A methodology to screen priority toxins in pollutant release inventories.

Pollutant release inventories are used for environmental policy making to reduce toxic pollutants, even though the quantity-based inventory analysis does not take into account the relative toxicity of pollutants. To overcome this limit, life cycle impact assessment (LCIA)-based inventory analysis was developed but still has a high uncertainty from modelling the site- and time-specific fates and transports of pollutants. Thus, this study develops a methodology to evaluate toxicity potentials based on the concentration of pollutants in the exposure to humans in order to circumvent the uncertainty and subsequently screen priority toxins in pollutant release inventories. This methodology combines (i) analytical measurement of the concentration of the pollutants exposed to humans; (ii) application of toxicity effect characterization factors for pollutants; and (iii) identification of priority toxins and industries based on the toxicity potential evaluation results. To demonstrate the methodology, a case study is considered, evaluating toxicity potentials from the ingestion of heavy metals in seafood organisms and then identifying priority toxins and industry sectors in a pollutant release inventory. The results of the case study show that the methodology-based priority pollutant is different from the quantity- and LCIA-based ones. Therefore, the methodology can contribute to making effective environmental policy.

Simultaneous recovery of phosphorus and nitrogen from sewage sludge ash and food wastewater as struvite by Mg-biochar.

The drawback of biochar as a soil ameliorant is its low-nutrient content while the bottleneck of struvite production is its high chemical cost. This drew the idea of using designed biochar for nutrient recovery from nutrient-rich wastewater as struvite. Mg-biochar was used for simultaneous P and N recovery from sewage sludge ash (SSA) and food wastewater (FW) by using ground coffee bean (GCB) and palm tree trunk (PTT) waste. PTT Mg-biochar could recover 92.2% of PO43--P and 54.8% of NH4+-N while GCB Mg-biochar could recover 79.5% of PO43--P and 38.6% of NH4+-N. Adsorption, precipitation and cation-exchange mechanisms are involved in the Mg-biochar for the simultaneous recovery of PO43--P and NH4+-N as struvite. Mg-biochars also showed higher struvite selectivity than the control samples. This method not only supports waste recycling and pollution mitigation but also highlights economical struvite production and the benefits of CO2 sequestration.