1.
Do ion tethered functional groups affect IL solvent properties? The case of sulfoxides and sulfones.
Chem Commun (Camb)
; (6): 646-8, 2006 Feb 14.
Article
in English
| MEDLINE
| ID: mdl-16446838
ABSTRACT
The covalent incorporation of functional groups-specifically sulfoxide and sulfone-into the cation of imidazolium ionic liquids leads to significant, quantifiable changes in solvent parameters which in turn have important effects on the bulk properties of the materials.
Subject(s)
Ionic Liquids/chemistry , Ions/chemistry , Safrole/analogs & derivatives , Sulfones/chemistry , Imidazoles/chemistry , Molecular Structure , Safrole/chemistry , Spectrophotometry, Infrared
2.
Chem Commun (Camb)
; (29): 3679-81, 2005 Aug 07.
Article
in English
| MEDLINE
| ID: mdl-16027909
ABSTRACT
Readily prepared imidazole-based boronium ions form stable, hydrophobic, room-temperature ionic liquids (RTIL) with unique electronic and spectroscopic characteristics.
3.
Chem Commun (Camb)
; (6): 630-1, 2004 Mar 21.
Article
in English
| MEDLINE
| ID: mdl-15010753
ABSTRACT
The anions of the sweeteners saccharin and acesulfame form ionic liquids when paired with a variety of organic cations.