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1.
Nanotechnology ; 24(34): 345402, 2013 Aug 30.
Article in English | MEDLINE | ID: mdl-23912379

ABSTRACT

A colloidal deposition technique is presented to construct long-range ordered hybrid arrays of self-assembled quantum dots and metal nanoparticles. Quantum dots are promising for novel opto-electronic devices but, in most cases, their optical transitions of interest lack sufficient light absorption to provide a significant impact in their implementation. A potential solution is to couple the dots with localized plasmons in metal nanoparticles. The extreme confinement of light in the near-field produced by the nanoparticles can potentially boost the absorption in the quantum dots by up to two orders of magnitude.In this work, light extinction measurements are employed to probe the plasmon resonance of spherical gold nanoparticles in lead sulfide colloidal quantum dots and amorphous silicon thin-films. Mie theory computations are used to analyze the experimental results and determine the absorption enhancement that can be generated by the highly intense near-field produced in the vicinity of the gold nanoparticles at their surface plasmon resonance.The results presented here are of interest for the development of plasmon-enhanced colloidal nanostructured photovoltaic materials, such as colloidal quantum dot intermediate-band solar cells.

2.
Opt Express ; 21 Suppl 2: A295-304, 2013 Mar 11.
Article in English | MEDLINE | ID: mdl-23482292

ABSTRACT

Light trapping is becoming of increasing importance in crystalline silicon solar cells as thinner wafers are used to reduce costs. In this work, we report on light trapping by rear-side diffraction gratings produced by nano-imprint lithography using interference lithography as the mastering technology. Gratings fabricated on crystalline silicon wafers are shown to provide significant absorption enhancements. Through a combination of optical measurement and simulation, it is shown that the crossed grating provides better absorption enhancement than the linear grating, and that the parasitic reflector absorption is reduced by planarizing the rear reflector, leading to an increase in the useful absorption in the silicon. Finally, electro-optical simulations are performed of solar cells employing the fabricated grating structures to estimate efficiency enhancement potential.

3.
Opt Express ; 19(17): 16207-22, 2011 Aug 15.
Article in English | MEDLINE | ID: mdl-21934983

ABSTRACT

This paper presents a numerical study of the light focusing properties of dielectric spheroids with sizes comparable to the illuminating wavelength. An analytical separation-of-variables method is used to determine the electric field distribution inside and in the near-field outside the particles. An optimization algorithm was implemented in the method to determine the particles' physical parameters that maximize the forward scattered light in the near-field region. It is found that such scatterers can exhibit pronounced electric intensity enhancement (above 100 times the incident intensity) in their close vicinity, or along wide focal regions extending to 10 times the wavelength. The results reveal the potential of wavelength-sized spheroids to manipulate light beyond the limitations of macroscopic geometrical optics. This can be of interest for several applications, such as light management in photovoltaics.

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