The influence of citrate and oxalate on 99TcVII, Cs, NpV and UVI sorption to a Savannah River Site soil.

Batch sorption experiments were conducted with 0.5-50 ppb 99Tc, 133Cs, 237Np and U in the presence and absence of citrate and/or oxalate in a 25 g/L Savannah River Site (SRS) soil suspension. Citrate and oxalate were the ligands of choice due to their relevancy to plant exudates, the nuclides were selected for their wide range of biogeochemical behavior, and the soil from SRS was selected as a model Department of Energy (DOE) site soil. Batch samples were continually mixed on a rotary shaker and maintained at a pH of approximately 5. Analysis via ICP-MS indicated that sorption of 237Np increased with ligand concentration compared to baseline studies, as did sorption of 99Tc although to a lesser extent. The increased sorption of 237Np is proposed to be due to a combination of factors that are dependent on the ligand(s) present in the specific system including, ligand dissolution of the soil by citrate and formation of tertiary soil-oxalate-Np complexes. The increased 99Tc sorption is attributed to the dissolution of the soil by the ligands, leading to an increase in the number of available sorption sites for 99Tc. Uranium sorption decreased and dissolution of native uranium was also observed with increasing ligand concentration, thought to be a result of the formation of strong U-ligand complexes remaining in the aqueous phase. The majority of these effects were observed at the highest ligand concentrations of 50 mgC/L. No notable changes were observed for the 133Cs system which is ascribed to the minimal interaction of Cs+ with these organic ligands.

Spot fumigation: fumigant gas dispersion and emission characteristics.

Reducing emissions of volatile organic compounds (VOCs) from fumigant pesticides is mandatory in California, especially in "nonattainment areas" like the San Joaquin Valley that do not meet federal air quality standards. A two-year field study was conducted to examine the feasibility of site-specific fumigant application only at future tree sites with dramatically reduced amounts of fumigant chemicals on an orchard basis. Soil gas distribution and atmospheric emission of 1,3-dichloropropene and chloropicrin were measured after applying InLine using subsurface drip irrigation. It was predicted that except in the surface 20 cm of soil, satisfactory pest control could be achieved within a 15 cm radius from the injection point. Also, at radial distances of 15-51 cm from the point of fumigant injection, effective nematode control may be achieved. Cumulative atmospheric emission of the fumigants was estimated to be 18-23% of the applied active ingredients in plots that had been cover cropped with Sudan grass and 2-6% in plots that had remained bare for several months before treatment. Considering the significantly small amount of fumigant used on an orchard basis, the spot drip fumigation may achieve a 10-fold reduction in atmospheric VOCs load from fumigant pesticides.