A new strategy for PET depolymerization: Application of bimetallic MOF-74 as a selective catalyst.

Large-volume production of poly(ethylene terephthalate) (PET), especially in the form of bottles and food packaging containers, causes problems with polymer waste management. Waste PET could be recycled thermally, mechanically or chemically and the last method allows to obtain individual monomers, but most often it is carried out in the presence of homogeneous catalysts, that are difficult to separate and reuse. In view of this, this work reports for the first time, application of bimetallic MOF-74 - as heterogeneous catalyst - for depolymerization of PET with high monomer (bishydroxyethyl terephthalate, BHET) recovery. The effect of type and amount of second metal in the MOF-74 (Mg/M) was systematically investigated. The results showed increased activity of MOF-74 (Mg/M) containing Co2+, Zn2+ and Mn2+ as a second metal, while the opposite correlation was observed for Cu2+ and Ni2+. It was found that the highest catalytic activity was demonstrated by the introduction of Mg-Mn into MOF-74 with ratio molar 1:1, which resulted in complete depolymerization of PET and 91.8% BHET yield within 4 h. Furthermore, the obtained catalyst showed good stability in 5 reaction cycles and allowed to achieve high-purity BHET, which was confirmed by HPLC analysis. The as-prepared MOF-74 (Mg/Mn) was easy to separate from the post-reaction mixture, clean and reuse in the next depolymerization reaction.

Microplastics in food - a critical approach to definition, sample preparation, and characterisation.

The ubiquity of microplastics (MPs) is a more and more frequently brought up topic. The fact that such particles are present in food raises particular concern. Information regarding the described contamination is incoherent and difficult to interpret. Problems appear already at the level of the definition of MPs. This paper will discuss ways of explaining the concept of MPs and methods used for its analysis. Isolation of characterised particles is usually performed using filtration, etching and/or density separation. Spectroscopic techniques are commonly applied for analysis, whereas visual evaluation of the particles is possible thanks to microscopic analysis. Basic information about the sample can be obtained by the combination of Fourier Transform Infrared spectroscopy or Raman spectroscopy and microscopy or using the thermal method combined with spectroscopy or chromatography. The unification of the research methodology will allow a credible assessment of the influence of this pollution coming from food on health.