ABSTRACT
In this descriptive cross-sectional study by census method, the performance of 116 radiographers in the target centers was evaluated in relation to the observance of radiation protection principles with respect to patients, patient companion and radiographers. The data collection tool was a checklist containing 34 principles of radiation protection that were used after confirmation of its continuity and justifiability. The results showed that only in (39.2%) 45 radiographers the observance rate of the principles of radiation protection was acceptable. The highest and lowest levels in which radiographers observed protective principles were observance of protective principles with respect to themselves (60.8%) and protective principles respect of the patient companion (6.3%), respectively. According to the findings, radiation protection principles are not systematically designed, implemented, controlled and monitored by radiographers, and less than half of the radiographers observe the protection principles at the optimal level.
Subject(s)
Radiation Protection , Humans , Cross-Sectional Studies , Iran , Surveys and QuestionnairesABSTRACT
In the environment, 4-aminophenol (4-AP) is present as a highly toxic compound and water pollutant. In this study, platinized agarose microspheres (PtAM) were used for the first time, for the preparation of a novel, modified graphite paste electrode (GPE/PtAM) for the electrochemical determination of 4-AP. PtAM was characterized using transmission electron microscopy, field emission scanning electron microscopy and energy dispersive X-ray analysis. The electrochemical response characteristics of GPE/PtAM towards 4-AP were investigated via electrochemical impedance spectroscopy, cyclic voltammetry, differential pulse voltammetry and chronoamperometry. The value of the charge transfer resistance obtained for GPE/PtAM was 27.3 Ω. Microscopic surface areas and the surface concentration of the electroactive species for GPE/PtAM were calculated to be 0.077 cm2 and 1.13 × 10-3 mol cm-2, respectively. The electron transfer coefficient, diffusion coefficient and standard heterogeneous rate constants of 4-AP were calculated as 0.274, 4.56 × 10-4 cm2 s-1, and 3.32 × 10-1 cm s-1, respectively. The influence of pH on the oxidation of 4-AP was investigated and a pH value of 2.0 (using a phosphate buffer solution) was selected as the optimum pH. Under optimum conditions, the calibration was linear between 0.8 and 87 µM with a detection limit of 45 nM. Moreover, GPE/PtAM was applied to determine the concentrations of 4-AP in water samples with satisfactory results.
ABSTRACT
Dihydroxybenzene isomers and nitrite, NO2 -, are present in the environment as highly toxic compounds and cause human cancer. In this study, for the first time poly(quercetin) (PQ) was synthesized from the reaction between quercetin (Q) and hydroquinone (HQ) as a linker. Bismuth nanowires (BNWs) were synthesized using a solvothermal technique and then the BNWs and PQ were used for preparation of a novel modified graphite paste electrode (GPE/PQ-BNWs) for simultaneous determination of dihydroxybenzene isomers; HQ, catechol (CC), resorcinol (RS) in the presence of NO2 -. The product was characterized using X-ray diffraction, field emission scanning electron microscopy and Fourier transform infrared spectroscopy. The electrochemical response characteristics of the modified GPE toward mix HQ, CC, RS and NO2 - were investigated by cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy. Under the optimum conditions, detection limits of 0.12, 0.2, 0.82 and 4.5 µM were obtained for HQ, CC, RS and NO2 -, respectively. Moreover, the GPE/PQ-BNWs were applied to determine HQ, CC, RS and NO2 - in water samples with satisfactory results.
