Janus membrane with asymmetric wettability for efficient oil/water separation.

The rapid development of society and industry as well as the frequent occurrence of oil spills cause the shortage of fresh water resources, which not only affects human safety and life, but also impedes the world-wide sustainable development. To address these challenges, novel membrane materials with unique wettability properties have gained significant attention, particularly in the field of oil/water separation. In this research, we modified the hydrophobic PET fabric to achieve superhydrophilic characteristics using impregnation method. Subsequently, we electrospun hydrophobic PVDF fibers onto the superhydrophilic fabric surface, and PVDF/Ca10(PO4)6(OH)2@PET Janus membrane with asymmetric wettability was obtained. The membrane has an excellent unidirectional liquid transport capacity, and can effectively separate heavy oil or light oil, the separation efficiency is more than 90 %. The results also show that the Janus membrane can be used under alkaline conditions and has satisfactory tensile resistance and re-use performance. This work provides a new idea for Janus membrane design and effectively improves the application potential of the Janus membrane in the field of oil/water separation.

A Janus membrane doped with carbon nanotubes for wet-thermal management.

In a human skin-fibrous fabric-external environment, fibrous materials, as the "second skin" of the human body, provide comfort against the wet and heat effectively. Fibrous materials protect human health and guarantee work efficiency in various outdoor or inner scenes. Personal wet-thermal management based on fibrous materials can regulate comfort in a facile manner with low or zero energy consumption, which has become a potential development area. However, realizing synergistic management of the wet and heat effectively and conveniently is a challenge in the development and production of fibrous materials. We designed and fabricated a Janus fibrous membrane composed of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA)-modified hydrophobic cotton gauze and electrospun carbon nanotubes (CNTs)-doped cellulose acetate (CA) hydrophilic fibrous membrane. Taking advantage of asymmetric wettability along its thickness direction, the Janus fibrous membrane, acting as a "liquid diode", could transport sweat/moisture from human skin to the external environment unidirectionally, which endowed a dry surface on human skin, avoiding "stickiness", and realizing wet management. Doped CNTs had good photothermal-conversion capacity, so the Janus membrane exhibited excellent heating capacity for passive radiation, so excellent synergistic wet-thermal management was obtained. The Janus membrane could be a candidate for diverse applications of fibrous membranes. Our data provide new ideas for the design and fabrication of fibrous membranes with remarkable wet-thermal management.

Two-dimensional gas chromatography coupled to isotope ratio mass spectrometry for determining high molecular weight polycyclic aromatic hydrocarbons in sediments.

The accuracy of compound-specific isotope analysis (CSIA) of trace-level pollutants in complex environmental samples has always been limited by two main challenges: poor chromatographic separation and insufficient amounts of analytes. In this study, a two-dimensional gas chromatography-isotope ratio mass spectrometry (2DGC-IRMS) system was constructed for compound-specific δ13C analysis of high molecular weight polycyclic aromatic hydrocarbons (HMW-PAHs) in estuarine/marine sediments. This construction occurred through hyphenating an extra gas chromatography system (GC) to a conventional GC-IRMS using a commercially available multi-column switching-cryogenic trapping system (MCS-CTS). Compared with the previous 2DGC-IRMS strategy, which utilizes a Deans Switch device, the newly implemented 2DGC-IRMS scheme resulted in online purification of target analytes as well as enriched them online via duplicate injection and cryogenic trapping in CTS; this resultingly lowered the limits of detection (LOD) of CSIA. To improve the sample transfer efficiency to the IRMS, a broader-bore and longer fused-silica capillary was utilized to replace the original sample capillary running from the sample open split to the IRMS. A ẟ13C analysis of PAH standards showed accurate ẟ13C values, and high precisions (standard deviations 0.13-0.37%) were achieved, with the LOD of HMW-PAHs reduced to at least 1.0 mg/L (i.e., 0.07 to 0.09 nmol carbon per compound on-column). The successful application of this newly developed 2DGC-IRMS scheme provides a practical solution for the reliable CSIA of trace-level pollutants in complex environmental samples that cannot be measured using the conventional GC-IRMS system.

Phase evolution of the surface iron (hydr)oxides to the iron sulfide through anion exchange during sulfidation of zero valent iron.

The naturally-formed iron (hydr)oxides on the surface of zero valent iron (ZVI) have long been considered as passivation layer and inert phases which significantly reduce the reaction activities when they are employed in environmental remediation. Although it seems there are no direct benefits to keep these passivation layers, here, we show that such phases are necessary intermediates for the transformation to iron sulfides through an anion exchange pathway during sulfidation of ZVI. The pre-formed (hydr)oxides undergo a phase evolution upon aging and specific phases can be effectively trapped, which can be confirmed by a combination of different characterization techniques including scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRPD), and X-ray absorption near edge structure (XANES) spectroscopy. Interestingly, after sulfidation, the resultant samples originated from different (hydr)oxides demonstrate different activities in the Cr(VI) sequestration. The XANES investigation of Fe K edge and Fe L2,3 edge indicates Fe remains the same after sulfidation, suggesting a non-redox, anion exchange reaction pathway for the production of iron sulfides, where O2- anions are directly replaced with S2-. Consequently, the structural characteristics of the parent (hydr)oxides are inherited by the as-formed iron sulfides, which make them behave differently because of their different structural natures.

Occurrence, spatial distribution, and fate of polycyclic musks in sediments from the catchment of Chaohu Lake, China.

