Current state of knowledge of environmental occurrence, toxic effects, and advanced treatment of PFOS and PFOA.

Per- and polyfluoroalkyl substances (PFAS) are anthropogenic synthetic compounds, with high chemical and thermal stability and a persistent, stable and bioaccumulative nature that renders them a potential hazard for the environment, its organisms, and humans alike. Perfluorooctane sulfonic acid (PFOS) and Perfluorooctanoic acid (PFOA) are the most well-known substances of this category and even though they are phased out from production they are still highly detectable in several environmental matrices. As a result, they have been spread globally in water sources, soil and biota exerting toxic and detrimental effects. Therefore, up and coming technologies, namely advanced oxidation processes (AOPs) and advanced reduction processes (ARPs) are being tested for their implementation in the degradation of these pollutants. Thus, the present review compiles the current knowledge on the occurrence of PFOS and PFOA in the environment, the various toxic effects they have induced in different organisms as well as the ability of AOPs and ARPs to diminish and/or eliminate them from the environment.

Mediterranean Plants as Potential Source of Biopesticides: An Overview of Current Research and Future Trends.

The development and implementation of safe natural alternatives to synthetic pesticides are urgent needs that will provide ecological solutions for the control of plant diseases, bacteria, viruses, nematodes, pests, and weeds to ensure the economic stability of farmers and food security, as well as protection of the environment and human health. Unambiguously, production of botanical pesticides will allow for the sustainable and efficient use of natural resources and finally decrease the use of chemical inputs and burden. This is further underlined by the strict regulations on pesticide residues in agricultural products and is in harmony with the Farm to Fork strategy, which aims to reduce pesticide use by 50% by 2030. Thus, the present work aims to compile the scientific knowledge of the last 5 years (2017-February 2023) regarding the Mediterranean plants that present biopesticidal effects. The literature review revealed 40 families of Mediterranean plants with at least one species that have been investigated as potential biopesticides. However, only six families had the highest number of species, and they were reviewed comprehensively in this study. Following a systematic approach, the extraction methods, chemical composition, biopesticidal activity, and commonly used assays for evaluating the antimicrobial, pesticidal, repellant, and herbicidal activity of plant extracts, as well as the toxicological and safety aspects of biopesticide formulation, are discussed in detail. Finally, the aspects that have not yet been investigated or are under-investigated and future perspectives are highlighted.

Herbicide Use in the Era of Farm to Fork: Strengths, Weaknesses, and Future Implications.

Climate change mitigation is a major concern of the European Union (EU). In 2019, the EU presented the European Green Deal (EGD), a new environmental strategy that aimed to neutralize climate change by 2050. Within its policy areas, the EGD included the Farm to Fork (F2F) Strategy that aims to reduce pesticide use by 50%, by 2030. This reduction was proposed due to the supposed negative effects of pesticides on the environment and its biota. Among the different pesticide groups (herbicides, fungicides, insecticides, etc.) though, herbicides are perhaps the hardest to reduce. This review aimed to shed light to any factors that might hinder the reduction of herbicide use; thus, the implementation of the Farm to Fork Strategy underlines some of its weaknesses and highlights key points of a viable herbicide reduction-related policy framework. The literature suggests that integrated weed management (IWM) consists perhaps the most suitable approach for the reduction of herbicides in the EU. Even though it is too soon to conclusively assess F2F, its success is not impossible.

Investigation of the Genotoxicological Profile of Aqueous Betula pendula Extracts.

Betula pendula belongs to the Betulaceae family and is most common in the northern hemisphere. Various birch species have exhibited antimicrobial, antioxidant and anticancer properties. In the present study, we investigated the genotoxic and cytotoxic activity as well as the antigenotoxic potential against the mutagenic agent mitomycin-C (MMC) of two commercial products, i.e., a Betula pendula aqueous leaf extract product (BE) and a Betula pendula product containing aqueous extract of birch leaves at a percentage of 94% and lemon juice at a percentage of 6% (BP) using the cytokinesis block micronucleus (CBMN) assay. The most prevalent compounds and elements of BE and BP were identified using UHPLC-MS and ICP-MS/MS, respectively. All mixtures of BE with MMC demonstrated a decrease in the MN frequencies, with the lowest and highest concentrations inducing a statistically significant antigenotoxic activity. BP lacked genotoxic potential, while it was cytotoxic in all concentrations. Its mixtures with MMC demonstrated statistically significant antigenotoxic activity only at the lowest concentration. UHPLC-MS and ICP-MS/MS showed the presence of various elements and phytochemicals. Our results reveal antigenotoxic and cytotoxic potential of both BE and BP, while the variations observed could indicate the importance of the interactions among different natural products and/or their compounds.

