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1.
Sensors (Basel) ; 22(1)2022 Jan 03.
Article in English | MEDLINE | ID: mdl-35009882

ABSTRACT

The ecosystem for an Internet of Things (IoT) generally comprises endpoint clients, network devices, and cloud servers. Thus, data transfers within the network present multiple security concerns. The recent boom in IoT applications has accelerated the need for a network infrastructure that provides timely and safe information exchange services. A shortcoming of many existing networks is the use of static key authentication. To enable the use of automatic key update mechanisms in IoT devices and enhance security in lightweight machine-to-machine (M2M) communications, we propose a key update mechanism, namely, double OTP (D-OTP), which combines both one-time password (OTP) and one-time pad to achieve an IoT ecosystem with theoretically unbreakable security. The proposed D-OTP was implemented into the Constrained Application Protocol (CoAP) through the commonly used libcoap library. The experimental results revealed that an additional 8.93% latency overhead was required to obtain an unbreakable guarantee of data transfers in 100 CoAP communication sessions.


Subject(s)
Computer Security , Internet of Things , Communication , Computer Communication Networks , Ecosystem , Humans
2.
J Hazard Mater ; 271: 252-7, 2014 Apr 30.
Article in English | MEDLINE | ID: mdl-24637449

ABSTRACT

In order to recover a low-turbidity polyalkylene glycol (PAG) liquid from silicon slurry waste by sedimentation, temperatures were adjusted, and acetone, ethanol or water was used as a diluent. The experimental results show that the particles in the waste would aggregate and settle readily by using water as a diluent. This is because particle surfaces had lower surface potential value and weaker steric stabilization in PAG-water than in PAG-ethanol or PAG-acetone solutions. Therefore, water is the suggested diluent for recovering a low-turbidity PAG (<100 NTU) by sedimentation. After 50 wt.% water-assisted sedimentation for 21 days, the solid content of the upper liquid reduced to 0.122 g/L, and the turbidity decreased to 44 NTU. The obtained upper liquid was then vacuum-distillated to remove water. The final recovered PAG with 0.37 NTU had similar viscosity and density to the unused PAG and could be reused in the cutting process.


Subject(s)
Glycols/chemistry , Industrial Waste , Polymers/chemistry , Recycling/methods , Silicon , Acetone/chemistry , Ethanol/chemistry , Nephelometry and Turbidimetry , Water/chemistry
3.
J Air Waste Manag Assoc ; 63(5): 521-7, 2013 May.
Article in English | MEDLINE | ID: mdl-23786143

ABSTRACT

UNLABELLED: The growing demand for silicon solar cells in the global market has greatly increased the amount of silicon sawing waste produced each year. Recycling kerf Si and SiC from sawing waste is an economical method to reduce this waste. This study reports the separation of Si and SiC using a ramp settling tank. As they settle in an electrical field, small Si particles with higher negative charges have a longer horizontal displacement than SiC particles in a solution of pH 7, resulting in the separation of Si and SiC. The agreement between experimental results and predicted results shows that the particles traveled a short distance to reach the collection port in the ramp tank. Consequently, the time required for tiny particles to hit the tank bottom decreased, and the interference caused by the dispersion between particles and the fluid motion during settling decreased. In the ramp tank, the highest purities of the collected SiC and Si powders were 95.2 and 7.01 wt%, respectively. Using a ramp tank, the recycling fraction of Si-rich powders (SiC < 15 wt%) reached 22.67% (based on the whole waste). This fraction is greater than that achieved using rectangular tanks. IMPLICATIONS: Recycling Si and SiC abrasives from the silicon sawing waste is regarded as an economical solution to reduce the sawing waste. However, the separation of Si and SiC is difficult. This study reports the separation of Si and SiC using a ramp settling tank under an applied electrical field. As they settle in an electrical field, small Si particles with higher negative charges have a longer horizontal displacement than SiC particles in a solution of pH 7, resulting in the separation of Si and SiC. Compared with the rectangular tanks, the recycling fraction of Si-rich powders using a ramp tank is greater, and the proposed ramp settling tank is more suitable for industrial applications.


Subject(s)
Carbon Compounds, Inorganic/chemistry , Carbon Compounds, Inorganic/isolation & purification , Industrial Waste/prevention & control , Recycling/methods , Silicon Compounds/chemistry , Silicon Compounds/isolation & purification , Silicon/chemistry , Silicon/isolation & purification , Solar Energy , Electric Conductivity , Hazardous Waste/prevention & control
4.
J Hazard Mater ; 189(1-2): 526-30, 2011 May 15.
Article in English | MEDLINE | ID: mdl-21402439

ABSTRACT

In silicon wafer manufacturing for solar cells, a great amount of hazardous sawing waste with tiny Si particles is produced, resulting in serious environmental problems. Recycling Si and abrasives from the waste is regarded as an effective solution. Based on the view of recycling, Al(2)O(3) might be good abrasives for cutting Si ingot due to its larger density and higher isoelectric point than SiC. This study reports the separation of Si/SiC and Si/Al(2)O(3) mixtures by electrophoresis and gravitational settling. At pH 9, nearly uncharged Al(2)O(3) settled quickly and the negatively charged Si moved toward the anode, leading to an obvious Si distribution on the cell bottom. The experimental results show the separation performance of Si and Al(2)O(3) at pH 9 was better than at pH 2.5, and the performance was higher than that between Si and SiC. The minimum and maximum Al(2)O(3) contents remaining in Si/Al(2)O(3) mixture were 9 wt% and 90 wt% after applying 1 V/cm for 24h at pH 9. The recovered material with high Si content can be considered as a new Si source for solar cell, and the abrasives can be reused in the sawing process.


Subject(s)
Electrophoresis , Energy-Generating Resources , Industrial Waste/prevention & control , Recycling/methods , Silicon/chemistry , Solar Energy , Aluminum Oxide , Hazardous Waste/prevention & control , Hydrogen-Ion Concentration , Silicon/isolation & purification
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