Carbon dioxide gasification characteristics of disposable COVID-19 masks using bubbling fluidized bed reactor.

The global demand for masks has increased significantly owing to COVID-19 and mutated viruses, resulting in a massive amount of mask waste of approximately 490,000 tons per month. Mask waste recycling is challenging because of the composition of multicomponent polymers and iron, which puts them at risk of viral infection. Conventional treatment methods also cause environmental pollution. Gasification is an effective method for processing multicomponent plastics and obtaining syngas for various applications. This study investigated the carbon dioxide gasification and tar removal characteristics of an activated carbon bed using a 1-kg/h laboratory-scale bubble fluidized bed gasifier. The syngas composition was analyzed as 10.52 vol% of hydrogen, 6.18 vol% of carbon monoxide, 12.05 vol% of methane, and 14.44 vol% of hydrocarbons (C2-C3). The results of carbon dioxide gasification with activated carbon showed a tar-reduction efficiency of 49%, carbon conversion efficiency of 45.16%, and cold gas efficiency of 88.92%. This study provides basic data on mask waste carbon dioxide gasification using greenhouse gases as useful product gases.

Hydrogen-rich gas production from disposable COVID-19 mask by steam gasification.

Globally, the demand for masks has increased due to the COVID-19 pandemic, resulting in 490,201 tons of waste masks disposed of per month. Since masks are used in places with a high risk of virus infection, waste masks retain the risk of virus contamination. In this study, a 1 kg/h lab-scale (diameter: 0.114 m, height: 1 m) bubbling fluidized bed gasifier was used for steam gasification (temperature: 800 °C, steam/carbon (S/C) ratio: 1.5) of waste masks. The use of a downstream reactor with activated carbon (AC) for tar cracking and the enhancement of hydrogen production was examined. Steam gasification with AC produces syngas with H2, CO, CH4, and CO2 content of 38.89, 6.40, 21.69, and 7.34 vol%, respectively. The lower heating value of the product gas was 29.66 MJ/Nm3 and the cold gas efficiency was 74.55 %. This study showed that steam gasification can be used for the utilization of waste masks and the production of hydrogen-rich gas for further applications.

Production of biochar from crop residues and its application for biofuel production processes - An overview.

A sustainable carbon-neutral society is imperative for future generations, and biochars and biofuels are inevitable choice to achieve this goal. Crop residues (CR) such as sugarcane bagasse, corn stover, and rice husk are promising sustainable resources as a feedstock for biochars and biofuels. Extensive research has been conducted on CR-based biochar production not only in environmental remediation areas but also in application for biofuel production. Here, the distribution and resource potential of major crop residues are presented. The production of CR-biochar and its applications in biofuel production processes, focusing on the latest research are discussed. Finally, the challenges and areas of opportunity for future research in terms of CR supply, CR-biochar production, and CR-biochar utilization for biofuel production are proposed. Compared with other literature reviews, this study can serve as a guide for the establishment of sustainable, economical, commercial CR-based biorefineries.

Recent advances of thermochemical conversion processes for biorefinery.

Lignocellulosic biomass is one of the most promising renewable resources and can replace fossil fuels via various biorefinery processes. Through this study, we addressed and analyzed recent advances in the thermochemical conversion of various lignocellulosic biomasses. We summarized the operation conditions and results related to each thermochemical conversion processes such as pyrolysis (torrefaction), hydrothermal treatment, gasification and combustion. This review indicates that using thermochemical conversion processes in biorefineries is techno-economically feasible, easy, and effective compared with biological processes. The challenges experienced in thermochemical conversion processes are also presented in this study for better understanding the future of thermochemical conversion processes for biorefinery. With the aid of artificial intelligence and machine learning, we can reduce time-consumption and experimental work for bio-oil production and syngas production processes.

Seasonal characterisation of municipal solid waste from Astana city, Kazakhstan: Composition and thermal properties of combustible fraction.

This study presents the results of a seasonal municipal solid waste composition campaign, that took place over the period of September 2017 to June 2018 in the capital city of Kazakhstan, Astana. Four sampling campaigns were conducted in order to identify the seasonal variation of municipal solid waste composition, recyclables and energy potential materials, such as combustible fraction, useful for the evaluation of waste-to-energy potential. The combustible fraction was analysed for thermal fuel properties, such as proximate and elemental analyses and gross calorific value. The results over the four different seasons showed that the average recyclable fraction of municipal solid waste on a wet basis of 33.3 wt.% and combustibles fraction was 8.3 wt.%. The largest fraction was the organics (47.2 wt.%), followed by plastic (15.4 wt.%) and paper (12.5 wt.%). Small seasonal variations were observed for organics, paper, plastic and glass fractions. The highest values were found in summer for the organic waste, in spring for paper and plastic and autumn for glass. The recyclables fraction showed an absolute seasonal variation of 5.7% with a peak in the winter season (35.4%) and the combustibles fraction showed a seasonal variation between 8.3 wt.% to 9.4 wt.%. Finally, the average calorific value of the combustible fraction was estimated to be 21.6 MJ kg-1 on a dry basis.