this work, we used electrochemical technique to intercalate Li into NiPS3single crystals and found the emergence of ferrimagnetism at low temperature in Li-intercalated NiPS3. Such tuning of magnetic properties highlights the effectiveness of intercalation, providing a novel strategy to manipulate the magnetism in vdW magnets.