Effect of land-use types on edaphic properties and plant species diversity in Mediterranean agroecosystem.

Land-use intensification, contrary to sustainable land management, has an impact on the healthiness of the environmental agroecosystem. To assess the environmental implications in abandoned land, olive groves and maize crops, the most sensitive and reliable edaphic indicators were measured to estimate plant species diversity and potentially toxic elements in soil, among different types of land-use. Species diversity presents a decrease in maize crops and olive groves compared to abandoned land. The families with the greatest species diversity were Poaceae, Asteraceae and Fabaceae in each land-use. From the results of the canonical correspondence analysis among species, sampling sites and selected environmental variables, a clear separation between species and sampling sites belonging to different types of land-use was found, presenting strong correlation with specific edaphic parameters (pH, Soil Organic Matter, Silt, Electrical Conductivity, Total Nitrogen, N O 3 - , P, K, Zn and Cu). Species diversity was reduced in maize crops due to anthropogenic interventions such as the excessive use of nitrogen and phosphate fertilizers and herbicides. Despite the fact that the lowest richness of plant species was found in olive groves, non-removal of crop residue preserves soil organic matter. In 7.4% of soil samples in olive groves, Cu total concentrations were over 100 mg kg-1 denoting polluted soils, while the potentially toxic concentrations of bioavailable copper fraction ( Cu DTPA ) probably lead to a decrease of species diversity. Future researches should therefore focus on the accumulation of toxic elements in agricultural land to preserve species diversity and a healthy environment.

Corrigendum to "Effects of Presowing Pulsed Electromagnetic Treatment of Tomato Seed on Growth, Yield, and Lycopene Content".

[This corrects the article DOI: 10.1155/2014/369745.].

Effects of presowing pulsed electromagnetic treatment of tomato seed on growth, yield, and lycopene content.

The use of magnetic field as a presowing treatment has been adopted by researchers as a new environmental friendly technique. The aim of this study was to determine the effect of magnetic field exposure on tomato seeds covering a range of parameters such as transplanting percentage, plant height, shoot diameter, number of leaves per plant, fresh weight, dry weight, number of flowers, yield, and lycopene content. Pulsed electromagnetic field was used for 0, 5, 10, and 15 minutes as a presowing treatment of tomato seeds in a field experiment for two years. Papimi device (amplitude on the order of 12.5 mT) has been used. The use of pulsed electromagnetic field as a presowing treatment was found to enhance plant growth in tomato plants at certain duration of exposure. Magnetic field treatments and especially the exposure of 10 and 15 minutes gave the best results in all measurements, except plant height and lycopene content. Yield per plant was higher in magnetic field treatments, compared to control. MF-15 treatment yield was 80.93% higher than control treatment. Lycopene content was higher in magnetic field treatments, although values showed no statistically significant differences.

Spatiotemporal variation and risk assessment of pesticides in water of the lower catchment basin of Acheloos River, Western Greece.

A three-year monitoring survey (March 2005-February 2008) was conducted to investigate, on monthly basis, the presence of thirty pesticides belonging to various categories and metabolites, in Acheloos River (Western Greece), one of the most important water resources in Greece. Six sampling stations along the river were established. Water analyses were performed using solid-phase extraction combined with gas chromatography with flame thermionic detector and mass spectrometry. Statistical analysis using one-way ANOVA and Duncan's multiple range test (P < 0.05) was used to compare annual mean concentrations of pesticides, seasonal and spatial distribution. In general, the highest mean concentrations of the pesticides were recorded at the three stations downstream. The greatest average concentrations were determined during spring and summer in agreement with the pesticide application period. The observed lower concentrations after 2006 reflect the land-use change because of the elimination of tobacco, the main cultivation of the area for many decades. The compounds most frequently detected were diazinon (78.6%), DEA (69.3%), and fenthion (52.6%). Environmental risk assessment using risk quotient (RQ) approach showed high risk for six insecticides in 2005 and one in 2007. A compliance with the European Environmental Quality Standards (EQS) was observed for the priority pesticides.