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Chem Commun (Camb) ; 52(2): 264-7, 2016 Jan 07.
Article in English | MEDLINE | ID: mdl-26466863

ABSTRACT

A new family of quaternary semiconductors Cu2ZnAS4-x and CuZn2AS4 (A = Al, Ga, In) has been synthesized in the form of wurtzite phase nanocrystals for the first time. The nanocrystals can be converted to the stannite phase via thermal annealing under a N2 atmosphere. A direct band gap in the visible wavelength region combined with a high absorption cross-section makes these materials promising for solar energy conversion applications.

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