Twenty-nine surface sediments from Chaohu Lake in China and from its six main tributaries were sampled to investigate the concentrations of two important polycyclic musks (PCMs), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta(g)-2-benzopyran (galaxolide, HHCB) and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene (tonalide, AHTN), as well as the concentration of 4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta(g)-2-benzopyran-1-one (galaxolidon, HHCB-lactone), which is the main degradation product of HHCB. Except for the high concentrations of AHTN and HHCB measured in the Nanfei River (879 ng/g dw and 5,513 ng/g dw, respectively), the levels of AHTN and HHCB in the river sediments were 7.08-44.9 ng/g dw and 20.6-268 ng/g dw, respectively, which are slightly lower than those documented in various areas worldwide. The concentrations of AHTN and HHCB in the sediments of Chaohu Lake were one or two orders of magnitude lower than those in the tributary rivers and showed a clear regional distribution. The concentrations of HHCB-lactone were comparable to those of HHCB and presented a significant positive correlation with the concentrations of HHCB, suggesting that the HHCB-lactone originated directly from the degradation of HHCB in wastewater treatment plants (WWTPs) or in the natural environment. The diagnostic ratios of HHCB/AHTN and HHCB-lactone/HHCB and the enantiomeric fractions (EFs) of these PCMs showed that the direct origins of the target PCMs in the study area were municipal and industrial wastewaters discharged from adjacent cities or point sources and that the HHCB-lactone in sediment originated from the natural degradation of HHCB in the rivers and the lake. The results of the risk assessment showed that the PCMs in the watershed sediments were unlikely to pose a threat to aquatic species. However, the effluents of industrial and municipal wastewaters that are discharged into the Nanfei River should be investigated in future research.

Surface Modulation and Chromium Complexation: All-in-One Solution for the Cr(VI) Sequestration with Bifunctional Molecules.

The sulfidation of zero valent iron (ZVI) to an Fe@FeSx (S-ZVI) composite has been intensively explored in the ZVI field. Yet, further benefits from the FeSx coating layer are seldom realized, especially those effectively using its intrinsic physical and chemical properties for elaborate design. Here, we demonstrate that in a traditional Cr(VI) sequestration reaction, the FeSx layer displays a great utility in immobilizing molecules containing hydroxyl groups (-OH) and hence, attracting Cr(VI) complexes chelated with carboxyl organics (RCOOH). Such intermolecular attraction readily promotes the diffusion of the Cr(VI) complexes to the S-ZVI surface, affording a higher reaction rate for the Cr(VI) sequestration process. In addition, the above mechanism was used to guide a rational selection of molecules incorporating both hydroxyl and carboxyl functional groups with a proper ratio and thereby, a significantly improved reaction efficiency was achieved. Furthermore, the FeSx phase was revealed to be consumed in the reaction, acting as a supplementary reductant. This work is the first to unveil the relationship between molecules with specific functionalization and the FeSx phase, providing a general rule in choosing appropriate reaction media for Cr(VI) sequestration and related reactions.

Omnidirectional polarization beam splitter for white light.

As a key element in optical systems, a broadband and omnidirectional polarization beam splitter has been long desired. Here, based on anisotropic metamaterials, a perfect polarizing beam splitter is theoretically designed for the extremely broad frequency and angle bands without energy loss. When an electromagnetic wave is incident on the beam splitter, the transverse magnetic-polarized component suffers total reflection, while the transverse electric-polarized component is completely transmitted within the incident angle range [-90°, 90°] for the white light. This study provides a new approach to design an efficient polarizing beam splitter and may promote the development and applications of anisotropic metamaterials.

Enantiomeric analysis of polycyclic musks AHTN and HHCB and HHCB-lactone in sewage sludge by gas chromatography/tandem mass spectrometry.

RATIONALE: Enantioselective analysis of chiral compounds is an interesting and challenging technique used to elucidate the degradation/transformation mechanisms of these compounds or understand their environmental processes. In this study, we have developed an effective separation and detection approach for the enantiomeric analysis of AHTN and HHCB, as well as a transformation product of HHCB (HHCB-lactone), in sludge samples. METHODS: The analytical method was developed using a cyclodextrin-based enantioselective gas chromatography column combined with tandem mass spectrometry (GC/MS/MS). The GC oven temperature gradients, the linear velocity of the helium carrier gas, as well as the MS/MS parameters, including quantitative and qualitative ion pairs, dwell times, and collision energies, were optimized to achieve good separation and high sensitivity for all target enantiomers. RESULTS: Baseline separations of all target enantiomers were observed. Limits of quantification (LOQs) for all enantiomers ranged from 0.010 to 0.045 µg/L, and calibration linearity for all single enantiomers was higher than 0.99. The intra-day and inter-day precisions for all single enantiomers of AHTN, HHCB, and HHCB-lactone ranged from 0.8 to 3.8% and from 4.2 to 8.3%, respectively. CONCLUSIONS: The developed method was fully validated through enantioselective analyses of AHTN, HHCB, and HHCB-lactone in sludge samples collected from 17 WWTPs. The enantiomeric fractions (EFs) of HHCB and HHCB-lactone in sludge samples distinctly deviated from 0.50, indicating a significant enantioselective transformation of HHCB with preferential degradation of the 4S enantiomers. Significant positive correlations were found between the EF values of cis-HHCB enantiomers and cis-HHCB-lactone enantiomers in the sludge samples, implying that further efforts are still needed to clarify the degradation/transformation mechanism from HHCB to HHCB-lactone.