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1.
Environ Sci Pollut Res Int ; 31(3): 3526-3544, 2024 Jan.
Article in English | MEDLINE | ID: mdl-38085483

ABSTRACT

The main objective of this study is to analyze hazardous elements in nanoparticles (NPs) (smaller than 100 nm) and ultrafine particles (smaller than 1 µm) in Porto Alegre City, southern Brazil using a self-made passive sampler and Sentinel-3B SYN satellite images in 32 collection points. The Aerosol Optical Thickness proportion (T550) identification was conducted using images of the Sentinel-3B SYN satellite at 634 points sampled in 2019, 2020, 2021, and 2022. Focused ion beam scanning electron microscopy analyses were performed to identify chemical elements present in NPs and ultrafine particles, followed by single-stage cascade impactor to be processed by high-resolution transmission electron microscopy. This process was coupled with energy-dispersive X-ray spectroscopy and later analysis via secondary ion mass spectrometry. Data was acquired from Sentinel-3B SYN images, normalized to a standard mean of 0.83 µg/mg, at moderate spatial resolution (260 m), and modeled in the Sentinel Application Platform (SNAP) software v.8.0. Statistical matrix data was generated in the JASP software (Jeffreys's Amazing Statistics Program) v.0.14.1.0 followed by a K-means cluster analysis. The results demonstrate the presence of between 1 and 100 nm particles of the following chemical elements: Si, Al, K, Mg, P, and Ti. Many people go through these areas daily and may inhale or absorb these elements that can harm human health. In the Sentinel-3B SYN satellite images, the sum of squares in cluster 6 is 168,265 and in cluster 7 a total of 21,583. The use of images from the Sentinel-3B SYN satellite to obtain T550 levels is of great importance as it reveals that atmospheric pollution can move through air currents contaminating large areas on a global scale.


Subject(s)
Air Pollutants , Nanoparticles , Humans , Air Pollutants/analysis , Brazil , Environmental Monitoring/methods , Particulate Matter/analysis , Aerosols/analysis , Particle Size
2.
Environ Sci Pollut Res Int ; 30(17): 50675-50689, 2023 Apr.
Article in English | MEDLINE | ID: mdl-36800092

ABSTRACT

The general objective of this study is to identify the presence of hazardous elements in the soils of five urban cemeteries in the city of Passo Fundo, in southern Brazil, and to design solutions (architecturally) for future cemeteries to be more sustainable by mitigating toxicological risks to the population residing in the area. A total of 250 soil samples were obtained from points within the cemeteries and in areas surrounding the two oldest cemeteries at a distance of up to 400 m. Twelve architects who design cemeteries primarily focused on sustainability were interviewed, and presented their suggestions for sustainable urban cemetery design. The Building Information Modeling (BIM) computer modeling system was utilized to present a visual representation of suggested architectural features by these architects. The concentration of Pb in the vicinity of cemeteries deserves special attention, as concentrations of this neurotoxin exceed the federal limits set by Brazil. Soil Pb values were found to exceed the limit of 72 mg kg-1 up to a distance of 400 m from the walls of cemeteries A and B, indicating the presence of a danger to human health even at greater distances. This manuscript highlights construction features that enable future burial structures to adequately mitigate the very real problem of contaminants entering the environment from current cemetery design. Two-thirds of the technicians interviewed for this manuscript, each of whom specialize in Brazilian cemetery design, highlighted the importance of revitalizing urban vegetation both when constructing and revitalizing urban vertical cemeteries.


Subject(s)
Cemeteries , Lead , Humans , Soil , Cities , Brazil
3.
Mar Pollut Bull ; 187: 114525, 2023 Feb.
Article in English | MEDLINE | ID: mdl-36580843

ABSTRACT

The Tinto River is known globally for having a reddish color due to the high concentration of dissolved metals in its waters. The general objective of this study is to analyze the dispersion of nanoparticles (NPs) and ultra-fine particles in terrestrial and geospatial suspended sediments (SSs) using Sentinel-3B OLCI (Ocean Land Color Instrument) satellite images; by examining water turbidity levels (TSM_NN), suspended pollution potential (ADG_443_NN) and presence of chlorophyll-a (CHL_NN). The images were collected in the estuary of the Tinto River, in the city of Nerva, Spanish province of Huelva, between 2019 and 2021. The following hazardous elements were identified in nanoparticles and ultra-fine particles by FE-SEM/EDS: As, Cd, Ni, V, Se, Mo, Pb, Sb and Sn. Sentinel-3B OLCI satellite images detected a 2019 TSM_NN of 23.47 g-3, and a 2021 reading of 16.38 g-3.


Subject(s)
Rivers , Water Pollutants, Chemical , Estuaries , Metals/analysis , Chlorophyll A , Environmental Monitoring/methods , Water Pollutants, Chemical/analysis , Geologic Sediments
4.
Geosci Front ; 13(6): 101310, 2022 Nov.
Article in English | MEDLINE | ID: mdl-36896207

ABSTRACT

Urban cemeteries are increasingly surrounded by areas of high residential density as urbanization continues world-wide. With increasing rates of mortality caused by the novel coronavirus, SARS-CoV-2, urban vertical cemeteries are experiencing interments at an unprecedented rate. Corpses interred in the 3rd to 5th layer of vertical urban cemeteries have the potential to contaminate large adjacent regions. The general objective of this manuscript is to analyze the reflectance of altimetry, normalized difference vegetation index (NDVI) and land surface temperature (LST) in the urban cemeteries and neighbouring areas of the City of Passo Fundo, Rio Grande do Sul, Brazil. It is assumed that the population residing in the vicinity of these cemeteries may be exposed to SARS-CoV-2 contamination through the displacement of microparticles carried by the wind as a corpse is placed in the burial niche or during the first several days of subsequent fluid and gas release through the process of decomposition. The reflectance analyses were performed utilizing Landsat 8 satellite images applied to altimetry, NDVI and LST, for hypothetical examination of possible displacement, transport and subsequent deposition of the SARS-CoV-2 virus. The results showed that two cemeteries within the city, cemeteries A and B could potentially transport SARS-CoV-2 of nanometric structure to neighboring residential areas through wind action. These two cemeteries are located at high relative altitudes in more densely populated regions of the city. The NDVI, which has been shown to control the proliferation of contaminants, proved to be insufficient in these areas, contributing to high LST values. Based on the results of this study, the formation and implementation of public policies that monitor urban cemeteries is suggested in areas that utilize vertical urban cemeteries in order to reduce the further spread of the SARS-CoV-2 virus.

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