ABSTRACT
Structural coloration has attracted great interest from scientists and engineers in recent years, owing to fascination with various brilliant examples displayed in nature as well as to promising applications of bio-inspired functional photonic structures and materials. Much research has been done to reveal and emulate the physical mechanisms that underlie the structural colors found in nature. In this article, we review the fundamental physics of many natural structural colors displayed by living organisms as well as their bio-inspired artificial counterparts, with emphasis on their connections, tunability strategies, and proposed applications, which aim to maximize the technological benefits one could derive from these photonic nanostructures. WIREs Nanomed Nanobiotechnol 2016, 8:758-775. doi: 10.1002/wnan.1396 For further resources related to this article, please visit the WIREs website.
Subject(s)
Nanoparticles , Optics and Photonics , Pigmentation , Pigments, Biological , Animals , Biomimetic Materials , Biotechnology , Birds , Coloring Agents , Fishes , Insecta , Nanoparticles/chemistry , Nanoparticles/ultrastructure , Nanotechnology , Pigments, Biological/chemistry , Pigments, Biological/physiology , ReptilesABSTRACT
Shape memory polymers (SMPs) have been shown to accurately replicate photonic structures that produce tunable optical responses, but in practice, these responses are limited by the irreversibility of conventional shape memory processes. Here, we report the intensity modulation of a diffraction grating utilizing two-way reversible shape changes. Reversible shifting of the grating height was accomplished through partial melting and recrystallization of semicrystalline poly(octylene adipate). The concurrent variations of the grating shape and diffraction intensity were monitored via atomic force microscopy and first order diffraction measurements, respectively. A maximum reversibility of the diffraction intensity of 36% was repeatable over multiple cycles. To that end, the reversible shape memory process is shown to broaden the functionality of SMP-based optical devices.