1.
J Org Chem
; 85(19): 12715-12723, 2020 Oct 02.
Article
in English
| MEDLINE
| ID: mdl-32900192
ABSTRACT
The hydroalkylation and hydroacylation of electron-deficient alkenes proceeded smoothly by using benzothiazoline derivatives as radical-transfer reagents under thermal conditions without light irradiation or any additive. Both benzyl and benzoyl moieties were transferred efficiently.
2.
Chem Commun (Camb)
; 55(75): 11171-11174, 2019 Sep 17.
Article
in English
| MEDLINE
| ID: mdl-31451826
ABSTRACT
Novel radical transfer reagents under photoirradiation conditions were developed by the use of benzothiazoline derivatives. These reagents enabled both hydroalkylation and hydroacylation of alkenes under neutral conditions at ambient temperature without any toxic reagents or an excess amount of metals. A mechanistic study was carried out to elucidate the radical process.