ABSTRACT
Synthetic polymers are the main food packaging material, although they are nonbiodegradable and their recycling process is expensive. A biodegradable, eco-friendly material, with high availability and low cost, such as starch, is a promising solution for the production of films for food packaging. To enhance starch film mechanical and barrier properties, nanoclays have been incorporated within the film matrix. Crosslinking is a well-established method to modify starch properties, but it has not been investigated in combination with nanoclay addition. In the present study, films were developed with starch that was crosslinked through the addition of 5, 15, and 40% wt. sodium trimetaphosphate (STMP) based on dry starch weight. To investigate the interaction between crosslinking and nanoclay addition, montmorillonite (MMT) was added at a 10.5% wt. concentration based on dry starch weight. Experimental data revealed a synergistic effect between STMP crosslinking and MMT addition regarding film thickness, elongation at break, color properties, and opacity. Regarding barrier properties, MMT addition negated the effect of STMP crosslinking, while, in the case of moisture content, it did not alter the effect of STMP crosslinking. Finally, in the case of tensile strength, a synergistic effect followed by a negative interaction was observed. In conclusion, the addition of MMT can potentially enhance, alongside crosslinking, some properties of the films, while other properties are not affected any more than just by crosslinking.
ABSTRACT
A definitive screening design was used in order to evaluate the effects of starch, glycerol and montmorillonite (MMT) concentrations, as well as the drying temperature, drying tray type and starch species, on packaging film's functional properties. Optimization showed that in order to obtain films with the minimum possible thickness, the maximum elongation at break, the maximum tensile strength, as well as reduced water vapor permeability and low opacity, a combination of factors should be used as follows: 5.5% wt starch concentration, 30% wt glycerol concentration on a dry starch basis, 10.5% wt MMT concentration on a dry starch basis, 45 °C drying temperature, chickpea as the starch species and plexiglass as the drying tray type. Based on these results, starch films were prepared, and fresh minced meat was stored in them for 3 days. It was shown that the incorporation of MMT at 10.5% wt on a dry starch basis in the packaging films led to a decreased mesophilic and psychrotrophic bacteria growth factor compared to commercial packaging. When assessed for their biodegradability, the starch films disintegrated after 10 days of thermophilic incubation under simulated composting conditions. Finally, to prove their handling capability during industrial production, the starch films were rewound in a paper cylinder using an industrial-scale rewinding machine.
